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Vol 54 Iss. 3
Pages:
78-86
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RUS
Article

Interaction of zirconium tetrachloride with titanium-containing chloride melt

Authors:
A. A. Golubev
S. V. Aleksandrovsky
A. N. Naumchik
R. A. Sandler
O. A. Dubovikov
Date submitted:
1972-09-24
Date accepted:
1972-11-23
Date published:
1973-10-05

Abstract

Melts containing titanium and zirconium chlorides are used in the production of refractory metals and their alloys. In particular, the electrolytic process of obtaining titanium zirconium powders was investigated. An equimolecular melt of NaCl and KS1 salts containing titanium di- and trichloride and zirconium tetrachloride was used as the electrolyte. The content of dissolved zirconium in the electrolyte did not exceed 0.8%.

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References

  1. Olesov Yu. G. and others. Investigation of the process of obtaining electrolytic powders of titanium zirconium alloys. Housing and communal services, 1971. vol. XLIV, No. 4,
  2. Gopienko V. G. Lower titanium chlorides and their alloys with alkali metal chlorides. Publishing House of the Central Research Institute of Metallurgy, 1968.
  3. Alexandrovsky S. V., Guskov V. M. Investigation of the process of reduction of titanium tetrachloride by sodium to lower chlorides. Izv. universities. Non-ferrous Metallurgy, 1965, No. 6.
  4. Ivanov A. I., Alexandrovsky S. V. Preparation of lower titanium chlorides by electrolysis of titanium tetrachloride. Electrochemistry. AS USSR, 1971, vol. VII, No. 6.
  5. Sandler R. A. and others. Equilibrium ratios of lower titanium chlorides in the environment of molten sodium and potassium chlorides. Izv. universities. Non-ferrous Metallurgy, 1971, No. 6.
  6. Morozov I. S. Application of chlorine in metallurgy of rare and non-ferrous metals. Science, 1966.

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