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Vol 142
Pages:
172-176
Download volume:
RUS
Article

Prediction of solubility of materials containing iron oxide-sulfide associations in sulfuric acid media

Authors:
T. A. Orlova
Date submitted:
1994-09-11
Date accepted:
1994-11-05
Date published:
1995-09-12

Abstract

Thermodynamic calculations performed on the computer by the proposed method determined the possibility of predicting the degree of sulfuric acid decomposition of iron oxide-sulfide associates of different composition and phase ratio. The high probability of galvanic interactions between the components of associates during their dissolution was shown.

Область исследования:
Metallurgy
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References

  1. Iudina N.N. Influence of deviation from stoichiometry on some physical properties of pyrrhotite and its leaching behavior: Cand.Cand.Dis./MISIS. М., 1971.
  2. Metallurgy of copper, nickel and cobalt. Per. from Engl. M.: Metallurgy, 1983.
  3. Orlova T.A. Study of physicochemical regularities of sulfuric acid decomposition of thermally prepared polymetallic sulfide materials in relation to the creation of complex technology of their processing: Cand. / Leningrad Mining Institute. L., 1991.
  4. Sveshnikov G.B. Electrochemical processes at sulfide deposits. L.: Chemistry, 1970.
  5. Slobodov A.A. Thermodynamic modeling of solubility of iron, cobalt and copper corrosion products in aqueous solutions at 298-623 K: Cand.Cand.Dis. / Lensovet LTI. L., 1986.
  6. Snurnikov A.P., Larin V.F. Study of interaction of iron sulfides with sulfuric acid // Journal of Applied Chemistry. 1966. Vol.34. Issue 12.
  7. Jazava A., Equchi M. // Bull.Res.Inst.Min.Dress and Met.Tohoku Univ. 1967. №23.
  8. Warren I.H., Roach G.I.D. // Inst. of Mining and Metall.Trans., sec. C. 1971/ Vol.80, B. 152.

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