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Date submitted2023-02-10
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Date accepted2023-09-20
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Date published2024-04-25
Depth distribution of radiation defects in irradiated diamonds by confocal Raman spectroscopy
Five colored diamonds were investigated. According to the results of the study by FTIR, UV-Vis-NIR and Photoluminescence spectroscopy, they are natural type Ia diamonds. The depth distribution of the color intensity was carried out by measuring the intensity of the PL peak at 741 nm (GR1 center) upon excitation by a laser with a wavelength of 633 nm of Raman Confocal microscope. To minimise the perturbation due to geometrical effects, defect distribution profiles were normalised with respect to diamond Raman peak intensity (691 nm) point by point. For two diamonds, the intensity of the GR1 peak (741 nm) sharply decreased to a depth of 10 µm, and then became equal to the background level, which is typical for irradiation with alpha particles from natural sources like uranium. In other diamonds, the profiles vary slightly with depth, and the color intensity is close to uniform, which is for irradiation with accelerated electrons or neutrons. The source of radiation has not been determined. However, long duration radioactivity measurements of the diamonds suggested that neutrons were not used for colour centers production in the diamonds studied.
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Date submitted2020-07-30
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Date accepted2021-03-02
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Date published2021-04-26
Experimental study of thermomechanical effects in water-saturated limestones during their deformation
Stability control of elements of stone constructions of various structures is a prerequisite for their safe operation. The use of modern methods of non-destructive diagnostics of the stress-strain state of such constructions is an effective, and in many cases the only way to control it. Studies of thermal radiation accompanying the processes of solid bodies deformation allowed to justify and develop a method that allows to obtain non-contact information about changes in the stress-strain state in various types of geomaterials, including limestones. However, studies of the water saturation influence of rocks on the thermal radiation parameters recorded in this way are currently superficial. Taking into account the water saturation degree of rocks is necessary when monitoring the mechanical condition of stone structures that are in direct contact with water. The main purpose of this work is to study the dependences of changes in the intensity of thermal radiation from the surface of limestone samples with different humidity under conditions of uniaxial compression. The obtained results showed the expected significant decrease in the mechanical properties (uniaxial compressive strength and elastic modulus) of water-saturated samples in comparison with dry ones. At the same time, a significant increase in the intensity of thermal radiation of limestone samples subjected to compression with an increase in their water saturation was recorded, which makes it necessary to take into account the revealed regularity when identifying changes in the stress state of stone structures established according to non-contact IR diagnostics in real conditions.
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Date submitted2019-05-07
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Date accepted2019-07-25
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Date published2019-10-23
Intensification of Bacterial-Chemical Leaching of Nickel, Copper and Cobalt from Sulfide Ores Using Microwave Radiation
- Authors:
- A. V. Kioresku
Currently, Russia and other countries display a steady tendency to decrease the amount of high grade and free- milling ore reserves. In this regard, the attention is being paid to the technology of bacterial-chemical leaching (BCL), which, unlike traditional pyrometallurgical enrichment methods, is well applicable for processing low-grade mineral raw materials. However, this technology has a significant drawback, which is the inability of microorganisms to create sufficiently aggressive conditions for the effective destruction of mineral complexes, which negatively affects the duration of the processes. The article presents the results of an experiment, the purpose of which was to study the multiple short-term effects of microwave radiation on the efficiency of extraction of nickel, copper, and cobalt in the process of bacterial-chemical leaching of sulfide ore. A microwave oven with a power of 900 W and a radiation frequency of 2.45 GHz was used as a source of microwave radiation. Irradiation was carried out every day throughout the experiment. The exposure time was 5 and 10 s; the flux density was 0.7 W/cm 2 . It was found that for all the studied microwave irradiation modes, a significant increase in the efficiency of biomass accumulation and the oxidizing ability of the medium was observed in comparison with the control that was not exposed to microwave radiation. Irradiation for 5 s twice a day increased the reduction of nickel by 16 %, cobalt by 15 % and copper by 6 %. The results of the study allow us to assess the prospects for the application of new biotechnology methods in the industrial practice of ore processing with an improvement in qualityindicators.
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Date submitted2015-10-23
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Date accepted2015-12-19
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Date published2016-08-22
Nondestructive techniques to control the quality and quantity of oil flows
- Authors:
- R. M. Proskuryakov
- A. V. Kopteva
The article considers the issue of improving the efficiency of exploiting the acting oil fields and transportation system on the basis of modern hi-tech technologies to control the extracted and transported material. Factors are studied that lower the reliability of oil flow measurements, both qualitatively and quantitatively, the main ambiguities are described of using current systems for metrological account of oil transported through the pipelines. The effect is studied of inclusions in the transported oil flow on measurement efficiency. A technique is suggested for selective measurements of separate phases in the complex multi-phase flows with isotropic radio emission, the principal relationships are presented to describe the intensity of direct and scattered gamma-radiation on flow parameters. Criteria are given for developing a measurement system that would control the actual component composition of the flow with time, hence the amount of oil transported; that would enable organizing a centralized open department to control the quality of oil and transportation conditions, upgrade the level of production and provide high measurement accuracy. Results are presented of testing the technique on an operating oil field; the relative error margin of measuring free gas content was 0.2 %. The range is reviewed of possible applications for the measurement system of multi-phase multi-component flows, developed in the Saint Petersburg Mining University.
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Date submitted2009-08-23
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Date accepted2009-10-17
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Date published2010-02-01
Mathematical description of microwave contact level controller for liquid agent
- Authors:
- N. V. Teterin
- O. M. Bolshunova
It is shown the problem of measurement of level in oil tanks. Considered the use of a method of the sway electromagnetic radiation for the control of level of section of environments in tanks, made its mathematical description, resulted the estimation of results of practical application.