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Vol 202
Pages:
92
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Thermodynamic of lanthanum (iii) and samarium (iii) extraction by using stoichiometric concentration solutions of naphtenic acid

Authors:
D. S. Lutskii1
T. E. Litvinova2
D. E. Chirkst3
V. A. Lutskaya4
S. V. Zhukov5
About authors
  • 1 — National Mineral Resources University (Mining University)
  • 2 — National Mineral Resources University (Mining University)
  • 3 — National Mineral Resources University (Mining University)
  • 4 — National Mineral Resources University (Mining University)
  • 5 — National Mineral Resources University (Mining University)
Date submitted:
2012-09-15
Date accepted:
2012-11-20
Date published:
2013-03-01

Abstract

Experimental data on solvent extraction of lanthanum (III) and samarium (III) by solutions of naphthenic acid from nitrate medium was obtained. Dependences of distribution coefficient of pH, concentration of organic and aqueous phase was obtained. thermodynamic characteristics of extraction equilibrium was calculated.

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References

  1. Вольдман Г.М. Теория гидрометаллургических процессов / Г.М.Вольдман, А.Н.Зеликман. М., 2003. 464 с.
  2. Гиндин Л.М. Экстракционные процессы и их применение. М., 1984. 144 с.
  3. Михайличенко А.И. Редкоземельные металлы / А.И.Михайличенко, Е.Б.Михлин, Ю.Б.Патрикеев. М., 1987. 232 с.
  4. Flett D.S. Solvent extraction in hydrometallurgy: the role of organophosphorus extractants // Journal of Organometallic Chemistry. 2005. Vol.690. P.2426-2438.
  5. Miller F. Carboxylic acids as metal extractants // Talanta rev. 1974. Vol.2. P.685-703.
  6. Singh D.K. Extraction of rare earths and yttrium with high molecular weight carboxylic acids / D.K.Singh, H.P.Singh, J.N.Mathur // Hydrometallurgy. 2006. Vol.81. P.174-181.
  7. Preston J.S. Solvent extraction of metals by carboxylic acids // Hydrometallurgy. 1985. Vol.14. P.171–188.

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