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Vol 54 Iss. 3
Pages:
130-137
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RUS
Article

Purification of selenium-containing solutions from impurities during neutralization

Authors:
I. G. Zaitseva
K. Kh. Kunyasheva
E. I. Baranov
Date submitted:
1972-09-20
Date accepted:
1972-11-21
Date published:
1973-10-05

Abstract

When selenium is extracted from copper electrolyte slurries, soda-alkaline selenium-containing solutions are usually obtained. In addition to the main component, selenium, they contain impurities: tellurium, various heavy metals, silver, iron, arsenic, mercury, etc. The main impurity is tellurium, which is isolated from the solution as hydrated dioxide by neutralization to pH = 5--6. At the same time, it is very important to remove other impurities, the ingress of which into selenium reduces its quality.

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References

  1. Anisimov S. M. et al. Separation of selenium and tellurium from platinum group metals in the form of selenite and tellurite of trivalent iron. News of higher education institutions. Non-ferrous metallurgy, 1961, No. 1.
  2. Plotnikov V. I. Coprecipitation of selenium and tellurium with metal hydroxides. Zh. NKh, 1960, No. 5 (3).
  3. Plotnikov V. I. Methods of analysis of ores and products. Tr. VNIITsvetmet, 1959, No. 5.
  4. Plotnikov V. I. Coprecipitation of small quantities of selenium and zinc with metal hydroxides. Zh. NKh, 1964, No. 9.
  5. Fundamentals of metallurgy. Vol. 1, Part 1. Metallurgy Publishing House, 1961.
  6. Chemist's Handbook, edited by B. P. Nikol'skii. Chemistry, Vol. 3, 1964.
  7. Greiver, T. N. Selecting a Method for Calculating the Solubility of Chalcogenides. News of Universities, Non-Ferrous Metallurgy, 1967, No. 5.
  8. Yatsimirskii, K. B., Vasiliev, V. P. Instability Constants of Complex Compounds. USSR Academy of Sciences, 1959.

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