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Date submitted2024-03-30
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Date accepted2024-06-13
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Date published2024-07-04
Organotin pollutants in emerging coastal-marine sediments of the Kaliningrad shelf, Baltic Sea
Based on two years of monitoring of modern bottom sediments of two sections of the Kaliningrad shelf of the Baltic Sea – “Curonian Spit” and “Northern Sambian” – an assessment of the sources of pollution with organotin compounds (OTs) and heavy metals was carried out. The content of individual organotin compounds and OTCs spectra obtained by gas chromatography with mass spectrometry of relatively coarse-grained bottom sediments indicate the presence of organotins in significant quantities – the total OTs content (ΣOTs) is from 0.6 to 8.3 ng/g. However, the content of tributyltin (TBT), the main component of anti-fouling systems for marine vessels and the most dangerous endocrine-disrupting compound among the hazardous substances for marine ecosystems, is at a low level (0-2.3 ng/g) in all studied samples and has not increased over the two-year observation period (biodegradation index 1.7-12.4). At the same time, the presence of abnormally high concentrations of mono-, triphenyl- and tricyclohexyltin in the sediments of the ”Northern Sambian” site (up to 30, 7 and 6.4 ng/g, respectively) indicates an additional source of pollution of coastal waters and shelf sediments (for example, plastic litter and agricultural runoff). The absence of significant shipping in the study areas ensures a consistently low level of pollution with tributyltin and its derivatives (less than 0.3 and 2.3 ng/g of TBT in 2017 and less than 0.1 and 1.3 ng/g in 2018 for the sites “Curonian Spit” and “Northern Sambian”, respectively), which indicates the activity of the processes of TBT transformation and self-cleaning of sandy sediments. However, the identified trends and their predictive accuracy require long-term observation and monitoring of the sediment environment using data on the deep-water part of the shelf, enriched in clay and humus components.
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Date submitted2015-12-21
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Date accepted2016-02-19
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Date published2016-12-23
Composition, age and tectonic meaning of granite boulders in the devonian conglomerates of the north-west part of Spitzbergen
- Authors:
- A. N. Sirotkin
- A. N. Evdokimov
Identifying complexes of the early Proterozoic age in the composition of crystal foundation is a key task in studying pre-Cambrian formations of the whole of Spitzbergen and its northwestern part in particular. The territory of that region is formed by three deeply metamorphosed complexes that underwent the processes of migmatization and granitization in mid-Rifey and were broken through by granitoids of mid-Rifey and mid-Paleozoic. In their turn, the outbursts of the foundation are overlayed by terrigene rocks of the Devonian graben of Spitzbergen, conglomerates forming a large share among them. In the course of petrographic and chemical studies of such compositions, as well as isotopic characteristics of zircons from the boulders of basal conglomerates of Red Bay (D 1 ) series, the suite of Wolfberget at Cape Conglomeratodden the presence was identified of reddish (meat-red) granites of isotopic age of 1631±19 Mil years, which is comparable to late Karelian processes manifested actively across the archipelago. It is also proven that transformations of these rocks within the range of 380±42 Mil years are well associated with mid-paleozoic events, considerable restructuring of the foundation associated with them. The age range we defined is another proof of manifestation of early pre-Cambrian (late Karelian) processes in the northwestern Spitzbergen.