Application of the second beginning of thermodynamics to electrolysis of sodium chloride solution
About authors
- 1 — G.V. Plekhanov Saint Petersburg Mining Institute
- 2 — G.V. Plekhanov Saint Petersburg Mining Institute
- 3 — G.V. Plekhanov Saint Petersburg Mining Institute
Abstract
In this paper it is shown that if in the electrolytic process the charge carriers do not participate in the electrode reaction, the Faraday minimum is not fulfilled. In this case, the electrolytic process agrees with the second law of thermodynamics in the following formulation "The work of the flow of electricity in an electrochemical system is spent on chemical reaction, heat generation and entropy drop due to physical processes".
Similar articles
Effective solution of problems of information support of metallurgical enterprises
2005 V. V. Karpov
Goniometric attachment to diffractometer DRON-7 for texture and macro stress analysis
2005 V. N. Anisimov, V. A. Lifshits, A. V. Malkov, V. A. Pronichev, V. A. Firsova
Principles of construction and examples of realization of intellectual simulators for ore-thermal production
2005 T. B. Chistyakova, O. V. Ershova
Features of chemical interactions occurring during atmospheric copper cleaning of nickel-cobalt solution in the technology of sulfuric acid leaching of high-copper matte
2005 A. V. Vydysh, M. N. Naftal, A. F. Petrov, I. V. Batsunova, A. G. Morachevskii