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Vol 238
Pages:
423
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Efficiency Estimation of the Single- and Multicomponent Anti-hydrate Reagents

Authors:
N. A. Shostak1
E. P. Zaporozhets2
About authors
  • 1 — Kuban State Technological University ▪ Orcid
  • 2 — Kuban State Technological University
Date submitted:
2019-03-05
Date accepted:
2019-05-03
Date published:
2019-08-25

Abstract

Different types of technological and technical problems in the oil, gas and chemical industries are connected with the hydrate formation process and with the using of anti-hydrate chemicals. That is why, it is necessary to estimate thermobaric ranges within which reagents does not let hydrate to grow or is their dissociation. Also, to estimate anti-hydrate influence we need to determine the chemicals’ anti-hydrate efficiency and chose the best one. They make the reagents consisting of several chemical components depending on the purpose of their application – for prevention of formation and (or) elimination of hydrates. It demands calculations of the optimum concentration and expenses and also the intensity (speed) of hydrates dissociation causing with the reagents. The analytical method of the anti-hydrate chemical reagents efficiency determination containing one or several components from different classes of chemical compounds – alcohols, salts, acids, compounds of nitrogen and oxygen – is presented in this paper. With its help it is possible to define decrease in temperature of hydrate formation from reagents influence, to count key parameters of reagents anti-hydrate efficiency depending on component compositions of hydrate gas and a phase condition of a hydrate-gas system, to select types of chemical components and their quantity in multicomponent reagents, i.e., to make new compounds. The method can be used for express assessment of anti-hydrate chemical reagents efficiency on criteria sign for practical application in oil, gas and processing industry.

10.31897/pmi.2019.4.423
Go to volume 238

References

  1. Production, preparation and transport of natural gas and condensate: Spravochnoe rukovodstvo v 2 t. / Ed. by Yu.P.Korotaev, R.D.Margulov. Moscow: Nedra, 1984. Vol. 1, p. 360 (in Russian).
  2. Zaporozhets E.P., Shostak N.A. Method for calculating hydrate formation parameters from multicomponent gases. Zhurnal fizicheskoi khimii. 2016. Vol. 90. N 9, p. 1389-1395. DOI: 10.1134/S0036024416090338 (in Russian).
  3. Zaporozhets E.P., Shostak N.A. Features of hydrate formation of single and multicomponent gases. Vestnik Permskogo natsional'nogo issledovatel'skogo politekhnicheskogo universiteta. Geologiya. Neftegazovoe i gornoe delo. 2016. Vol. 15. N 20, p. 232-239. DOI: 10.15593/2224-9923/2016.20.3 (in Russian).
  4. Zaporozhets E.P., Shostak N.A. Method for calculating the equilibrium thermobaric conditions for the formation or dissociation of hydrates in multicomponent mixtures. Oborudovanie i tekhnologii dlya neftegazovogo kompleksa. 2017. N 6, p. 54-57
  5. (in Russian).
  6. Kalacheva L.P., Rozhin I.I., Fedorova A.F. Studying the effect of formation water mineralization on the hydrate formation of natural gases from deposits in the east of the Siberian Platform. SOCAR Proceedings. 2017. N 2, p. 56-61. DOI: 10.5510/OGP20170200315 (in Russian).
  7. Stupin D.Yu., Seleznev A.P., Istomin V.A. Experimental study of the conditions of hydrate formation of gas mixtures «methane-ethane-propane» in the presence of aqueous solutions of methanol. Nauchnye trudy VNIIGAZa. Tekhnika i tekhnologiya pererabotki gaza i kondensata. 1990, p. 68-79 (in Russian).
  8. Haghighi H., Chapoy A., Burgess R., Tohidi B. Experimental and thermodynamic modelling of systems containing water and ethylene glycol: Application to flow assurance and gas processing. Fluid Phase Equilibria. 2009. Vol. 276. Iss. 1, p. 24-30. DOI: 10.1016/j.fluid.2008.10.006.
  9. Haghighi H. Phase equilibria modelling of petroleum reservoir fluids containing water, hydrate inhibitors and electrolyte solutions: Submitted for the degree of Doctor of Philosophy in Petroleum Engineering. Heriot-Watt University, 2009, p. 187.
  10. Petrucci R.H., Herring F.G., Madura J.D., Bissonnette C. General Chemistry: Principles and Modern Applications: 11th Edition. Pearson Canada Inc., 2016, p. 1496.
  11. Khlfaoui B., Meniai A.H., Borja R. Thermodynamic properties of water + normal alcohols and vapor-liquid equilibria for binary systems of methanol or 2-propanol with water. Fluid Phase Equilibria. 1997. Vol. 127. Iss. 1-2, p. 181-190. DOI: 10.1016/S0378-3812(96)03129-9
  12. Mohammadi A.H., Richon D. Phase Equilibria of Methane Hydrates in the Presence of Methanol and/or Ethylene Glycol Aqueous Solutions. Industrial & Engineering Chemistry Research. 2010. Vol. 49. Iss. 2, p. 925-928. DOI: 10.1021/ie901357m
  13. Mohammadi A.H., Richon D. Gas Hydrate Phase Equilibrium in Methane + Ethylene Glycol, Diethylene Glycol,
  14. or Triethylene Glycol + Water System. Journal of Chemical & Engineering Data. 2011. Vol. 56. Iss. 12, p. 4544-4548. DOI: 10.1021/je2005038
  15. Najibi H., Kamali Z., Mohammadi A.H. Phase equilibria of carbon dioxide clathrate hydrates in the presence of methanol/ethylene glycol + single salt aqueous solutions: Experimental measurement and prediction. Fluid Phase Equilibria. 2013. Vol. 342, p. 71-74. DOI: 10.1016/j.fluid.2013.01.001
  16. Rabinovich V.A., Beketov V.C. Moist gases: thermodynamic properties. New York: Begell House Inc., 1995, р. 294.
  17. Cordray D.R., Kaplan L.R., Woyciesjes P.M., Kozak T.F. Solid-liquid phase diagram for ethylene glycol + water. Fluid Phase Equilibria. 1996. Vol. 117. Iss. 1-2, p. 146-152. DOI: 10.1016/0378-3812(95)02947-8

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