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Date submitted2022-09-30
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Date accepted2024-11-07
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Date published2025-02-25
Carbon dioxide corrosion inhibitors: current state of research and development
Among the methods of corrosion control in the oil and gas production industry the leading place belongs to inhibitor protection, since there is no need for technological and technical changes in the existing equipment. The combination of high variability of inhibitor composition with changing conditions of its application and low capital investments makes it an indispensable reagent at oil and gas fields. The main classes of compounds used as active bases of carbonic acid corrosion inhibitors for the protection of oil and gas equipment are described. Classical organic active bases containing heteroatoms (oxygen, sulfur, nitrogen) are examined. Special attention was paid to alkylimidazolines and other nitrogen-containing compounds as the most frequently used as active bases of carbonic acid corrosion inhibitors in Russia and abroad. A wide range of possibilities to achieve the desired properties of corrosion inhibitors by varying the substitutes has been demonstrated. Nowadays, in addition to the traditional requirements for corrosion inhibitors, their safety for the environment is equally important. The information on prospective research and development aimed at improving the environmental characteristics of the reagents used is given. Plant extracts, synthetic and biological polymers involved in traditional corrosion inhibitors or used as new independent compounds are considered. It is shown that the effectiveness of corrosion inhibitors significantly depends on the pH of the medium, temperature, partial pressure of СО2, flow rate, and other factors.
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Date submitted2022-02-22
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Date accepted2022-09-15
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Date published2022-11-10
The problem of the genesis of the Mesoarchean aluminosilicate rocks from the Karelian craton and their possible use as a quartz-feldspar raw material
The article presents original data obtained in the study of the chemical and mineral compositions of the Late Archean aluminosilicate rocks (formerly called silicites) from the Koikari and Elmus structures of the Vedlozero-Segozero greenstone belt of the Karelian craton (Central Karelia). A comprehensive study of these formations revealed their complex genesis as a result of the late imposition of hydrothermal and metamorphic alteration on sedimentary and volcanic-sedimentary rocks of feldspar-quartz composition. Due to the superimposed metasomatic (temperature?) impact on feldspar-quartz siltstones, Fe was removed from microinclusions in quartz and feldspar and its oxides were concentrated along the grain boundaries. Minerals such as monazite, parisite, allanite are also located either along the grain boundaries of quartz and feldspars, or together with calcite they fill microfractures, which makes it possible to get rid of them when preparing quartz-feldspar concentrates using various beneficiation technologies. According to most indicators limited by GOSTs, individual samples in their natural form meet the requirements for quartz-feldspar raw materials for use as part of batch in the production of diverse types of glass. Additional beneficiation of the feedstock (grinding, screening into narrow classes and further magnetic separation) leads to a decrease in Fe 2 O 3 content to normalized values. The resulting quartz-feldspar concentrates with various particle sizes can be used in the production of building material and fine ceramics (sanitary and ceramic products, facing and finishing tiles, artistic, household porcelain and faience). The homogeneity of the mineral and chemical composition, the possibility of compact extraction and beneficiation (including in mobile small-sized installations) increase the prospects and competitiveness of this non-traditional feldspar raw material from Central Karelia.
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Date submitted2015-10-18
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Date accepted2015-12-01
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Date published2016-08-22
Effect of surface geometry and insolation on temperature profile of green roof in Saint-Petersburg environment
- Authors:
- S. A. Ignatev
- D. S. Kessel
The paper addresses an issue of creating an environment favorable for the life in megacities by planting vegetation on the rooftops. It also provides information about rooftop greening practices adopted in other countries. The issues of ‘green roof’ building in climatic conditions of Saint Petersburg and roof vegetation impact on the urban ecosystem are examined. Vegetation composition quality- and quantity-wise has been proposed for the roof under research and a 3D model of this roof reflecting its geometric properties has been developed. A structure of roof covering and substrate qualitative composition is presented. An effect of rooftop geometry on the substrate temperature is explored. The annual substrate temperature and moisture content in different parts of the roof have been analyzed. Results of thermal imaging monitoring and insolation modelling for different parts of green roof surface are presented.
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Date submitted2015-08-25
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Date accepted2015-10-24
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Date published2016-04-22
The modern technology of drilling and casing of well during the exploration of gas hydrates
- Authors:
- N. I. Nikolaev
- Lyu Tyanle
In the paper, the perspectives of exploration and completion of gas hydrate fields and the drilling problems in the gas hydrates of the northwest china are studied. It has been established, that the main reasons of complications in the Muli field are the secondary hydrate formation on the walls of the well and drilling assembly and ice formation inside the set cement during the well drilling and completion in permafrost. It has been shown, that in the areas with permafrost during the drilling of the layers containing gas hydrates, temperature and pressure changes can lead to the dissociation of hydrates. At the same time, pressure increase in the annular space due to the gas release, can lead to the secondary formation of gas hydrates, drill string stuck, ceasing of drilling fluid circulation, which is the reason of serious trouble in the wellbore. The results of the research on the development of drilling fluids compositions, which lower the drilling troubles of permafrost, are presented. Comparative experiments have been conducted to evaluate the effectiveness of thermodynamic and kinetic inhibitors, which prevent the repeated hydrate formation. It has been established, that the kinetic inhibitors have the clear advantage: they have good inhibiting effects even with low amounts of additives. In the laboratory conditions, the researches have been conducted to evaluate the phase equilibrium of gas hydrates during their reaction with the water solutions, containing kinetic inhibitor PVP. A thin clay drilling mud has been developed on the water base, providing the holding of the temperature in the level of –2 °С and its effectiveness for the gas hydrate fields in the PRC has been shown. Casing effectiveness of unstable rocks during the drilling in the conditions of negative temperatures inside the well largely depends on their physical-mechanical properties, composition and the technical indicators of cement materials. The authors suggest the composition of quick-setting cements based on aluminum binding materials. It has been established, that the analyzed compositions have the ability to considerably improve the results of cementing.
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Date submitted2014-10-15
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Date accepted2014-12-30
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Date published2015-08-25
Method of controlling the temperature field on the basis of the Green's function
- Authors:
- Yu. V. Ilyushin
- I. M. Pershin
At the present stage of development of automatic control systems raises the question of maintaining the set temperature objects. The authors developed MetO-wild synthesis of nonlinear regulators to stabilize the temperature field, a uniform object of management on the basis of a given error. We obtained a function of the initial heating and the mathematical modeling of the process, analyzed the results. By creating a regulator there has been designed software and hardware programming language Pascal, which allows to simulate the behavior of temperature fields in an isotropic web. It is a simulation of the temperature of the system in different configurations: with different amounts of pulsed heating sources with relay control principle. Practical results of the research suggest the possibility of constructing silicon carbide heating element made in the form of an isotropic core.