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Date submitted2022-03-21
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Date accepted2022-06-15
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Date published2022-07-26
Ti-Fe-Cr spinels in layered (stratified) complexes of the western slope of the Southern Urals: species diversity and formation conditions
- Authors:
- Sergey G. Kovalev
- Sergey S. Kovalev
Materials on geochemistry and ore Fe-Ti-Cr mineralization of rocks composing layered (stratified) bodies of the western slope of the Southern Urals are presented. A detailed analysis showed similarity in the redistribution of REE, noble metals, and Fe-Ti-Cr mineralization of practically all parameters in rocks of the Misaelga and Kusin-Kopan complexes. It has been established that the parameters of metamorphism, which influenced components redistribution in Fe-Ti-Cr minerals of the layered complexes, correspond to Misaelga – T = <550-750 °С, P = 0.1-2.8 kbar, Kusin-Kopan – T = <550-630 °С, P = 0.3-0.7 kbar, and Shuidinsky complexes – T = <550-760 °С, P = 0.5-2.5 kbar. The result of modelling the melt crystallization process showed that the Kusin-Kopan complex is an intrusive body with an ultramafic horizon in the idealized cross-section. Due to collisional processes, the lower part of the intrusion has been detached from the upper part. The proposed structure of the Kusin-Kopan complex sharply increases its prospects for such types of minerals as platinum group minerals + sulphide copper-nickel mine-ralization and/or chromites.
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Date submitted2022-03-31
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Date accepted2022-05-11
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Date published2022-07-26
Carbonatite complexes of the South Urals: geochemical features, ore mineralization, and geodynamic settings
- Authors:
- Irina L. Nedosekova
The article presents the results of study of the Ilmeno-Vishnevogorsky and Buldym carbonatite complexes in the Urals. It has been established that the carbonatites of the Ilmeno-Vishnevogorsky complex are represented by high-temperature calciocarbonatites (sövites I and II) with pyrochlore ore mineralization. U-Ta-rich populations of uranium pyrochlores (I) and fluorocalciopyrochlores (II) crystallize in miaskite-pegmatites and sövites I; fluorocalciopyrochlores (III) and Sr-REE-pyrochlores (IV) of late populations form in sövites II. In the Buldym complex, along with high-temperature calciocarbonatites containing fluorocalciopyrochlore (III), medium-temperature varieties of magnesiocarbonatites with REE-Nb mineralization (monazite, niobo-aeschynite, columbite, etc.) are widespread. Miaskites and carbonatites of the Urals are characterized by high contents of LILE (Sr, Ba, K, Rb) and HFSE (Nb, Ta, Zr, Hf, Ti), which are close to the contents in rift-related carbonatite complexes of intraplate settings and significantly differ from synorogenic collisional carbonatite complexes. The Ural carbonatite complexes formed on continental rift margins during the opening of the Ural Ocean at the time of transition from extensional to compressional tectonics. Later on, they were captured and deformed in the suture zone as a result of collision. Plastic and brittle deformations, anatexis, recrystallization of rocks and ores of carbonatite complexes in the Urals are associated with orogenic and post-collision settings.
