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Date submitted2024-10-29
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Date accepted2024-10-29
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Date published2024-11-12
Study of thermodynamic processes of the Earth from the position of the genesis of hydrocarbons at great depths
In the context of significant depletion of traditional proven oil reserves in the Russian Federation and the inevitability of searching for new directions of study and expansion of the raw material base of hydrocarbon raw materials in hard-to-reach regions and on the Arctic shelf, a scientific search is underway for accumulations in complex geological conditions and in manifestations that differ significantly from traditional ones, which include the processes of oil and gas formation and preservation of oil and gas in low-permeability “shale” strata and in heterogeneous reservoirs at great and super-great depths. Within the oil and gas provinces of the world, drilling of a number of deep and super-deep wells has revealed deposits at great depths, established connections between hydrocarbon deposits and “traces” of hydrocarbon migration left in the core of deep wells, which has made it possible to significantly re-evaluate theoretical ideas on the issue of oil and gas formation conditions and the search for technologies aimed at solving applied problems. Modern geochemical, chromatographic, bituminological, coal petrographic and pyrolytic methods of studying oil and bitumoids extracted from the host rocks of deep well cores give a hope for identifying correlations in the oil-source system, revealing processes that determine the possibility of hydrocarbon formation and accumulation, and defining predictive criteria for oil and gas potential at great depths.
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Date submitted2019-01-13
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Date accepted2019-03-04
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Date published2019-06-25
Thermodynamic model of ion-exchange process as exemplified by cerium sorption from multisalt solutions
A complex heterogeneous process of ion exchange can be defined with an isotherm-isobar equation of the chemical reaction, which describes differential affinity between the process and its effect – the law of mass action. Ion exchange includes processes accompanied by changes in the charge of ions and functional groups caused by the passing of ionic bond into covalent one. Hence isotherm equations of ion exchange for such processes must differ from conventional stoichiometric equations, but they can be obtained by classical study approaches to ion exchange equilibrium. The paper describes a new thermodynamic model, based on linearization of mass action law, modified for the ion exchange equation. The application of this model allows to define stoichiometry of ion exchange and the shape of ions adsorbed by the solid phase of ion-exchange resins, as well as to estimate equilibrium constant and Gibbs free energy of the process. Comparative analysis has been carried out for the thermodynamic model of cerium sorption in the form of anionic complex with Trilon B from a multisalt solution with ionic strength of 1 mol/kg (NaNO 3 ) under рН = 3 and temperature 298 K on a test sample of weak-base anion-exchange resin Cybber EV009. Experimental isotherm of the sorption has been obtained. Calculations of thermodynamic parameters have been performed using Langmuir, Freundlich, Dubinin – Radushkevich, Temkin and Flory – Huggins models, as well as thermodynamic model of linearized mass action law, proposed by the authors. Calculated values of the equilibrium constant and Gibbs energy – K = 9.0±0.5 and ΔrG 0 298 = –5.54±0.27 kJ/mol – characterize the sorption of EDTA cerate ions by ion-exchange resin. The shape of adsorbed ions has been defined in Stern-Helmholtz layer of CeTr, and total capacity of anion resin EV009 for EDTA cerate ions has been estimated as q ∞ = 2.0±0.1 mol/kg.
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Date submitted2018-11-03
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Date accepted2019-01-21
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Date published2019-04-23
Estimation of critical depth of deposits by rock bump hazard condition
- Authors:
- V. N. Tyupin
During the development of minerals by the underground method, dynamic manifestations of rock pressure occur at a certain depth, which significantly reduces the safety of mining operations. Regulatory documents prescribe at the exploration and design stages to establish the critical depth for classifying a deposit as liable to rock bumps. Currently, there are a number, mainly instrumental, methods for determining the liability of rock mass to rock bumps and methods based on the determination of physical and technical properties and the stress-strain state of rock massifs. The paper proposes a theoretical method for determining the critical depth for classifying a deposit as liable to rock bumps. A formula for determining the critical depth of the rock bump hazard condition is obtained. A mathematical analysis of the influence of the physical and technical parameters of the formula on the critical depth is carried out. Its physical and mathematical validity is substantiated. The numerical calculations of the critical depth for 17 developed fields were carried out using a simplified formula. It also provides a comparison of calculated and actual critical depth values. It is established that the variation of the actual and calculated critical depth is due to the lack of actual data on the value of the friction coefficient and parameters of fracturing of the rock mass in the simplified formula. A simplified calculation formula can be used to estimate the critical depth of a field at the survey and design stages. More accurate results can be obtained if there are actual data on fracture parameters, friction coefficients and stress concentration near the working areas.
