Melts containing titanium and zirconium chlorides are used in the production of refractory metals and their alloys. In particular, the electrolytic process of obtaining titanium zirconium powders was investigated. An equimolecular melt of NaCl and KS1 salts containing titanium di- and trichloride and zirconium tetrachloride was used as the electrolyte. The content of dissolved zirconium in the electrolyte did not exceed 0.8%.