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Vol 46 Iss. 3
Pages:
115-120
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RUS
Article

Some methods of cobalt extraction from dilute ammonia solutions

Authors:
A. B. Lipin
Date submitted:
1965-09-06
Date accepted:
1965-11-28
Date published:
1966-11-23

Abstract

The advantage of ammonia leaching of cobalt-bearing ores after reduction roasting is the possibility of almost complete separation of iron. However, the concentration of cobalt in solution after ammonia leaching of poor ores is very low, which causes difficulties in their further processing.Precipitation of cobalt from ammonia solution in the form of sulfide. The solubility of cobalt sulfide in ammonia solutions is negligible, so when sulfides Na2S, (NH4)2S are introduced into solution, cobalt ammoniacates are destroyed and metal sulfide is precipitated.

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References

  1. Gindin L.M. et al. Extraction-electrolysis method for obtaining high purity cobalt. Non-Ferrous Metals, No. 12, 1961.
  2. IlluvievaG. V. Application of ionites for extraction of some non-ferrous metals from dilute solutions. Proc. vuzov, Non-Ferrous Metallurgy, No. 2, 1963.
  3. Kasherininov G.O. Research of the process of ammonia leaching of cobalt from poor oxidized ores. Author's abstract of cand. diss., 1954.
  4. Materova E.A., Ehrenkrantz P.V. Exchange of nickel ions on sulfo-cationites. In the collection: Chromatography. PH LSU, 1956.
  5. Chernobrov S. M., Gorelik E. M. Application of Ionites in Hydrometallurgy of Nickel and Cobalt. Proc. of Gipronickel Institute, vol. 3, 1958.
  6. Redlik M. Hutnickie Letters 2, No. 13, 1958.

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