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Vol 155 No 1
Pages:
179-181
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Research article
Metallurgy

Calculation of thermodynamic probability of reactions in the system manganese - phosphorus - sulfur

Authors:
A. A. Darin
About authors
  • Research assistant G.V. Plekhanov Saint Petersburg State Mining Institute
Date submitted:
2002-06-01
Date accepted:
2002-07-27
Date published:
2003-01-01

Abstract

The basic methods of hydrometallurgical processing of ferromanganese nodules are considered: leaching with pre-sulfation roasting and sulfuric acid leaching. The conclusion about the applicability of both methods for processing of phosphorus-containing ferromanganese nodules has been made on the basis of calculation of thermodynamics of characteristic chemical reactions. Calculated interaction energies in the systems Mn-S-O and Mn-P-S at different temperatures are given.

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References

  1. ГальнбекА.А. Расчеты пирометаллургических процессов и аппаратуры цветной металлургии / А.А.Гальнбек, Л.М.Шалыгин, Ю.Б.Шмонин. Челябинск: Металлургия, 1990.
  2. Глинка H.JJОбщая химия. М.: Химия, 1965.
  3. Теляков Н.М. Теория и практика извлечения благородных металлов при комплексной переработке руд с применением сегрегационного и сульфатизирующего обжигов / Санкт-Петербургский горный ин-т. СПб, 2000.
  4. Теляков Н.М. Разработка теоретических основ и эффективных технологических схем извлечения цветных металлов из окисленных руд, полупродуктов и новых видов минерального сырья: Автореф. ... докт. техн. наук / Санкт-Петербургский горный ин-т. СПб, 2002.

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