The global volume of natural gas trapped in hydrate deposits far exceeds the conventionally recoverable hydrocarbon reserves. However, the high costs associated with hydrate production, transportation, and storage currently hinder the large-scale implementation of hydrate-based technologies. A promising way to reduce these costs is through phase transition technology, which involves СН₄ hydrate depressurization in the presence of biosurfactants, followed by СО₂ formation. This approach also enables carbon dioxide sequestration, addressing the corresponding environmental concerns. Biosurfactants, which are naturally present in many hydrate reservoirs, enhance hydrate growth and accelerate СН₄-СО₂ exchange. The newly developed method of producing highly porous ice using biosurfactants, presented in this research, provides higher formation rates, substantially reducing the time required for the process. Most importantly, this technique eliminates the risk of mixed hydrate formation – a major limitation, which hindered the replacement efficiency. As a result, the proposed sequential phase transition method decreases the total time of CO₂ hydrate synthesis by two to three orders of magnitude compared to direct СН₄-СО₂ replacement. The method is particularly effective for permafrost regions and offers a more environmentally friendly approach to developing gas hydrate deposits by minimizing methane emissions while enabling CO₂ storage.