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Date submitted2023-02-10
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Date accepted2023-09-20
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Date published2024-04-25
Depth distribution of radiation defects in irradiated diamonds by confocal Raman spectroscopy
Five colored diamonds were investigated. According to the results of the study by FTIR, UV-Vis-NIR and Photoluminescence spectroscopy, they are natural type Ia diamonds. The depth distribution of the color intensity was carried out by measuring the intensity of the PL peak at 741 nm (GR1 center) upon excitation by a laser with a wavelength of 633 nm of Raman Confocal microscope. To minimise the perturbation due to geometrical effects, defect distribution profiles were normalised with respect to diamond Raman peak intensity (691 nm) point by point. For two diamonds, the intensity of the GR1 peak (741 nm) sharply decreased to a depth of 10 µm, and then became equal to the background level, which is typical for irradiation with alpha particles from natural sources like uranium. In other diamonds, the profiles vary slightly with depth, and the color intensity is close to uniform, which is for irradiation with accelerated electrons or neutrons. The source of radiation has not been determined. However, long duration radioactivity measurements of the diamonds suggested that neutrons were not used for colour centers production in the diamonds studied.
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Date submitted2021-02-09
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Date accepted2023-09-20
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Date published2024-02-29
Analysis of experience in the use of preformed particle polymer gels in the development of high-water-cut production facilities in low-temperature oil reservoirs
- Authors:
- Sergei V. Galkin
- Yuliya A. Rozhkova
Foreign practice of oil production in high-water-cut conditions suggests using the technology of injection of preformed particle gel (PPG) suspension into injection wells. After swelling, the polymer particles become elastic and are able to penetrate through highly permeable watered intervals into the remote reservoir zone, forming a polymer “plug”. Thus far, the domestic experience of application of this technology boiled down to testing foreign compounds. We have looked into the possibilities of PPG technology application in geological and technological conditions of high-water-cut fields of Perm Krai. The paper proposes PPG reagents effective in low-temperature reservoirs (20-35 °С) and at relatively high salinity of formation water (more than 200 g/l). The world experience of PPG technology application was analyzed to identify the principal scheme of reagent injection, to establish variants of sequence of injection of PPG particles of different sizes, as well as the possibility of regulating the morphological characteristics of polymer gel particles during synthesis depending on the porosity and permeability of the reservoir. A prerequisite for the technology is the ability to remove PPG particles after treatment from the bottom-hole zone of the formation; for this purpose, tests were carried out on a breaker compound based on sodium persulfate with synergizing additives. PPG technology is effective in reservoirs with high permeability heterogeneity. Two types of high-water-cut production facilities potentially promising for PPG realization have been identified for oil fields of Perm Krai. The first type includes carbonate Tournaisian-Famennian reservoirs with pronounced macrofracturing, in which the PPGs are used for colmatation of flushed large fractures. The second type is terrigenous Visean deposits with increased oil viscosity from 5 to 100 mPa∙s and high permeability of reservoirs (> 0.5 μm2). For both types of reservoirs, areas have been selected that are promising for the implementation of PPG technology.
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Date submitted2022-06-20
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Date accepted2023-01-10
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Date published2023-08-28
Laboratory, numerical and field assessment of the effectiveness of cyclic geomechanical treatment on a tournaisian carbonate reservoir
Results are discussed for evaluation of effectiveness of the cyclic geomechanical treatment (CGT) on a Tournaisian carbonate reservoir. Analysis of laboratory experiments performed according to a special program to assess permeability changes for Tournaisian samples under cyclic changes in pore pressure is presented. The main conclusion is the positive selectivity of the CGT: an increase in permeability is observed for samples saturated with hydrocarbons (kerosene) with connate water, and maximal effect is related to the tightest samples. For water-saturated samples, the permeability decreases after the CGT. Thus, the CGT improves the drainage conditions for tight oil-saturated intervals. It is also confirmed that the CGT reduces the fracturing pressure in carbonate reservoirs. Using flow simulations on detailed sector models taking into account the results of laboratory experiments, a possible increase in well productivity index after CGT with different amplitudes of pressure variation was estimated. Results of a pilot CGT study on a well operating a Tournaisian carbonate reservoir are presented, including the interpretation of production logging and well testing. The increase in the well productivity index is estimated at 44-49 % for liquid and at 21-26 % for oil, with a more uniform inflow profile after the treatment. The results of the field experiment confirm the conclusions about the mechanisms and features of the CGT obtained from laboratory studies and flow simulations.
