-
Date submitted2024-04-16
-
Date accepted2024-06-03
-
Date published2024-07-04
Quantitative determination of sulfur forms in bottom sediments for rapid assessment of the industrial facilities impact on aquatic ecosystems
- Authors:
- Ivan P. Sverchkov
- Vladimir G. Povarov
The article describes an X-ray fluorescence method for quantitative analysis of sulfate and total sulfur in bottom sediments of watercourses and reservoirs located in the area of industrial enterprises impact. The quantitative determination of sulfur forms was carried out by analyzing the characteristic curves SKα1,2 and SKβ1,3, as well as the satellite line SKβ′ on X-ray emission spectra measured by an X-ray fluorescence spectrometer with wavelength dispersion. The study shows that these characteristic curves allow not only to determine the predominant form of sulfur, but also to separately conduct quantitative analyses of sulfates and total sulfur after fitting peaks and to separately analyze overlapping spectral lines. The results of quantitative analysis of the chemical state of sulfur by the proposed X-ray fluorescence method were compared with the results of inductively coupled plasma atomic emission spectroscopy and elemental analysis, as well as certified standard samples of soils and sediments. The results are in good agreement with each other.
-
Date submitted2019-01-03
-
Date accepted2019-03-23
-
Date published2019-06-25
Normalization of thermal mode of extended blind workings operating at high temperatures based on mobile mine air conditioners
Thermal working conditions in the deep mines of Donbass are the main deterrent to the development of coal mining in the region. Mining is carried out at the lower technical boundaries at a depth of almost 1,400 m with a temperature of rocks of 47.5-50.0 °C. The air temperature in the working faces significantly exceeds the permissible safety standards. The most severe climatic conditions are formed in the faces of blind development workings, where the air temperature is 38-42 °С. It is due to the adopted coal seam mining systems, the large remoteness of the working faces from the main air supply openings, the difficulty in providing blind workings with a calculated amount of air due to the lack of local ventilation fans of the required range. To ensure thermodynamic safety mine n.a. A.F.Zasyadko we accepted the development of a draft of a central cooling system with ground-based absorption refrigerating machines with a total capacity of 9 MW with the implementation of the three types of generation principle (generation of refrigeration, electrical and thermal energy). However, the long terms of design and construction and installation work necessitated the use of mobile air conditioners in blind development faces. The use of such air conditioners does not require significant capital expenditures, and the terms of their commissioning do not exceed several weeks. The use of a mobile air conditioner of the KPSh type with a cooling capacity of 130 kW made it possible to completely normalize the thermal working conditions at the bottom of the blind workings 2200 m long, carried out at a depth of 1220-1377 m at a temperature of host rocks 43.4-47.5 °С. It became possible due to the closest placement of the air conditioner to the face in combination with the use of a high-pressure local ventilation fan and ducts, which ensured the air flow produced by the calculated amount of air. The use of the air conditioner did not allow to fully normalize the thermal conditions along the entire length of the blind face but reduced the urgency of the problem of normalizing the thermal regime and ensured the commissioning of the clearing face.
-
Date submitted2017-11-22
-
Date accepted2018-01-04
-
Date published2018-04-24
Justification of a methodical approach of aerologic evaluation of methane hazard in development workings at mines of Vietnam
- Authors:
- V. V. Smirnyakov
- Nguen Min' Fen
The methods of evaluation of the aerological conditions to be performed for the purpose of normalization of mining conditions are provided in the present review; the location of possible accumulations of explosive gases during the drift of the development workings are taken into account. To increase the safety of the development working regarding the gas factor, a complex evaluation of a working was developed with respect to the dynamics of methane emission and air coursing along the working which is strongly affected by the character of the leakages from the ventilation ducting. Thereby, there occurs a necessity of the enhancement of a methodical approach of calculation of ventilation of a working which consists in taking into consideration a total aerodynamic resistance of the booster fan including the local resistances of the zones of the working. An integer simulation of the gas-air flows realized on the basis of a software package FLowVision allows to evaluate a change in the methane concentration in the zones of local accumulations.