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Date submitted2016-11-07
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Date accepted2016-12-27
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Date published2017-04-14
Method of determining characteristics for air heating system in railway tunnels in harsh climatic conditions
- Authors:
- S. G. Gendler
- S. V. Sinyavina
The article describes climatic and mining-technical conditions influencing frost formation process. It was noted that the radical tools for preventing frost formation in winter periods is creation of positive temperature in tunnels by heating the incoming outside air. We formulated tasks, which solution will promote development of engineering calculation method for heating systems parameters. The article provides results of theoretical studies based on mathematical modelling and analytical solutions and data on field instrumental measurements, which were processed with similarity criteria. It compares mathematical modelling results on determining amount of tunnel incoming air flow with portal gates and calculations data from experimentally determined coefficient of local resistance. We proved the energy efficiency of placing the tunnel portal gates and validated the places of preheated air injection points and removal of cool air from this flow, which provides maximal energy effect.
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Date submitted2014-11-05
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Date accepted2015-01-24
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Date published2015-10-26
Use of geoinformation technologies for otpimized distribution of stations of atmospheric air quality monitoring
- Authors:
- M. V. Volkodaeva
The article deals with possible applications of modern geographic information systems for optimized distribution of stations of atmospheric air quality monitoring. Due to the fact that estimation of atmospheric pollutant concentrations is a reason for decisions to improve air quality, costly measures to protect the atmosphere and monitoring effectiveness of these actions, atmospheric air quality indicators, and therefore the proper distribution of monitoring stations, are of great importance. Results of model calculations of atmospheric air pollution, which have been recently developed in our country, in combination with GIS solutions, should be used for optimized distribution of stations of atmospheric air quality monitoring. One of the major factors of objective estimation of urban atmospheric air quality is proper reference of industrial and transport pollutant emission sources to the city’s topographic base (both in citywide and local coordinate systems), as well as distribution of stations of atmospheric air quality monitoring and selection of high-priority pollutants for a particular city district. Some recommendations for monitoring stations distribution and pollutants selection based on the GIS analysis of spatial distribution of maximum ground level concentrations of pollutants are given.
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Date submitted2014-07-21
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Date accepted2014-09-19
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Date published2014-12-22
Preliminary preparation of oil for primary processing
Oil supplied for primary processing always undergoes preliminary preparation, the purpose of which is to eliminate the harmful effect of water and salt contained in the oil. It is thought that corrosion of the equipment is connected mainly with chlorides of magnesium and calcium, which are subjected to hydrolysis with the formation of hydrochloric acid. Under the influence of hydrochloric acid the destruction (corrosion) of metal equipment at technological plants occurs (especially refrigerating-condensing and heatexchange equipment, furnaces of rectification units etc.). The authors of the article, on the basis of thermodynamic calculations, provide their point of view on this process and give a methodology by which the process of preliminary oil dehydration and desalting can be controlled. The thermodynamic calculations executed for standard conditions on the basis of refer-enced data confirm a high probability of chemical interaction of iron with hydrogen ions, hy-drogen sulphide and especially with carbonic acid. This testifies to high activity of the carbon dioxide dissolved in water and the impossibility of hydrolysis of ions of magnesium, calcium and iron. The calculations show that only the hydrolysis of magnesium chloride is possible tak-ing into account the ionic composition of the water phase in the oil. It should be noted that the presence of ions of chlorine shifts the iron potential in a nega-tive direction and increases the speed of corrosion of petrochemical equipment. The solution of this problem is in the development of modern methods of crude oil dehydration and desalting. It is also, however, in an intensification of the processes of mixing water-oil emulsions with wash-ing water by using various physical fields (for example, ultrasound) and creating new effective mixing devices on the basis of them.