Thermodynamic of lanthanum (iii) and samarium (iii) extraction by using stoichiometric concentration solutions of naphtenic acid
About authors
- 1 — National Mineral Resources University (Mining University)
- 2 — National Mineral Resources University (Mining University)
- 3 — National Mineral Resources University (Mining University)
- 4 — National Mineral Resources University (Mining University)
- 5 — National Mineral Resources University (Mining University)
Abstract
Experimental data on solvent extraction of lanthanum (III) and samarium (III) by solutions of naphthenic acid from nitrate medium was obtained. Dependences of distribution coefficient of pH, concentration of organic and aqueous phase was obtained. thermodynamic characteristics of extraction equilibrium was calculated.
References
- Вольдман Г.М. Теория гидрометаллургических процессов / Г.М.Вольдман, А.Н.Зеликман. М., 2003. 464 с.
- Гиндин Л.М. Экстракционные процессы и их применение. М., 1984. 144 с.
- Михайличенко А.И. Редкоземельные металлы / А.И.Михайличенко, Е.Б.Михлин, Ю.Б.Патрикеев. М., 1987. 232 с.
- Flett D.S. Solvent extraction in hydrometallurgy: the role of organophosphorus extractants // Journal of Organometallic Chemistry. 2005. Vol.690. P.2426-2438.
- Miller F. Carboxylic acids as metal extractants // Talanta rev. 1974. Vol.2. P.685-703.
- Singh D.K. Extraction of rare earths and yttrium with high molecular weight carboxylic acids / D.K.Singh, H.P.Singh, J.N.Mathur // Hydrometallurgy. 2006. Vol.81. P.174-181.
- Preston J.S. Solvent extraction of metals by carboxylic acids // Hydrometallurgy. 1985. Vol.14. P.171–188.
Similar articles
The role of mineralized additivies in the alumina phase transformation process
2013 V. M. Sizyakov, O. A. Dubovikov, N. V. Nikolaeva, M. I. Kalashnikova
Application of high-level calcium carbonate for synthesis products in the system NA2O–AL2O3–CAO–CO2–H2O
2013 V. N. Brichkin, V. M. Sizyakov, V. V. Vasilev, E. E. Gordyushenkov
Control and management e of electric arc ratio in ore-smelting furnace
2013 A. P. Suslov, N. I. Koteleva, Yu. L. Zhukovskii, V. V. Vasilev