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Vol 167 No 2
Pages:
96-98
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Research article
Mining. Ecology

X-ray spectral studies of sorption mechanism on the surface of iron-manganese nodules

Authors:
M. Yu. Ionova
About authors
  • G.V. Plekhanov Saint Petersburg Mining Institute
Date submitted:
2005-07-24
Date accepted:
2005-08-26
Date published:
2006-02-01

Abstract

A method of analyzing the changes in the state of the sorbent surface depending on the time of sorption of petroleum products from aqueous solutions for different granulometric composition of the initial sorbent using coherent scattered X-ray radiation has been developed. The theoretical basis and experimental estimates of changes in the angle of coherently scattered photons from the sorbent surface are given. It is obtained that the angle of coherent scattering of photons depends on the class of sor-bent coarseness. In the process of sorption there is a change in the surface structure, which leads to a change in the scattering angle. Thus, knowing the angle of scattered radiation, it is possible to determine the type of the surface of any porous sorbent, as well as to estimate the degree of filling of the surface with the sorbed substance.

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References

  1. Артемьев В.А. Об ослаблении рентгеновского излучения ультрадисперсными средами // Письма в ЖТФ. 1997. Т.23. № 6. С.5-8.
  2. Бухгалтер Э.Б. Экология нефтегазового комплекса / Э.Б.Бухгалтер, И.А.Голубева, О.П.Лыков. М.: Нефть и газ, 2003. Т.1. 415 с.
  3. Лосев Н.Ф. Основы рентгеноспектрального флуоресцентного анализа / Н.Ф.Лосев, А.Н.Смагунова. М.: Химия, 1982. 206 с.

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