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Vol 206
Pages:
135
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RUS

Thermodynamics sorption of complex of cerium ions on the anion exchanger

Authors:
M. A. Ponomareva1
O. V. Cheremisina2
D. E. Chirkst3
About authors
  • 1 — National Mineral Resources University (Mining University)
  • 2 — National Mineral Resources University (Mining University)
  • 3 — National Mineral Resources University (Mining University)
Date submitted:
2013-01-26
Date accepted:
2013-03-05
Date published:
2013-07-01

Abstract

Sorption isotherms was obtained in the form sulfate complex of cerium on the anion exchanger D-403 at a temperature of 298 K and pH = 2÷4 in the presence of various concentrations of magnesium sulfate. Thermodynamic description of the sorption isotherm sulfate complexes of cerium by the method, which based on linearization of the equations of the law of mass action modifed for the reaction of ion exchange. The values of the apparent constants of ion exchange and differential Gibbs energy calculated for the ions of Ce(SO 4 ) - 2 .

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References

  1. Волкова Н.М. Проблемы использования нетрадиционного редкометалльного минерального сырья / Н.М.Волкова, Д.С.Ключарев, М.Ф.Комин // Первая всероссийская научно-практическая конференция «Перспективы добычи, производства и применения РЗМ». 26-27 сентября 2011 г. М., 2011. 141 с.
  2. Дибров И.А. Термодинамическое моделирование экстракции церия (III) из сульфатных растворов солями четвертичных аммониевых оснований / И.А.Дибров, Д.Э.Чиркст, Т.Е.Литвинова // Журнал прикладной химии. 2002. Т.75. Вып.2. С.197-201.
  3. Лурье Ю.Ю. Аналитическая химия промышленных сточных вод. М., 1984. 448 с.
  4. Савин С.Б. Арсеназо (III). М., 1966. 175 с.
  5. Чистяков А.А. Сорбция алюмината из щелочных растворов на анионе D-403 / А.А.Чистяков, Д.Э.Чиркст, О.В.Черемисина // Журнал физической химии. 2011. Т.85. Вып.11. С.2137-2142.

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