It was examined the correlation between water-repellent properties and reactionary properties in the process of oxidation for nanostructured materials, based on steel and industry trademarks of aluminum powder. Analysis experimental data showed, that for samples, which have nanofilms on cationic tensides and silicon-organic compounds on steel there is the symbatic correlation between water-repellent properties of coatings and their protective properties. And samples, based on aluminum, have highest intensivity of oxidation with middle level of water-repellent properties.