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Vol 54 Iss. 3
Pages:
114-118
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RUS
Article

Kinetics of heterogeneous ion exchange reaction between copper sulfate and cobalt or nickel naphthenate

Authors:
E. I. Pavlova
G. V. Illyuvieva
Date submitted:
1972-09-20
Date accepted:
1972-11-27
Date published:
1973-10-05

Abstract

Heterogeneous equilibria involving metal carboxylates have been studied in sufficient detail. Based on the results of these studies, an extraction series of elements has been compiled, which makes it possible to predict the direction of possible ion exchange reactions. At the same time, the kinetics of heterogeneous processes of this kind has not been studied, which prevents the elucidation of the mechanism of the reactions and the correct choice of equipment for the process.

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References

  1. Illyuvieva, G. V. Extraction Properties of Naphthenic Acids. Zap. LGI, 1966, Vol. XLVI, Issue 3.
  2. Abramzon, A. A. Study of the Kinetics of Heterolytic Reactions in Liquid-Liquid Systems. Abstract of a Doctoral Dissertation, LTI, 1968.
  3. Pavlova, E. I. Methodology for Studying Extraction Kinetics. In: New Research in Metallurgy, Chemistry, and Beneficiation. Issue 2. LGI Publ., 1971.
  4. Kletenik, Yu. B., Navrotskaya, V. A. Kinetics of Iron Extraction with Diisoamylphosphoric Acid. J. A. Kh., No. 7, 1969, Vol. 7, p. 1900.
  5. Kletenik, Yu. B., Navrotskaya, V. A., Potapova, A. I., "On a Method for Studying the Dependence of Metal Extraction Rate on Specific Surface Area of ​​the Phase Interface." Izvestiya SB RAS, Chem. Ser., 1970, No. 4, Issue 2.
  6. Spivakov, B. Ya., Zolotov, Yu. A., "Exchange Extraction of Complex Compounds (Review). J. A. Kh., 1970, Vol. 25.
  7. Adrain, A. Morrow, A. Warren Spring Lab., May, 1965.

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