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Vol 196
Pages:
121-124
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RUS
Article

Removal of samarium (3+) and cerium (3+) from nitrate and chloride solutions by ion flotation

Authors:
N. V. Dzhevaga1
D. E. Chirkst2
O. L. Lobacheva3
L. V. Grigoreva4
About authors
  • 1 — post-graduate student Saint Petersburg State Mining University
  • 2 — Ph.D., Dr.Sci. professor Saint Petersburg State Mining University
  • 3 — Ph.D. associate professor Saint Petersburg State Mining University
  • 4 — Ph.D. associate professor Saint Petersburg State Mining University
Date submitted:
2011-08-14
Date accepted:
2011-10-08
Date published:
2012-05-22

Abstract

The ion flotation of cerium (3+) and samarium (3+) from nitrate solutions by use of sodium dodecyl sulphate as a collector with addition of sodium chloride has been stated. The ratio of distribution coefficients and separation coefficient as function of the pH-aqueous phase with different concentration of chloride-ions has been analyzed. The separation coefficient has rise from 1,3 till 4,75 when chloride has been added.

Область исследования:
(Archived) Metallurgy, physical and chemical regularities of technological processes
Keywords:
ion flotation distribution coefficients separation coefficient rare-earth metals
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References

  1. Kreshkov А.P. Fundamentals of Analytical Chemistry. Theoretical basis. Quantitative analysis. Мoscow, 1976. 480 p.
  2. Pat. N 2320738 RP. Method of separation of yttrium and cerium / D.E.Chirkst, T.E.Litvinova, V.S.Starshinova, D.S.Lutskiy/ Publ. 27.03.2008.
  3. Savin S.B. Arsenazo III. Мoscow, 1966. 265 p.
  4. Thermodynamic study of ion flotation erbium / D.E.Chirkst, O.L.Lobacheva, I.V.Berlinskiy, S.А.Levichev // Messenger SPSY. Series physics, chemistry. 2009. Issue 4. P.88-93.
  5. Timopheev S.V., Materova V.А., Arkchangelskiy L.К. / Electrode behavior of the ion-selective membranes in surfactant solution // Vestnik LSY. Series physics, chemistry. 1978. N 16. Issue 3. P.139-141.
  6. Chirkst D.E., Lobacheva O.L., Berlinskiy I.V. Thermodynamic properties hydroxide combination and mechanism of ion flotation of cerium, europium and yttrium // JPC. 2009. Vol.82. Issue 11. P.1-6.
  7. Chirkst D.E., Litvinova T.E., Starshinova V.S., Lutskiy D.S. Extraction of cerium (III) and yttrium (III) of the naphthenic acid chloride conditions // Notes of the Mining Institute. 2006. Vol.169. P.204-208.

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