СРАВНИТЕЛЬНАЯ ХАРАКТЕРИСТИКА ОКИСЛЕНИЯ ЦИНКА И ОЛОВА С УЧАСТИЕМ КИСЛОТ ПРИ КОМНАТНЫХ ТЕМПЕРАТУРАХ
- 1 — Юго-Западный государственный университет
- 2 — Юго-Западный государственный университет
- 3 — Юго-Западный государственный университет
Аннотация
Анализ характеристик глубокого окисления цинка и олова соединениями меди (II) и молекулярным йодом в присутствии молекулярного кислорода и пероксида водорода как синхронно работающих с ними вторых окислителей в различных средах (водных, водно-органических и органических) с участием минеральных и карбоновых кислот, близких к комнатной температурах, показал следующее. Вклад реакционной способности металла в скорость его расходования, особенно среднюю, часто оказывается много меньше вклада, связанного с особенностями деблокирования рабочей поверхности, определяемыми скоростями накопления поверхностных отложений продуктов окисления металла, их прочностными и адгезионными характеристиками, с одной стороны, и эффективностью используемых путей их разрушения и отвода в объемную фазу – с другой.
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