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Vol 150 No 1
Pages:
116-119
Download volume:
RUS
Research article
Metallurgy

Study of ionic exchange in soils for the purpose of their purification from heavy metals

Authors:
M. V. Ivanov1
D. E. Chirkst2
About authors
  • 1 — Student, research assistant G.V. Plekhanov Saint Petersburg Mining University
  • 2 — Professor G.V. Plekhanov Saint Petersburg Mining University
Date submitted:
2001-06-07
Date accepted:
2001-07-15
Date published:
2002-03-14

Abstract

Adsorption of strontium and iron from aqueous solutions on various minerals was studied. According to the sorption capacity, the studied minerals can be arranged in the following sequence: Cambrian clay ~ kaolinite > potassium feldspar > albite > oligoclase. This sequence correlates well with the specific surface of the studied minerals determined by thermal argon desorption and their exchange capacity determined by methylene blue adsorption. Coefficients of distribution of Sr 2+ and Fe 3+ between minerals and aqueous solutions and ionic exchange constants between Sr 2+ and Fe 3+ were determined. The value of the latter value was 23.6 for albite and 17.1 for oligoclase. Therefore, aqueous solutions of iron (III) may be recommended for cleaning soils from strontium contamination.

Иванов М.В., Чиркст Д.Э. Изучение ионного обмена в грунтах с целью их очистки от тяжелых металлов // Записки Горного института. 2002. Т. 150 № 1. С. 116-119.
Ivanov M.V., Chirkst D.E. Study of ionic exchange in soils for the purpose of their purification from heavy metals // Journal of Mining Institute. 2002. Vol. 150 № 1. p. 116-119.
Go to volume 150

References

  1. Патент № 2050029 РФ. Способ дезактивации почвогрунтов от радионуклида цезия-137 / Д.Э.Чиркст, К.Н.Чалиян, А.Г. Чалиян. Опубликован в Б.И. 1995. № 4. С. 252.
  2. Изучение прочности связывания изотопов цезия и стронция в илах радиоактивно загрязненных водоемов/ Э.А.Чувелева, Л.А.Фирсова, В.В.Милютин, В.М.Гелис, С.И.Ушаков // Радиохимия. 1996. Т.38. № 6. С. 554-557.
  3. Кинетика десорбции радионуклидов 137Cs и 90Sr с почвогрунтов, загрязненных в результате аварии на ЧАЭС / Д.Э.Чиркст, К.Н.Чалиян, А.Г.Чалиян, Н.Р.Андреева // Радиохимия. 1996. Т.38. № 1. С.88-90.
  4. Dibrov L.A. Leaching of 37Cs and 90Sr contaminated soils by FeCl3 and NH4C1 soluions / I.A.Dibrov, D.E.Chirkst, K.N.Chaliyan // Environmental Technology. V.20. P.575-585.

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