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Date submitted2023-11-02
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Date accepted2024-03-05
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Date published2024-08-26
The polyphase Belokurikhinsky granite massif, Gorny Altai: isotope-geochemical study of zircon
Based on the isotopic-geochemical analyses of zircons from granites of the Belokurikhinsky massif in the Gorny Altai using the U-Pb method, the ages of three intrusion phases have been determined for the first time: the age of the first phase refers to the time interval of 255-250 Ma, the second and the third phases have similar ages of about 250 Ma. The formation time of the Belokurikhinsky massif is estimated as not exceeding 5-8 Ma. The δ18O values for zircons from granites of the second and the third intrusion phases average around 11.5-12.0 ‰, indicating a significant contribution of a crustal component in the formation of the parent melts for granites of these phases. The crystallization temperature values of the zircons by the Ti-in-zircon thermometer for three phases range from 820 to 800 °C. The P-T crystallization parameters of titanite from the first phase, determined using a titanite thermobarometer, average around 770 °C and 2.7 kbar. The zircons from the first phase mostly exhibits geochemical characteristics of typical magmatic zircons. The zircons from the second and the third intrusion phases either may be unaltered magmatic zircons or enriched in incompatible elements (LREE, Th, U, Ti, Ca, etc.) due to fluid influence, resembling hydrothermal-metasomatic type zircons in terms of their geochemical characteristics. A number of zircon grains from the second and the third phases of granites demonstrate anomalous geochemical characteristics – the REE distribution spectra atypical for zircons (including “bird's wing” type spectra with oppositely tilted of light and heavy REE distribution profiles), as well as significantly higher contents of certain trace elements compared to other varieties. Such an enriched zircon composition and wide variations in the incompatible element content are due to non-equilibrium conditions of zircon crystallization and evolution of the fluid-saturated melt composition during the final stages of the massif formation.
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Date submitted2022-08-22
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Date accepted2023-02-02
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Date published2023-08-28
Wodginite as an indicator mineral of tantalum-bearing pegmatites and granites
- Authors:
- Viktor I. Alekseev
In the composition of tantalum-niobates, the tin-bearing wodginite group minerals (WGM) were found: wod-ginite, titanowodginite, ferrowodginite, ferrotitanowodginite, lithiowodginite, tantalowodginite, “wolframowodginite”. We reviewed the worldwide research on WGM and created a database of 698 analyses from 55 sources including the author's data. WGM are associated with Li-F pegmatites and Li-F granites. Wodginite is the most prevalent mineral, occurring in 86.6 % of pegmatites and 78.3 % of granites. The occurrence of WGM in granites and pegmatites differs. For instance, titanowodginite and “wolframowodginite” occur three times more frequently in granites than in pegmatites, whereas lithiowodginite and tantalowodginite do not appear in granites at all. The difference between WGM in granites and pegmatites is in finer grain size, higher content of Sn, Nb, Ti, W, and Sc; lower content of Fe 3+ , Ta, Zr, Hf; higher ratio of Mn/(Mn + Fe); and lower ratio of Zr/Hf. The evolutionary series of WGM in pegmatites are as follows: ferrowodginite → ferrotitanowodginite → titanowodginite → “wolframowodginite” → wodginite → tantalowodginite; in granites: ferrowodginite → ferrotitanowodginite → “wolframowodginite” → wodginite → titanowodginite. WGM can serve as indicators of tantalum-bearing pegmatites and granites. In Russia the promising sources of tantalum are deposits of the Far Eastern belt of Li-F granites containing wodginite.