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Date submitted2019-08-08
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Date accepted2019-09-16
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Date published2020-02-25
Testing of preformed particles polymer gel technology on core filtration models to limit water inflows
In order to reduce watering of wells and equalize their injectivity profiles, the prospects of introducing PPG technology in Russian fields are considered, in which preformed particles polymer gel are pumped into the injection well. These particles, being a supersorbent based on polyacrylamide, absorb water, become elastic, which allows them to shrink and tear in narrow filtration channels. When the polymer is filtered along permeable layers saturated with water, polymer particles accumulate in waterlogged intervals and thus they form a polymer plug, which redistributes the filtration flows and increases the coverage of the formation by the process of oil displacement. More than 4000 downhole operations have been carried out in the fields of China and the USA using PPG technology by now. In domestic fields in Western Siberia, there is limited experience in applying a similar technology in high-temperature formations with low mineralization of formation water. Due to the absence of hydrolytic processes in polyacrylamide, well-known domestic compositions are not applicable due to the low absorption capacity in the conditions of low-temperature deposits with increased mineralization of formation water. The authors synthesized a polymer based on polyacrylamide by block polymerization, which allows to obtain a high absorption capacity, including for low-temperature formations with high mineralization of formation water, which is typical for Perm Territory fields. Filtration experiments were carried out on core models with the composition developed by the authors, this composition focused on low formation temperatures and high mineralization of formation water. As a result of the experiments, it was found that the swollen particles of the gel are able to pass into fractures with a diameter less than their own size at least 20 times. With a significant increase in the viscosity of the dispersion medium, the stability of the suspension increases. Particles of polymer gel have the necessary strength for injection in the field conditions. The fracture permeability during polymer injection decreases by several times and becomes comparable with the permeability of pore collectors.
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Date submitted2019-03-25
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Date accepted2019-05-14
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Date published2019-08-23
Increase in Intake Capacity by Dynamic Operation of Injection Wells
- Authors:
- E. V. Belonogov
- A. Yu. Korovin
- A. A. Yakovlev
The method of pumping water to compensate for fluid withdrawals from an oil formation in order to maintain formation pressure has long established itself as an effective technology and is widely used at oil and gas fields. At the same time, field operator is often faced with the problem of reduction in the intake capacity of injection wells, which may be caused by various complications arising in the near-wellbore area due to a violation of water treatment technology or other factors. This problem is typical for reservoirs with low permeability values, which leads to a decrease in the performance indicators of the formation pressure maintenance system. In order to counter contamination of the bottomhole zone of the well, as a rule, injection of specialized acid compositions for the purpose of cleaning is used. To increase the effectiveness of this procedure, the authors of the article propose to discharge the injection well at the maximum permissible speeds. This event will allow primary cleaning of the bottomhole zone of the formation from moving particles clogging the pore space, and reduce formation pressure in the vicinity of the injection well, which will subsequently improve the intake capacity of the well during treatment with acid compositions. The decrease in formation pressure in the bottomhole zone of the well also has a positive effect on the radius of acid penetration into the formation. The proposed approach has been successfully tested on a number of injection wells at one of «Gazprom Neft» enterprises. The results of pilot operations showed an increase in the quality of cleaning the bottomhole zone of the formation and an increase in the intake capacity of injection wells with subsequent preservation of intake dynamics.
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Date submitted2018-09-08
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Date accepted2018-10-27
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Date published2019-02-22
Special strategy of treatment of difficulty-profile conical screw surfaces of single-screw compressors working bodies
- Authors:
- A. S. Vasilev
- A. A. Goncharov
The article deals with the problems arising during the shaping of complex profile tapered helical surfaces. These surfaces form the geometry of the working bodies of single-screw miniature compressors, which have great prospects for use in mobile miniature compressor plants, which is especially important for medical and space technology, robotics, oil and gas and mining industries. Due to the fact that the capabilities of existing CAD systems do not allow obtaining three-dimensional models of these surfaces, the problem of preparing a control program for a CNC machine arises, since the calculation of the tool path in CAM systems when processing complex surfaces is impossible without a three-dimensional surface model. To solve the problem, an automated programming system was developed that implements a formalized toolpath calculation in accordance with the proposed special processing strategy for conical helical surfaces. As the initial data for calculating the toolpath, the system needs information about the tool geometry and the helical surface in a parametric form, which makes it possible to abandon the construction of a three-dimensional surface model. The results of processing prototypes for the proposed strategy are given.