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Vol 192
Pages:
9-14
Download volume:
RUS
Article

Ivestigation of conditions оf formation calcium hydrosulfasaluminates in the NA2O – AL2O3 – CAO – SO3 – H2O system

Authors:
V. M. Sizyakov1
E. V. Sizyakova2
E. V. Tikhonova3
About authors
  • 1 — Ph.D., Dr.Sci. professor Saint Petersburg State Mining University
  • 2 — Ph.D. assistant Saint Petersburg State Mining University
  • 3 — post-graduate student Saint Petersburg State Mining University
Date submitted:
2010-10-27
Date accepted:
2010-12-23
Date published:
2011-04-01

Abstract

Calcium hydrosulfasaluminates (GSAK) is a component of cement. They are slowly formed together with the forming of the structure of cement in water solution at measurable temperatures (0-25 °C) during about 4-6 months. Slow rate of crystallization of GSAK wasn`t allowed to treat them as self-autonomy objects for use in various technological applications. The possibility of formation of GSAK (4CaO×Al2O3×mSO3×nH2O) is proved in an environment of saturated electrolytes – aluminates solutions of alumina production. They crystallize in a short time about 1-2 hours and retain their stability in long time about 24-36 hours. This allowed for us to identify ways of their industrial use.

Область исследования:
(Archived) Innovation technology in the field of metallurgy and enrichment
Keywords:
hydrosulfasaluminate calcium alumina synthesis aluminates solution
Go to volume 192

References

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  9. Siziakov V.M., Siziakova E.V., Fokina S.B. About the mechanism of secondary losses at nepheline cakes leach-ing // I International congress «Nonferrous metals of Siberia». Krasnoyarsk, 8-10th September, 2009. P.145-151.
  10. Siziakov V.M., Siziakova E.V., Modestova S.A. The technology low-temperature leaching of nepheline cakes // I International congress «Nonferrous metals of Siberia». Krasnoyarsk, 2009. P.142-144.
  11. Soloveva E.S., Segalova E.E. Conditions of forma-tion of calciumaluminate // The colloid magazine. 1961. N23. P.306-314.
  12. Dosch W., Zur Strassen H. // Improvement of the technology of cement production. Zem. Kalk-Gips, 1967. V.20. Р.392-401.
  13. Lerch W., Ashton F.W., Boque Rl.H. The Sulfoalu-minates on Calcium // Jour. of Res., Nat. Bur. of Stand., 1929. V.2. Р.715-731.
  14. Mehta P.K. Mechanism of Expansion Associated witch Ettringite Formation // Ibid. V.1,3. Р.1-6.
  15. Mehta P.K., Klein A. About Structure of fast hard Portland Cement. Symposium on Structure of Portland Ce-ment Paste and Concrete // Highway Research Board, Special Report, 1966. N90. Р.328-352.
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