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Date submitted2022-04-18
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Date accepted2022-05-25
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Date published2022-07-26
U-Pb (SHRIMP-RG) age of zircon from rare-metal (Li, Cs) pegmatites of the Okhmylk deposit of the Kolmozero-Voron’ya greenstone belt (northeast of the Fennoscandian shield)
The results of isotopic and geochronological study of zircon from rare-metal pegmatites of the Okhmylk deposit are presented. There were no reliable data on the age of lepidolite-spodumene-pollucite pegmatites of this and the other deposits spatially located within the Archean Kolmozero-Voron’ya greenstone belt. The earlier estimates of the pegmatite age indicate a broad time range from 2.7 to 1.8 Ga. Zircon in the studied pegmatites is characterized by inner heterogeneity, where core and rim zones are distinguished. Minor changes are observed in the core zones, they have a spotted structure and contain numerous uranium oxide inclusions. According to X-ray diffraction analysis, zircon crystallinity is preserved completely in these areas. Complete recrystallization with modification of the original U-Pb isotopic system occurred in the zircon rims. New U-Pb (zircon) isotopic and geochronological data of 2607±9 Ma reflect the time of crystallization of pegmatite veins in the Okhmylk deposit. Isotopic data with ages of ~1.7-1.6 Ga indicate later hydrothermal alteration. The obtained results testify to the Neo-Archean age of the formation of the Okhmylk deposit 2.65-2.60 Ga, reflecting the global age of pegmatite formation and associated the world's largest rare-metal pegmatite deposits.
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Date submitted2020-08-03
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Date accepted2020-12-13
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Date published2021-06-24
Tectonic and magmatic factors of Li-F granites localization of the East of Russia
- Authors:
- Viktor I. Alekseev
We have investigated tectonic and magmatic factors of Li-F granites localization of the East of Russia. The study is based on the ideas of Far Eastern geologists about the deep structures of intraplate activity. A model of a source structure with mantle heat sources and ore-forming magmatic complexes was used. We carried out a special metallogenic analysis of the East of Russia as applied to the rare metal-tin-bearing formation of subalkaline leucogranites, including Li-F ones. Source structures are the main factor in the tectonic and magmatic development of the East of Russia, localization of ore-forming granites and the formation of rare-metal-tin ore regions. On deep layers of source structures there are areas of the mantle and earth's crust decompaction, heat, magmas and fluids sources, as well as granitoid cryptobatholiths. Relatively large massifs of leucogranites, small intrusions of tin monzonitoids and Li-F granites are concentrated near the modern surface. The source structures correspond to the rank of the ore region. The source structures in the South of the region are: Badzhalskaya, Miao-Chanskaya, Ippato-Merekskaya, Hogdu-Lianchlinskaya, Arminskaya, etc.; in the North: Pevekskaya, Kuiviveem-Pyrkakayskaya, Kuekvun-Ekiatapskaya, Iultinskaya, Telekayskaya, Central Polousnaya, Omsukchanskaya, etc. Three types of ore regions have been identified according to the degree of source structures and Li-F granites erosion. We have also outlined the patterns of source structures evolution and their place in the geological history of ore-bearing granites. A classification of source structures and its comparison with the classifications of regional intrusives and metallogenic subdivisions are proposed. It has been established that, despite the diversity of tectonic, geological and petrological settings in the East of Russia, the intrusions of Li-F granites are regulated by the same tectonic and magmatic factors. The tectonic and magmatic factors of Li-F granites localization in the East of Russia are identified and classified as geophysical, orogenic, geoblock, magmatic, metasomatic and disjunctive.
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Date submitted2019-10-17
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Date accepted2020-01-24
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Date published2020-04-24
Composition and probable ore igneous rocks source of columbite from alluvial deposits of Mayoko district (Republic of the Congo)
The article presents the results of optical, electron microscopic and electron microprobe studies of columbite group minerals, collected during heavy mineral concentrate sampling of alluvial deposits in the Mayoko region (Republic of the Congo). The aim of the study is revealing tantalum niobates ore body in this region. We found that these minerals in loose deposits are represented by two grain-size groups: less than 1.6 mm (fine fraction) and 1.6-15 mm (coarse fraction). The grains of both fractions belong mainly to columbite-(Fe), less often to columbite-(Mn), tantalite-(Mn) and tantalite-(Fe), contain impurities of Sc, Ti, and W. The crystals have micro-scaled zoning (zones varies slightly in the Ta/Nb ratio values) and contains a lot of mineral inclusions and veins represented by zircon, pyrochlore supergroup minerals and others. Columbite-(Fe) and columbite-(Mn) are characterized by an increased content of Ta 2 O 5 up to the transition to tantalite-(Fe) and tantalite-(Mn). This allows us to exclude the formation of subalkaline rare-metal granites, their metasomatites (albitites and greisenes) and carbonatites, from the list of possible columbite ore rocks source in the Mayoko district. Thus, beryl type and complex spodumene subtype rare-element pegmatites of the mixed petrogenetic family LCT-NYF (according to P.Černý) should be considered as a probable root source. The results of the research should be taken into account when developing the methodology for prospecting in this area.
