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Vol 196
Pages:
113-116
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RUS
Article

Effect of potassium on the solubility of aluminum hydroxide in alkaline aluminate solutions аnd their decomposition

Authors:
V. N. Brichkin1
E. A. Alekseeva2
N. V. Nikolaeva3
E. E. Gordyushenkov4
About authors
  • 1 — Ph.D., Dr.Sci. professor Saint-Petersburg State Mining University
  • 2 — post-graduate student Saint-Petersburg State Mining University
  • 3 — Ph.D. assistant lecturer Saint-Petersburg State Mining University
  • 4 — student Saint-Petersburg State Mining University
Date submitted:
2011-08-23
Date accepted:
2011-10-07
Date published:
2012-05-22

Abstract

Materials of calculation of solubility of aluminum hydroxide in the system Na2O – K2O – Al2O3 – H2O, by data of the solubility in the private sections of this system for a wide range of compositions aluminate solutions by the content of alkaline components are presented. It is shown that the solubility of aluminum hydroxide in the range of concentration of alkaline components from 1,29 mol/l to 1,94 mol/l is a linear function of the mol fraction of one of them. The results of experimental researches on decomposition of aluminate solutions are given. Significant increase of the degree of decomposition of aluminate solutions in per cents of the theoretical values with growth of mol fraction of K2O in a mixture of alkaline components has been established.

Область исследования:
(Archived) Metallurgy, physical and chemical regularities of technological processes
Keywords:
aluminum hydroxide solubility potassium hydroxide the decomposition
Go to volume 196

References

  1. Brichkin V.N. Kinetics of decomposition of aluminate solutions in the system Na2O – K2O – Al2O3 – H2O / V.N.Brichkin, V.V.Radko, V.V.Vasilyev, N.A.Novikov // Non-Ferrous Metals of Siberia – 2009. Krasnoyarsk, 2009. P.162-165.
  2. Liner Y. Solubility isotherms in the system Na2O – K2O – Al2O3 – H2O at 20, 60 and 95 C / A. Liner, I.Kitler // Metallurgy of nonferrous and rare metals. 1968. P.191-194.
  3. The Metallurgy of nonferrous metals. Alumina / Ed. by Y.V.Baimakova, Y.E.Kantorovich. Moscow, 1970. 320 p.
  4. Leyteyzen M.G. Settlement density of sodiumpotassium aluminate-alkaline solutions at a temperature of 25 C / M.G.Leyteyzen, T.I.Vinogradova // Alumina. VAMI. 1975. N 91. P.128-129.
  5. Yanli Xie. Study on the effect of K2O on seed precipitation in sodium aluminate liquors / Yanli Xie, Qun Zhao, Zhenan Lu, Shiwen Bi // Light Metals. 2006. P.159-163.

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