Application of the second beginning of thermodynamics to electrolysis of sodium chloride solution

G. E. Itkin; A. P. Gorshenin; D. E. Chirkst

Vol 165

Pages:

88-90

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Application of the second beginning of thermodynamics to electrolysis of sodium chloride solution

Authors:

G. E. Itkin¹

A. P. Gorshenin²

D. E. Chirkst³

About authors

1 — G.V. Plekhanov Saint Petersburg Mining Institute
2 — G.V. Plekhanov Saint Petersburg Mining Institute
3 — G.V. Plekhanov Saint Petersburg Mining Institute

Date submitted:

2004-12-05

Date accepted:

2005-01-30

Date published:

2005-11-22

Abstract

In this paper it is shown that if in the electrolytic process the charge carriers do not participate in the electrode reaction, the Faraday minimum is not fulfilled. In this case, the electrolytic process agrees with the second law of thermodynamics in the following formulation "The work of the flow of electricity in an electrochemical system is spent on chemical reaction, heat generation and entropy drop due to physical processes".

Иткин Г.Е., Горшенин А.П., Чиркст Д.Э. Приложение второго начала термодинамики к электролизу раствора хлорида натрия // Записки Горного института. 2005. Т. 165 . С. 88-90.

Itkin G.E., Gorshenin A.P., Chirkst D.E. Application of the second beginning of thermodynamics to electrolysis of sodium chloride solution // Journal of Mining Institute. 2005. Vol. 165 . p. 88-90.

Application of the second beginning of thermodynamics to electrolysis of sodium chloride solution

Abstract

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