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Date submitted2022-01-16
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Date accepted2022-04-06
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Date published2023-04-25
Production of biodiesel fuel from vegetable raw materials
One way to reduce the amount of harmful emissions from diesel fuel could be the replacement of part of the fuel with biofuel. Research is related to the production of biodiesel fuel in three ways: transesterification of vegetable oils; esterification of fat acids extracted from vegetable oil; and hydroprocessing of vegetable oils using catalysts in the diesel hydrotreatment process. Food and non-food oils, monatomic and diatomic alcohols were used to produce biodiesel fuel. Optimal parameters of vegetable oil transesterification have been determined: temperature; raw material ratio (oil/alcohol); mixing speed; time; type of process catalyst. The characteristics of the obtained biodiesel fuel samples were studied and compared with each other as well as with the requirements of EN 14214 “Automotive fuels. Fat acid methyl ethers for diesel engines. General technical requirements” and EN 590:2009 “EURO diesel fuel. Technical specifications”. With regard to the physical and chemical characteristics of biodiesel fuel, the best way to produce it is by transesterification of vegetable oils. However, all fuels can be used as components of a blended environmentally friendly diesel fuel.
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Date submitted2022-03-17
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Date accepted2022-06-20
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Date published2022-11-03
Assessment of collecting activity of physically sorbed reagents on the example of easily floatable coking coal sludge
- Authors:
- Sergey A. Kondratev
- Tatyana A. Khamzina
The article presents one of the new approaches to theoretical assessment of collecting ability of reagents. The efficiency of reagents-collectors with different chemical composition used for flotation of coking coals was studied. A comparative assessment of the flotation activity of kerosene, mineral oil, thermal gas oil, KETGOL and FLOTEK is given. The criteria of collecting activity of the above reagents-collectors for coal sludge flotation were specified. A correlation was established between the indicators of coal sludge flotation by the above reagents and their physical parameters. It is shown that the rate of spreading over water surface can characterize the flotation activity of reagents. Based on dependence of the collecting activity of a reagent on its rate of spreading along the “gas – liquid” interface and surface pressure, the main approaches to determining the structure and composition of molecules of an effective flotation collector can be determined. A new concept of the function performed by a physically sorbed collector in the elementary act of flotation and a criterion for the flotation activity of reagents used in coal sludge beneficiation are proposed. It is shown that the collector used in coal flotation, in addition to hydrophobizing the surface of the extracted particles, should reduce the induction time and remove the kinetic constraint on formation of a flotation aggregate.