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Date submitted2024-05-17
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Date accepted2024-10-14
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Date published2024-11-12
Black shales – an unconventional source of noble metals and rhenium
The content of noble metals and rhenium in the Lower Paleozoic black shales of the eastern Baltic paleobasin in Russia was estimated. Shales are enriched in platinoids (PGM to 0.12 g/t) and rhenium (to 1.54 g/t). The main accessory elements of noble metals and Re are U, V, Mo, Cu, and Ni. Black shales consist of organic (9-26 rel.%), clay (40-60 rel.%), and silt-sandy (25-50 rel.%) components and a nodule complex (2-5 rel.%) (carbonate, sulfide, phosphate and silicate nodules). Noble metals occur sporadically in the silt-sandy admixture as native forms and intermetallics: Aunat, Au-Ag, Au-Cu, Au-(Cu)-Hg, Au-Hg, Ag-Cu, Pt-Fe. Micromineral phases of noble metals were found in diagenetic sulfides: Aunat, chalcopyrite with Au admixture, pyrite with platinoid admixture. Clay fraction is 10-fold enriched in noble metals as compared to shale – to 0.28 g/t Au, 0.55 g/t Pt, 1.05 g/t Pd, and 1.56 g/t Re. Organic matter sorbs noble metals to a limited extent but accumulates rhenium. Pore space of black shales contains a colloidal salt component (submicron fraction) which is represented by particles smaller than 1,000 nm. The share of submicron fraction in black shales is 0.1-6 wt.%. The submicron fraction contains on average: PGM – 14 g/t, Au – 0.85 g/t, and Re – 4.62 g/t. The geochemical resource of noble metals (Au, Pt, Pd), Re and the accessory elements (U, V, Mo, Cu, and Ni) for black shales as a whole and their submicron fraction was estimated. Black shales are recommended as an integrated source of raw materials.
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Date submitted2015-08-02
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Date accepted2015-10-04
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Date published2016-04-22
Development of innovative technologies of dedusting in mining and advance coal mine faces
- Authors:
- G. I. Korshunov
- S. B. Romanchenko
The article describes the results of the implementation of investment projects in the field of complex dedusting implemented in major coal producing companies in Russia. Experimental study of the processes reduce the levels of dust in the workplace in the application of modern systems of irrigation and aspiration systems. The factors that determine the mass and composition of particulate airborne dust at various ways of dust suppression. The results of the analysis of the laser dispersed composition of particles removed from the air of the working area
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Date submitted2015-07-26
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Date accepted2015-09-12
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Date published2016-02-24
Technological aspects of extraction of precious and rare metals from carbonaceous rocks
- Authors:
- T. N. Aleksandrova
- E. G. Panova
The results of mineralogical, geochemical and technological research of black shale rocks are given. It is proved that black shales are now regarded as a new promising and innovative source of precious and rare-metal raw materials. It is pointed out that 3 wt. % of black shales samples is colloid-salt fraction (nanofraction) with a particle size less than 1000 nm and it can be extracted with water under specially chosen conditions. The use of water instead of chemically active reagents guarantees the absence of dissolved mineral matrix and clearly shows the colloidal salt component in samples. The results determine the direction of creating some new methods and technologies of carbonaceous feed dressing for integrated development of solid minerals in the mining and oil producing regions of Russia.
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Date submitted2013-07-09
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Date accepted2013-09-04
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Date published2014-03-17
A new chemical method of dust suppression for the storage of the rock mass
The using of chemically-active reagents is one of the most promising directions in the process of dust suppression. Due to the need to develop new ways of suppression of dust during storage of the rock mass. The paper provides the analysis of the use of calcium carbide as an element of the dust suppression system and the system of permafrost rocks.