Application of the second beginning of thermodynamics to electrolysis of sodium chloride solution
About authors
- 1 — G.V. Plekhanov Saint Petersburg Mining Institute
- 2 — G.V. Plekhanov Saint Petersburg Mining Institute
- 3 — G.V. Plekhanov Saint Petersburg Mining Institute
Abstract
In this paper it is shown that if in the electrolytic process the charge carriers do not participate in the electrode reaction, the Faraday minimum is not fulfilled. In this case, the electrolytic process agrees with the second law of thermodynamics in the following formulation "The work of the flow of electricity in an electrochemical system is spent on chemical reaction, heat generation and entropy drop due to physical processes".
Область исследования:
(Archived) Without section
Funding:
None
Similar articles
Involvement of technogenic raw materials in autoclave oxidizing technology of pyrrhotite concentrates processing
2005 I. N. Khramtsova, R. D. Shestakova, A. F. Petrov, I. I. Asanova, G. A. Kropachev, I. V. Dmitriev, I. V. Volyanskii, L. V. Panfilova
Development of technology for enrichment of platinum-metal ores of the Pan massif of the Kola Peninsula
2005 V. I. Beloborodov, I. B. Zakharova, A. N. Kulakov, V. I. Kolomiets, M. Yu. Chernyakova
Investigation of crystallization patterns of high copper/nickel ratio matte with increased copper/nickel ratio
2005 I. G. Fokeeva, L. B. Tsymbulov, L. N. Ertseva
Development of modes of thickening of products of Nadezhda Metallurgical Plant using different flocculants
2005 R. D. Shestakova, A. F. Petrova, I. I. Asanova, I. G. Sushkova