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Date submitted2018-11-09
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Date accepted2019-01-08
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Date published2019-04-23
Effect of chalk thermal treatment mode on its strength
- Authors:
- V. A. Lipin
- D. A. Trufanov
Natural chalk is characterized by a fine-grained structure. The processing of chalk in conditions traditional for calcium carbonate baking is accompanied by its almost destruction and the formation of a huge amount of dust. The paper presents strength characteristics of chalk and chalky stone baking obtained with different temperature-time conditions of heating the raw material to a temperature of 450-600 °C. The uniaxial compression method was used to determine the strength depending on variable factors. Based on the experimental data, a model was constructed that determines the dependence of chalk strength on time and heating temperature. In the temperature range of 450-600 °C, the strength of chalk stone increases with increasing temperature and decreases with the increasing heating rate. In the process of isothermal heating, several factors will immediately affect the strength of a chalky stone: the formation and growth of calcite crystals, the evaporation of water, and the agglomeration of calcite grains. With an increase in the heating temperature from 450 to 600 °C, the average size of the crystals significantly increases and crystals with an estimated size of more than 4 microns are detected. An increase in the size of crystals is associated with an increase in their growth rate. The agglomeration of grains occurs at a temperature of 600 °C.
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Date submitted2018-01-15
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Date accepted2018-02-28
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Date published2018-06-22
About the role of hydrafed calcium carboaluminates in improving the technology of complex processing of nephelines
- Authors:
- V. M. Sizyakov
- V. N. Brichkin
The scientific justification and development of the method for industrial synthesis of complex aluminates of alkaline earth metals is an innovative solution that determined several directions in the development of technology for complex processing of nepheline raw materials. It ensures the production of high-quality metallurgical alumina, the effective utilization of nepheline sludge and production of new types of multipurpose by-products. The modern development of these technical solutions is associated with ensuring the energy efficiency of the synthesis of hydrafed calcium carboaluminates (HCCA) and increasing the level of purification of aluminate solutions. The conditions for synthesizing HCCA with the use of calcareous materials of natural and technogenic origin have been experimentally determined, which makes it possible to isolate the average particle diameter as one of the determining factors of this process. The effect of the turnover of the hydrogarnet sludge on the removal of kinetic limitations in the process of deep desalination of aluminous solutions is theoretically justified. The conditions of a two-stage dosage of HCCA are experimentally determined. It is shown that the optimum ratio of the amount of the reagent supplied in the first and second stages is about 3: 2. At the same time, the maximum degree of precipitation of silica provides the production of aluminate solutions with a silicon module at the level of 95,000, which is achieved by using a HCCA synthesized based on chemically precipitated calcium carbonate in the processing of wastes from the production of mineral fertilizers.
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Date submitted2014-07-21
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Date accepted2014-09-19
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Date published2014-12-22
Preliminary preparation of oil for primary processing
Oil supplied for primary processing always undergoes preliminary preparation, the purpose of which is to eliminate the harmful effect of water and salt contained in the oil. It is thought that corrosion of the equipment is connected mainly with chlorides of magnesium and calcium, which are subjected to hydrolysis with the formation of hydrochloric acid. Under the influence of hydrochloric acid the destruction (corrosion) of metal equipment at technological plants occurs (especially refrigerating-condensing and heatexchange equipment, furnaces of rectification units etc.). The authors of the article, on the basis of thermodynamic calculations, provide their point of view on this process and give a methodology by which the process of preliminary oil dehydration and desalting can be controlled. The thermodynamic calculations executed for standard conditions on the basis of refer-enced data confirm a high probability of chemical interaction of iron with hydrogen ions, hy-drogen sulphide and especially with carbonic acid. This testifies to high activity of the carbon dioxide dissolved in water and the impossibility of hydrolysis of ions of magnesium, calcium and iron. The calculations show that only the hydrolysis of magnesium chloride is possible tak-ing into account the ionic composition of the water phase in the oil. It should be noted that the presence of ions of chlorine shifts the iron potential in a nega-tive direction and increases the speed of corrosion of petrochemical equipment. The solution of this problem is in the development of modern methods of crude oil dehydration and desalting. It is also, however, in an intensification of the processes of mixing water-oil emulsions with wash-ing water by using various physical fields (for example, ultrasound) and creating new effective mixing devices on the basis of them.