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Date submitted2021-06-17
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Date accepted2021-10-18
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Date published2021-12-16
Dissolution kinetics of rare earth metal phosphates in carbonate solutions of alkali metals
- Authors:
- Tatyana E. Litvinova
- Ivan L. Oleynik
Treatment of apatite raw materials is associated with the formation of large-tonnage waste – phosphogypsum. The content of rare earth metals in such waste reaches 1 %, which makes it possible to consider it a technogenic source for obtaining rare earth metals and their compounds. Up to the present moment, there are neither processing plants, nor an efficient process flow to handle phosphogypsum dumps. It is rational to use a way that involves extraction of valuable components and overall reduction of phosphogypsum dumps. Such process flow is available with carbonate conversion of phosphogypsum to alkali metal or ammonium sulfate and calcium carbonate upon the condition of associated extraction of rare earth metal (REM) compounds. Associated extraction of REM compounds becomes possible since they form strong and stable complexes with hard bases according to Pearson, which among other things include carbonate, phosphate and sulfate anions. Formation of lanthanide complexes with inorganic oxygen-containing anions is facilitated by the formation of high-energy Ln-O bonds. The study focuses on the dissolution of lanthanide phosphates in carbonate media. It was established that formation of REM carbonate complexes from their phosphates is a spontaneous endothermic process and that formation of lanthanide carbonates and hydroxides serves as thermodynamic limitation of dissolution. A shift in equilibrium towards the formation of carbonate complexes is achieved by increasing the temperature to 90-100 °C and providing an excess of carbonate. The limiting stage of REM phosphate dissolution in carbonate media is external diffusion. This is indicated by increasing rate of the process with an intensification of stirring, first order of the reaction and the value of activation energy for phosphate dissolution from 27 to 60 kJ/mol. A combination of physical and chemical parameters of the process allowed to develop an engineering solution for associated REM extraction during carbonate conversion of phosphogypsum, which included a 4-5 h conversion of phosphogypsum at temperature of 90-110 °C by an alkali metal or ammonium carbonate solution with a concentration of 2-3 mol/l. As a result, a solution with alkali metal (ammonium) sulfate is obtained, which contains REMs in the form of carbonate complexes and calcium carbonate. The rate of REM extraction into the solution reaches no less than 93 %. Rare earth metals are separated from the mother liquor by precipitation or sorption on anion exchange resins, while the excess of alkali metal or ammonium carbonate is returned to the start of the process.
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Date submitted2018-12-30
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Date accepted2019-03-01
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Date published2019-06-25
The concept of development of monitoring systems and management of intelligent technical complexes
Conceptual approaches to improving the system of monitoring and managing the functional capabilities of intelligent technical complexes of buildings and transport and technological machines of mining enterprises are defined. Criteria are proposed for the efficiency of functioning of automatic systems for controlling the movement of transport-technological machines, taking into account the probabilistic nature of system-forming factors. The scheme of scientific and methodological research on the improvement of automation systems and traffic control in the automotive transport is presented. The perspective directions of the formation of control functions for the movement of vehicles based on the use of intelligent automated systems are substantiated. The stages of the life cycle of technical systems for monitoring the movement of vehicles, taking into account the features of their operation. A technique has been developed for the optimal use of technical means of control in the field of providing control and supervisory functions in the operation of vehicles, and the dependence of determining the financial costs of maintaining their efficiency has been determined.
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Date submitted2015-07-14
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Date accepted2015-09-27
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Date published2016-02-24
Chemical and technological mechanisms of a alkaline aluminum silicates sintering and a hydrochemical sinter processing
- Authors:
- V. M. Sizyakov
Complex mineral raw material, as alkali aluminum silicates, is an interest for aluminum industry, chemical industry and for the production of constructional materials. They are well represented in the earth's crust, characterized by the complexity of material composition and variable content of the main components such as alumina, silica and alkalies. They often occur where due to the geological conditions there is no bauxite, for instance, in the United States, Canada, Venezuela, Mexico, Iran, Egypt, Portugal, Spain, Bulgaria and other countries. At the present time for the Russian economy the nephelines from this list are the most valuable and have the great concern for the raw materials balance of the national aluminum industry. Because of limited reserves the bauxites proportion of alumina produced from nephelines by sintering is 40 % and in time this proportion will increase due to the involvement in the production of new deposits of alkali aluminum silicates. Many of foreign companies have also shown interest to the complex processing of ores. The investigation of technology is based on the method of sintering ore with limestone. As a result, the after-sintering mixture consists of alkali metal aluminates and dicalcium silicate; after-sintering mixture is leached by circulating alkaline aluminate solution, alumina, soda and potash are thrown out from the solution. Dicalcium silicate (nepheline sludge) is processed to Portland. For the investigated after-sintering mixture the tendency shows the increasing of optimum sintering temperature with the lowering Al 2 O 3 content. With the increasing of silicate module (SiO 2 / Al 3 O 3 ) of the initial alkali aluminum silicates charges the temperature of after-sintering mixture formation increases. After-sintering mixtures that are on base of alkali aluminum silicates have different microstructure and the degree of crystallization in which b-С 2 S and sodium aluminate is improved with a decrease of the aluminate phase amount. Results of investigations show a very limited solubility of aluminate phase in dicalcium silicate, which theoretically justifies a sufficiently high level of useful components chemical extraction in the processing of different types of alkali aluminum silicates by sintering.
