The article describes problems of blasting operations carried out at an industrial scale using ammonia-nitrate explosives. Based on experimental studies conducted by the authors, it was determined that for use in mining enterprises in Mongolia, primarily in coal mines, the most rational and effective explosives are mixed ones based on ammonium nitrate in the solid state with various liquid as well as solid dispersed fuels additives - ANFO mixtures. The temperature boundaries for the phase transitions of ammonium nitrate in open areas for the period of three months for different humidity values have been determined. The indicators of oil absorption are identified depending on the cycle of phase transitions for ammonium nitrate.