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Date submitted2022-10-24
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Date accepted2023-03-03
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Date published2023-04-25
Use of clay-containing waste as pozzolanic additives
Growing productivity of mining and processing enterprises entails an increase in the volumes of liquid tailings impoundments and upstream impoundments of ore processing waste. Enterprises face the challenge of minimizing the environmental impact of waste and guaranteeing the sanitary and epidemiological safety of population. The article presents a possibility of recycling one type of such waste (clay-containing concentration tailings of apatite-nepheline and sylvinite ores, coal beneficiation tailings) by using them after preliminary thermochemical treatment as pozzolanic additives to cements and concretes, including concrete mixtures used for soil stabilization, development of territories, reclamation of mine workings, as a component of the insulating layer of landfills for the disposal of municipal solid waste. An analysis of the phase changes of kaolinite, one of the main minerals that make up clay-containing waste, in the temperature range of 200-1,000 °С showed that a change in its mineral form during heat treatment is the main factor in changing its pozzolanic activity. The effect of heat treatment of clay minerals at temperature of 700-800 °C on their pozzolanic activity, estimated by the ability to absorb calcium hydroxide (0.7 g Ca(OH) 2 per 1 g of modified kaolinite), is considered. It is shown that the addition of heat-treated samples (20 % by weight) improves the quality of cement increasing its activity by 15 %, in comparison with the use of unmodified clay minerals. It was proved experimentally that partial replacement of Portland cement with thermally modified kaolinite increases the strength of consolidating stowing mixture by up to 15 %. This approach to processing of ores containing layered silicates, which provides for thermochemical modification of run-of-mine ore, intensifies the processes of tailings thickening and filtering.
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Date submitted2018-11-20
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Date accepted2019-01-14
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Date published2019-04-23
Low-density cement compositions for well cementing under abnormally low reservoir pressure conditions
- Authors:
- N. I. Nikolaev
- E. L. Leusheva
The paper considers variants of lightweight cement compositions with additives of various substances, such as clay components, ash systems, silica additives, kerogen, gilsonite, microspheres, as well as the process of cement slurry aeration. Recommendations on the use of compositions in different conditions are presented. A decrease in the density of the solution is achieved not only due to the low density of the materials used, but also as a result of an increase in the water-cement ratio. In such conditions, it is not possible to ensure the formation of a durable and impermeable cement stone in the well, which creates high quality inter-reservoir insulation. The characteristics of the physical and mechanical properties of existing lightening additives are given, which allows determining the most rational conditions for the use of cement slurries for improvement of the well cementing quality.