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Date submitted2019-04-04
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Date accepted2019-08-04
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Date published2020-04-24
Chemical heterogeneity as a factor of improving the strength of steels manufactured by selective laser melting technology
The aim of this paper was to establish the causes of the heterogeneity of the chemical composition of the metal obtained by the LC technology. The powdered raw material was made from a monolithic alloy, which was fused by the SLM, the initial raw material was a laboratory melting metal of a low-carbon chromium-manganese-nickel composition based on iron. To determine the distribution pattern of alloying chemical elements in the resulting powder, electron-microscopic images of thin sections were combined with X-ray analysis data on the cross-sections of the powder particles. As a result, it was found that transition (Mn, Ni) and heavy (Mo) metals are uniformly distributed over the powder particle cross-sections, and the mass fraction of silicon (Si) is uneven: in the center of the particles, it is several times larger in some cases. The revealed feature in the distribution of silicon is supposedly due to the formation of various forms of SiO 4 upon the cooling of the formed particles. The internal structure of the manufactured powder is represented by the martensitic structure of stack morphology. After laser fusion, etched thin sections revealed traces of segregation heterogeneity in the form of a grid with cells of ~ 200 μm.
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Date submitted2018-05-06
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Date accepted2018-07-17
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Date published2018-10-24
Obtaining intermetallic compounds in Al–Ti–Zn system
- Authors:
- V. V. Kaminskii
- S. Y. Petrovich
- V. A. Lipin
Binary intermetallic compounds – titanium aluminides (TiAl, Ti 3 Al) – when added to the alloys, significantly increase their strength and special properties. The most promising direction to produce intermetallic compounds are mechanochemical technologies, including mechanical alloy building. Mechanical alloying makes it possible to introduce much smaller particles into the metal matrix than can be achieved using standard powder metallurgy technologies. In addition to mechanical synthesis, aluminum-based intermetallic compounds were produced by self-propagating high-temperature synthesis (SHS) of solid chemical compounds. The synthesis was carried out according to a multistage scheme: preparation of titanium and aluminum powder, mixing; synthesis of the Al 3 Ti intermetallic compound by the SHS method in vacuum followed by mechanical activation of stoichiometric charges. The aim of the research was to study the dynamics of the development of nanodispersed phases in the process of synthesis during mechanical alloying. The power absorbed by the unit mass of the material for different processing times of the charge was calculated. When the level of the specific power (dose) of mechanical treatment was 3.5 kJ/g, the maximum content of intermetallic compound in the resulting material was achieved. Based on calculations and the data obtained during X-ray phase analysis, the dependence of the change in the content of ternary intermetallic compounds in the final product on the absorbed power was determined. As a result of the studies using raster electron microscopy and X-ray analysis, it was found that mechanical alloying of nanostructured intermetallic compounds Ti 4 ZnAl 11 and Ti 25 Zn 9 Al 66 with the size of nanodisperse phases less than 12 nm in the Al–Ti–Zn system, the weight ratio of proportion of the latter reaches 74 %.
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Date submitted2018-05-04
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Date accepted2018-07-23
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Date published2018-10-24
Analysis of possible enhancementof properties of VK15 material used for drilling tools
- Authors:
- Yu. A. Kurganova
- K. S. Panina
- P. S. Beshenkov
Traditionally, when drilling hard and abrasive rocks, it is recommended to use a tungsten-cobalt hard alloy VK15. The analysis of information on the possibility of improving the potential of the material has demonstrated the existence of mechanisms that provide structural transformations that enhance its strength, hardness and toughness. The use of such technology instead of traditional methods will lead to an increase in the operating efficiency and durability of the tool. During the work, experimental samples of alloy VK15 were obtained by sintering in four different modes. Then their properties were analyzed. The results of the metallographic study carried out on the «Carl Zeiss» microscope made it possible to estimate the distribution of tungsten carbide grains in cobalt bon and show the grinding of the carbide phase. Thus, with traditional sintering, the amount of tungsten carbide grains with an average size of less than 1 μm in diameter from the entire size range reaches 19.5 %, while after additional heat treatment with a holding time of 1280 °C, the value was 41.5 %; 900 °C – 59.1 %; 600 °С – 54.5 %. The maximum improvement results were the following: hardness by 18 %, a coercive force by 49 %, and crack resistance by 11 % of the traditional alloy, there were achieved at 900-1280 °C. A hypothesis has been put forward on the formation of additional structural elements not detected by the methods of optical metallography. Studies of the topology and structure of the samples on an atomic force microscope confirmed the presence of nanoscale inclusions from 20 to 40 nm (presumably tungsten carbide) in a cobalt bond.For VK15, comparative studies of properties and analysis of the microstructure of experimental samples obtained by the traditional sintering and modified technology have shown that the sintering mode at 900 °C is a priority.
