Interaction of zirconium tetrachloride with titanium-bearing chloride melt
Abstract
Melts containing titanium and zirconium chlorides are used in the production of refractory metals and their alloys. In particular, the electrolytic process for producing titanium-zirconium powders was investigated. An equimolecular melt of NaCl and KCl salts containing di- and trivalent titanium chlorides and zirconium tetrachloride was used as the electrolyte. The content of dissolved zirconium in the electrolyte did not exceed 0.8%.
Область исследования:
(Archived) Without section
Funding:
None
References
- Olesov Yu. G. et al. Investigation of the process of obtaining electrolytic powders of titanium-zirconium alloys. ZhPKh , 1971, vol. XLIV, No. 4 (in Russian)
- Gopienko V. G. Lower titanium chlorides and their alloys with alkali metal chlorides. Izd. TsNII tsvetnoi metallurgii , 1968 (in Russian)
- Alexandrovsky S. V., Guskov V. M. Investigation of the process of reduction of titanium tetrachloride by sodium to lower chlorides. Izv. vuzov. Tsvetnaya metallurgiya , 1965, No. 6 (in Russian)
- Ivanov A. I., Alexandrovsky S. V. Preparation of lower titanium chlorides by electrolysis of titanium tetrachloride. Elektrokhimiya. AN SSSR , 1971, vol. VII, No. 6 (in Russian)
- Sandler R. A. et al. Equilibrium ratios of lower titanium chlorides in the medium of molten sodium and potassium chlorides. Izv. vuzov. Tsvetnaya metallurgiya , 1971, No. 6 (in Russian)
- Morozov I. S. Application of chlorine in metallurgy of rare and non-ferrous metals. Nauka, 1966 (in Russian)
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