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Date submitted2023-07-07
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Date accepted2023-12-27
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Date published2024-12-25
A new insight into recording the mineral composition of carbonate reservoirs at well killing: experimental studies
Well killing operation remains an important technological stage before well workover or servicing, during which filtrate penetrates the bottomhole area of the formation. The impact of process fluids and their filtrate on rock has a significant influence on permeability and porosity of carbonate reservoirs, which decrease due to fines migration. There are few known scientific studies of the interaction of killing fluid filtrate with carbonate rock and fines migration. In our experiments, an aqueous phase was used which is the basis for well killing in pure form, for the preparation of blocking agents and is used in reservoir pressure maintenance system. Core samples taken from the pay of the reservoir were used to simulate the well killing process with generation of reservoir thermobaric conditions. Killing fluid filtrate was kept for seven days, which characterizes the average workover time at flowing wells in the fields of the Perm Territory. Using micro-X-ray tomography and scanning electron microscope, images were obtained before and after the experiment, which allowed confirming a decrease in total number of voids due to fines migration and, as a consequence, a decreasing permeability of samples. Measurement of pH and fines concentration in the aqueous phase was performed before and after the experiment and pointed to mineral reactions occurring as a result of rock dissolution. The results of experiments made it possible to record a decrease in permeability of carbonate samples by an average of 50 % due to clogging of void space and migration of fines (clayey and non-clayey).
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Date submitted2023-07-07
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Date accepted2023-09-20
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Date published2024-02-29
Isotherm and kinetic adsorption of rice husk particles as a model adsorbent for solving issues in the sustainable gold mining environment from mercury leaching
One of the techniques used in extracting gold in small-scale gold mining is mercury amalgamation. However, the use of mercury presents significant health and environmental hazards, as well as suboptimal efficiency in gold extraction. This study explores the possibility of the use of rice husk as a prototype adsorbent for mercury removal from its leaching in mining environments. To support the analysis, the rice husk adsorbent was characterized by Fourier-transform infrared spectroscopy, scanning electron microscopy, electron dispersive X-ray spectroscopy, atomic absorption spectrophotometers and Brunauer − Emmett − Teller analysis. To investigate the removal of Hg from aqueous solutions, batch adsorption experiments were conducted, and the efficiency was optimized under various parameters such as contact time, rice husk dosage, and initial concentration of mercury. Kinetic and isotherm investigations were also carried out to gain a better understanding of the adsorption properties. The kinetic adsorption was analyzed using the pseudo-first-order and pseudo-second-order. Furthermore, the isotherm adsorption was analyzed using ten adsorption isotherm models (i.e., Langmuir, Freundlich, Temkin, Dubinin – Radushkevich, Flory – Huggins, Fowler – Guggenheim, Hill – de Boer, Jovanovic, Harkin – Jura, and Halsey). The amount of mercury absorption increased with increasing contact time, adsorbent mass, and initial concentration of mercury. The pseudo-second-order kinetic model is the best model that can be applied to describe the adsorption process. Analysis of the adsorption results obtained shows that the adsorption pattern is explained through the formation of a monolayer without any lateral interaction between the adsorbate and adsorbent. In addition, the formation of multilayers due to inhomogeneous pore distribution also occurs which causes a pore filling mechanism. We found that the isotherm phenomena are near the Jovanovic models with the maximum adsorption capacity) of rice husk found to be 107.299 mg/g. As a result, rice husk could be a promising option for wastewater treatment due to its fast and efficient removal capacity, as well as its affordability and eco-friendliness. The predicted thermodynamic studies using the Flory – Huggins isotherm model show that the adsorption process is endothermic, spontaneous, and physisorption. The impact shows that the utilization of rice husk can be used and fit for the current issues in the sustainable development goals (SDGs).
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Date submitted2022-05-13
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Date accepted2022-09-24
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Date published2022-11-03
Rapid detection of coal ash based on machine learning and X-ray fluorescence
Real-time testing of coal ash plays a vital role in the chemical, power generation, metallurgical, and coal separation sectors. The rapid online testing of coal ash using radiation measurement as the mainstream technology has problems such as strict coal sample requirements, poor radiation safety, low accuracy, and complicated equipment replacement. In this study, an intelligent detection technique based on feed-forward neural networks and improved particle swarm optimization (IPSO-FNN) is proposed to predict coal quality ash content in a fast, accurate, safe，and convenient manner. The data set was obtained by testing the elemental content of 198 coal samples with X-ray fluorescence (XRF). The types of input elements for machine learning (Si, Al, Fe, K, Ca, Mg, Ti, Zn, Na, P) were determined by combining the X-ray photoelectron spectroscopy (XPS) data with the change in the physical phase of each element in the coal samples during combustion. The mean squared error and coefficient of determination were chosen as the performance measures for the model. The results show that the IPSO algorithm is useful in adjusting the optimal number of nodes in the hidden layer. The IPSO-FNN model has strong prediction ability and good accuracy in coal ash prediction. The effect of the input element content of the IPSO-FNN model on the ash content was investigated, and it was found that the potassium content was the most significant factor affecting the ash content. This study is essential for real-time online, accurate, and fast prediction of coal ash.