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Date submitted2017-10-31
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Date accepted2018-01-01
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Date published2018-04-24
Peculiarities of formation and growth of nanodispersed intermetallic strengthening inclusions in rapidly-solidified alloys of Al–Mg–Zr–X-system
- Authors:
- D. I. Budelovskii
- S. Yu. Petrovich
- V. A. Lipin
The paper is devoted to the influence of the fourth element on the microstructure of the rapidly-solidified alloys of the Al–Mg–Zr-system. Alloys were additionally doped with high-melting-point metals Ti, Hf, W, and Nb. In the structure of all samples in the immediate area of the cooled surface, uniformly distributed intermetallic inclusions of several nanometers in size were detected. Such a structure can be represented as a dispersion-strengthened composite. A quantitative metallographic analysis was carried out to quantitatively describe the structure of the obtained particles of the cooled melt. The obtained rapidly-solidified alloys can be described as dispersion-strengthened composite materials with the aluminum-magnesium alloy matrix and the intermetallic particles strengthener. Depending on the alloying component, these particles differ in shape (spheres, plates, agglomerates) and in size (from 200 nm when alloying with Hf and W up to 1.2-1.5 μm with Ti and Nb alloying). The X-ray phase analysis (XPA) showed that in the studied alloys of the Al–5Mg–1.2Zr–(0.5÷2.0)X-system, high cooling rates of melts lead to the formation of new intermetallic compounds that are absent in equilibrium systems. The example of an alloy with hafnium additive shows that an increase in the content of the alloying component (from 0.5 to 2 % by mass) leads to an increase in the volume ratio of intermetallic inclusions (from 5 to 12.8 %). At the same time, their shape and average size remain unchanged. The additional alloying component will improve the mechanical characteristics of aluminum alloys by increasing the recrystallization threshold of a rapidly-solidified alloy.
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Date submitted2017-08-30
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Date accepted2017-11-23
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Date published2018-02-22
Basic provisions and problems of ELW technology for the manufacture of aluminum-magnesium alloys constructions
- Authors:
- E. I. Pryakhin
- N. I. Sharonov
Existing problems of electron beam welding of aluminum alloy constructions are considered. For research purposes, the aluminum-magnesium alloy of grade 1561 up to 60 mm thick was used. The thermal field in the heat influence zone is studied experimentally and analytically on the basis of the finite element method (the «Ansys» program). The effect of electron beam movement (scanning) influence on the quality of welded connections and the surface of the welded parts was studied. On the basis of metallographic studies and mechanical tests of welded metal, it is proved that high quality of welded joints is ensured when the beam moves along a curve of the «compressed brackets» shape. A special generator is designed to control the electron beam, which allows to implement a new type of scanning (compressed brackets). The fundamentals of welding technology for alloy 1561 up to 60 mm thick are outlined. Specific recommendations are given, and two new methods are proposed that will allow the successful use of the developed technology in factories in the production of new products and in the repair processes. Examples and analysis of thermal cycles obtained by calculation and experimental method are given. The patterns of heat distribution along the trajectory of the beam movement for different types of scanning are established. The main types of defects in the formation of the welded joints and those formed in the metal during crystallization are considered. Their interrelation with the parameters of the welding mode is shown.
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Date submitted2015-12-13
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Date accepted2016-02-23
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Date published2016-12-23
Properties isotropy of magnesium alloy strip workpieces
- Authors:
- R. Kavalla
- V. Yu. Bazhin
The paper discusses the issue of obtaining high quality cast workpieces of magnesium alloys produced by strip roll-casting. Producing strips of magnesium alloys by combining the processes of casting and rolling when liquid melt is fed continuously to fast rolls is quite promising and economic. In the process of sheet stamping considerable losses of metal occur on festoons formed due to anisotropy of properties of foil workpiece, as defined by the macro- and microstructure and modes of rolling and annealing. The principal causes of anisotropic mechanical properties of metal strips produced by the combined casting and rolling technique are the character of distribution of intermetallic compounds in the strip, orientation of phases of metal defects and the residual tensions. One of the tasks in increasing the output of fit products during stamping operations consists in minimizing the amount of defects. To lower the level of anisotropy in mechanical properties various ways of treating the melt during casting are suggested. Designing the technology of producing strips of magnesium alloys opens a possibility of using them in automobile industry to manufacture light-weight body elements instead of those made of steel.
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Date submitted2014-10-15
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Date accepted2014-12-14
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Date published2015-08-25
Formiing of structure and properties of sheet strips from magnesium alloys in the conditions of twin roll casting process
- Authors:
- R. Kavalla
- V. Yu. Bazhin
In this article the problem of receiving high-quality cast strips from the magnesium alloys received by units of twin roll casting process in the combined methods is discussed. Production of sheets from magnesium alloys combination of casting and rolling at continuous giving of liquid melt to the rotating rolls is perspective and more economic method. Features of crystallization of magnesium alloys of AZ31 and AZ61 in a gap of rolls crystallizers depending on heat exchange conditions at change of technological parameters are considered. Due to impact on melt in forming system it is possible to provide formation of equal fine-grained structure of sheet hire without superficial defects. Development of the production technology of sheets from magnesium alloys creates possibility of their use of automobile branch as the facilitated details of bodies instead of the knots made of steel.
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Date submitted2009-09-22
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Date accepted2009-11-17
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Date published2010-06-25
Linear ccd-sensors based multiprocessor photometer system for spectral analysis
- Authors:
- A. S. Mustafaev
- A. B. Tsyganov
- B. V. Dobrolezh
There is presented a multiprocessor photometric CCD-system for a wide range of spectrometers and for various spectral analysis methods implementation.