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Date submitted2016-11-03
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Date accepted2016-12-27
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Date published2017-04-14
Evolution of mineral forms of rare element accumulation in ore-bearing granites and meta-somatites of Verkhneurmiysk ore cluster (Priamur region)
It has been attempted to expand existing understanding of accessory mineralization evolution of rare metal-granite series at post-magmatic stage of their development and formation of associated hydrothermal deposits. Composition and distribution of rare elements of Verkhneurmiysk ore cluster have been examined from the position of mineralogy: the study focused on accessory and ore minerals Sn, W, Nb, Ta, Bi, Y, rare earth elements in rare metal Li-F granites and associated metasomatites. It has been discovered that accessory magmatic and hydrothermal mineral complexes share the same geochemical features, are formed under the leading role of abovementioned elements and consistently follow each other over time. It has been traced how mineral forms of accumulation of Sn, W, Nb, Ta, Y and rare earth elements evolve in the processes of magmatic crystallization and post-magmatic metasomatism in the time series: rare metal granites → zwitters → tourmalinites → chloritites. Mineral rocks of each stage were noted to inherit mineralogical and geochemical distinctions from the rocks of the previous stage. A significant number of minerals, forming in the course of two-three stages, have been discovered, as well as omnipresent magmagene-hydrothermal minerals. For a number of accessory minerals of rare metal granites post-magmatic generations have been identified. Special diversity among accessories of rare metal granites and zwitters was observed in tungsten, tin and bismuth minerals.
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Date submitted2008-10-24
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Date accepted2008-12-01
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Date published2009-12-11
History and prospects for the development of the karelian isthmus facing stone mineral base
- Authors:
- A. Y. Tutakova
The prerequisites for the development of the deposits, the previous studies and the current state of Karelian Isthmus facing stone sources as well as their comparison with those of other regions of Northwestern Federal Districts of Russia are considered. The objects for top-priority geological prospecting are determined.
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Date submitted1958-03-23
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Date accepted1958-05-15
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Date published1958-05-09
СТРОЕНИЕ И ГЕНЕЗИС ПИСЬМЕННЫХ ГРАНИТОВ В ПЕГМАТИТОВЫХ ЖИЛАХ
- Authors:
- Unknown
Письменные граниты своеобразием своей структуры давно привлекали внимание исследователей. Известно, что эти породы по своему химическому и минеральному составу подобны обычным гранитам, но весь кварц в них заключен внутри кристаллов полевых шпатов в форме многочисленных правильно ориентированных включений. Последние часто напоминают рисунок древних письмен. Эта особенность структуры пород и определила их название: руниты, еврейский камень, графические пегматиты, пегматит и наиболее принятое в нашей литературе — письменные граниты. Письменные граниты входят в состав различных геологических образований. Они известны в дайках кислых магматических пород, в апикальных частях гранитных массивов, в составе толщ глубоко метаморфизованных пород типа гнейсов и других. Наиболее эффектные и крупнозернистые образцы письменных гранитов находятся в пегматитовых жилах. Именно здесь они изучались подробно, и их первые описания насчитывают уже более чем полуторавековую давность. С тех пор изучению письменных гранитов и особенно обсуждению генезиса этих пород было посвящено большое количество работ.