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Date submitted2009-07-27
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Date accepted2009-09-15
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Date published2010-04-22
Geomechanical problems in the forecast of stress-strain state of underground stations of the metro at a great depth
- Authors:
- P. A. Demenkov
- I. E. Dolgiy
- V. I. Ochkurov
Forecast of stress and strain state of deep underground metro stations is considered in this article. A complex approach to study of static work of the metro stations including the in situ testing at different stages of their construction and numerical modeling with finite element method is shown.
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Date submitted2008-11-23
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Date accepted2009-01-30
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Date published2009-12-11
The estimate of the utilization’s efficiency of the production waste products, which appeared as a result of the preservation of the environment measures
- Authors:
- E. M. Pronin
Nowadays the problems of the stable growth of mineral and source of raw materials and fuel and energy complex industries are attached great importance to, since it influences the country social-economic condition. In its turn the development of the mining industry requires opening up new lands, which are especially vulnerable to different kinds of anthropogenous and technogenous factors. The changes in the state of economic system have excluded the lowering expenditure by the economy of the production scale. The typical features of a new economy became the progress of free competition and intensive demonopolization. At the same time for the mining industry it is significant that large-scale enterprises should be the foundation of many cities economies of the Russian Federation. For the way out of a system crisis it is necessary to change the strategy – to alter not only the condition of the system, but its management. The formation of the mining complexes permits to use sources of raw materials of the exploited deposits in the proper way, to process waste products of the basic production into the commodity output, to raise the efficiency and cut costs of the preservation of the environment measures from concentration waste products, exhaust solutions, gases, warm water harmful influence on the environment. The practical use of the production waste products of the mining complexes is unprofitable and makes sense only because of its opportunity partially compensating the aggregate investments for the preservation of the environment. The estimate of the utilization s efficiency of the production waste products has made.
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Date submitted2008-10-24
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Date accepted2008-12-06
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Date published2009-12-11
Geological structure, characteristics of ores and genesis of ore occurrences in the Halvdanpiggen field (West Spitsbergen island)
- Authors:
- A. N. Sirotkin
- V. V. Khailov
- D. V. Nikitin
A new metallogenic zone was separated out in a central part of the archipelago Spitsbergen by the results of exploration work. It was shown an integral series of ore areas and fields in the limits of this zone, including the ore field Halvdanpiggen. This field integrates several non-uniformly scaled the ore occurrences, which present a great interest in regard to a material composition of the ore. They likewise produce an information for determination of genesis and outlooks of total metallogenic zone. The article contains data on geology, mineralogy and geochemistry of deposits; it is established their genesis, formation membership and time of origination.
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Date submitted1958-03-29
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Date accepted1958-05-29
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Date published1958-05-09
О ПРИРОДЕ ЦИРКОНА ЩЕЛОЧНЫХ ПЕГМАТИТОВ ПРИАЗОВЬЯ
- Authors:
- Unknown
Затрагивая вопрос формирования кристаллов циркона в щелочных пегматитах, автор опирается главным образом на результаты обработки материала, собранного при изучении мариуполитов — щелочных пород, развитых в Приазовской части Украины. Однако просмотр литературы показывает, что, по-видимому, природа циркона, встречающегося и в других щелочных комплексах весьма тождественна. Решение этой задачи тесно связано с расшифровкой особенностей формирования вмещающих циркон мариуполитов, поэтому ниже рассматриваются основные черты генезиса мариуполитов в таком виде, в каком они были доложены на заседаниях Федоровской сессии.