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Vol 54 Iss. 3
Pages:
41-49
Download volume:
RUS
Article

Interaction of ferric chloride with the solid and gaseous phases during chloride volatilization

Authors:
I. N. Piskunov
A. K. Orlov
A. N. Gurov
Yu. M. Smirnov
E. S. Alyavdina
Date submitted:
1972-09-20
Date accepted:
1972-11-17
Date published:
1973-10-05

Abstract

Despite significant advances achieved in the development of methods for selective chlorination and chloride volatilization of materials containing nickel, cobalt and copper, iron chlorides remain an indispensable component of both the gas phase and the condensate. This indicates the possibility of interaction of gaseous ferric chloride with oxides of non-ferrous metals in the chlorination zone and with oxygen in the condensation system. As a result of the latter process, iron is converted from gaseous chloride to solid oxide, which improves the selectivity of the condensate, and the released chlorine can be returned to the chloride volatilization process. The present work is devoted to the study of some regularities of these processes.

Область исследования:
(Archived) Without section
Funding:

None

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References

  1. Babenko A. R., Leontiev G. I. Chlorinating roasting of pyrite cinders in a fluidized bed. Byull. Tsvetnaya metallurgiya , 1961, No. 17 (in Russian)
  2. Babenko A. R., Burov G. D., Slyunkov V. K. Semi-industrial tests of chlorinating roasting of copper pyrite cinders in a fluidized bed. Byull. Tsvetnaya metallurgiya , 1964, No. 1 (in Russian)
  3. Motornaya G. A., Gnatyshenko G. I., Benyash E. Ya. Low-temperature chlorinating roasting of cobalt-containing pyrite cinders. Sb. trudov VNIItsvetmeta . Ust-Kamenogorsk, 1967, issue 10 (in Russian)
  4. Denisov S. I. Study of physico-chemical conditions of separate chlorination of nickel, cobalt, and iron. Author's abstract of Cand. diss., LGI, 1960 (in Russian)
  5. Orlov A. K., Piskunov I. N. On the regularities of the cobalt chloride volatilization process from pyrite concentrate cinders. Zapiski Gornogo Instituta, 1963, vol. XLII, issue 3 (in Russian)
  6. Orlov A. K. The influence of a gaseous medium on some patterns of chloride volatilization. Zapiski Gornogo Instituta, 1966, vol. XLVI, issue 3 (in Russian)
  7. Smirnov Yu. M., Orlov A. K. On the kinetics of chlorination of nickel oxide with chlorine gas. Sb.: "Novye issledovaniya v khimii, metallurgii, obogashchenii". Izd. LGI , 1971, issue 2 (in Russian)
  8. Smirnov Yu. M., Orlov A. K. On the role of ferric chloride in chloride volatilization processes. Sb.:"Novye issledovaniya v khimii, metallurgii, obogashchenii". Izd. LGI , 1969, issue 1 (in Russian)
  9. Gurov A. N., Orlov A. K. Study of the kinetics of the interaction of ferric chloride with oxygen. Sb.: Novye issledovaniya v khimii, metallurgii, obogashchenii. Izd. LGI 1971, issue 3 (in Russian)
  10. Denbig K. G. Theory of chemical reactors. Nauka, 1968 (in Russian)
  11. Gurov A. N., Orlov A. K., Piskunov I. N. Study of the equilibrium of the reaction of iron oxide with chlorine. Izv. vuzov. Tsvetnaya metallurgiya , 1971, No. 6 (in Russian)
  12. Leveshpil O. Engineering design of chemical processes. Khimiya, 1969 (in Russian)
  13. Gaigaishe P. Ann. Chim, 1948, No. 3(21)

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