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Date submitted2020-06-15
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Date accepted2020-06-15
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Date published2020-06-30
Description of steady inflow of fluid to wells with different configurations and various partial drilling-in
- Authors:
- Valery A. Iktissanov
There are many equations of steady inflow of fluid to the wells depending on the type of well, presence or absence of artificial or natural fractures passing through the well, different degrees of drilling-in of the wellbores. For some complex cases, analytical solutions describing the inflow of fluid to the well have not yet been obtained. An alternative to many equations is the use of numerical methods, but this approach has a significant disadvantage – a considerable counting time. In this regard, it is important to develop a more general analytical approach to describe different types of wells with different formation drilling-in and presence or absence of fractures. Creation of this method is possible during modeling of fractures by a set of nodes-vertical wells passing from a roof to floor, and modeling of a wellbore (wellbores, perforation) by a set of nodes – spheres close to each other. As a result, based on this approach, a calculation algorithm was developed and widely tested, in which total inflow to the well consists of the flow rate of each node taking into account the interference between the nodes and considering the impermeable roof and floor of the formation. Performed modeling confirmed a number of known patterns for horizontal wells, perforation, partial drilling-in of a formation, and also allowed solving a number of problems.
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Date submitted2017-11-20
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Date accepted2018-01-09
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Date published2018-04-24
Sulfidization of silver-polymetallic ores of «Goltsovoe» deposit for decreasing loss of silver in mill tailings
- Authors:
- L. V. Shumilova
- O. S. Kostikova
The results of laboratory studies of flotation concentration of silver-polymetallic ores of the Goltsovoe deposit at the Omsukchansk concentrator are presented. The results of sieve analysis of mill tailings of the experimental sample of MTP N 101 (N 7577-i) are described. They indicate that a large amount of silver (123 g/t) is lost in the size class – 0.040 mm (yield 50.25 %). According to the results of mineralogical analysis, it is established that the major losses of noble metal are associated with its fine impregnation in oxides, sulfides and silicate rocks. The main silver-bearing minerals are acanthite, polybasite and kustelite (class – 0.040 mm). Experimental studies were carried out in two stages. The purpose of the first stage is to determine the influence of grinding fineness in flotation feed (for a finished class content of 0.074 mm in the range of 60-95 %) for silver recovery at different amounts of butyl potassium xanthate (50, 150, 300 g/t). The purpose of the second stage is to evaluate the effectiveness of sulfidization at different consumption of sodium sulfide Na 2 S·9H 2 O (50, 150, 200, 450, 750 g/t – 1 % aqueous solution) under the conditions of the optimal reagent mode established in the first stage of the study. The results of experiments to determine the optimum grinding fineness and studies on the enrichment of silver-polymetallic ore with the use of sodium sulfide as a sulfidizer are presented. The efficiency of the sulfidization process is estimated. The following experimental dependencies of silver recovery are established: on the degree of grinding and consumption of butyl potassium xanthate; on variations of grinding fineness and the consumption of sodium sulphide (with a consumption of butyl xanthate 150 g/t); and on grinding fineness at optimum consumption of sodium sulfide 150 g/t and butyl potassium xanthate 300 g/t. A comparative evaluation of dependence of silver recovery index from the degree of grinding fineness before and after introduction of sodium sulphide (collecting agent consumption of 150 g/t) is given. T\
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Date submitted2014-09-25
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Date accepted2014-11-20
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Date published2015-06-26
Power consumption of hydraulic transport of products of mineral processing
- Authors:
- V. I. Aleksandrov
- Irzhi Sobota
The problem of decreasing power consumption by hydraulic transport systems remains to be the most important among other problems in the mining industry. The increase of solid material concentration in the volume of transported pulp leads to reduction of general pulp flow rate on the one hand and to increase of pressure losses and, accordingly, of a necessary head for over-coming hydraulic resistance on the other hand. The problem of minimizing power consumption in slurry transport is of particular relevance now when there is a tendency for hydraulic transport of highly-concentrated pulps and pastes to be widely used in the mining industry. The article shows that the energy intensity to a certain extent depends on the performance of hydraulic transport of solid materials, and this dependence is of extreme nature. At low concentra-tions of solid particles large volumes of recycled water have to be pumped to provide the neces-sary performance, which leads to consumption of large amounts of electricity. The increase оf concentration results in the decrease in the volumetric flow rate of the pulp and, accordingly, spe-cific power consumption of the process. The process of reducing energy consumption takes place up to a certain critical value of the concentration above which a further increase in the concentra-tion raises power consumption.
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Date submitted2010-07-21
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Date accepted2010-09-23
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Date published2011-03-21
Engineering-geological substantiation of reshaping wave-built solid masses with partial removal of hydraulic mine dump
- Authors:
- I. V. Kuznetsova
- V. P. Zharikov
Consider the case of partial removal of hydraulic mine dump in the Kuzbass region in connection with the need to retrieve from under him mothballed coal reserves. The results of geotechnical studies alluvial array: the physical and mechanical properties of alluvial rock and measurement of pore pressure in them. The problems of research and some methodological techniques. We settle the question of creating a new sustainable construction is part of the hydraulic mine dump.
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Date submitted2008-11-01
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Date accepted2009-01-22
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Date published2009-12-11
Rate setting of electrical equipment reserve stocks on the enterprises of the gas main transport
- Authors:
- L. V. Vazhenina
Minimization of economic losses from downtime of equipment and, first of all, off-schedule (breakdowns, accidents) is an actual problem whose solution can be achieved by the development and creation of a reserve stocks (irreducible level) materials and spare parts of electrical equipment. As a result of the study and comparative analysis of different methods for determining the amount of the reserve stocks has been concluded that these approaches are not fully reflect the real needs of the enterprise. In this regard, has developed an optimal method for determining the amount of irreducible level of reserve stocks of electrical equipment, taking into account the rational order of delivery of equipment, spare parts.