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Vol 32 Iss. 3
Pages:
121-161
Download volume:
RUS
Article

Study of interaction processes of sodium sulfide and xanthates with malachite

Authors:
G. A. Osolodkov
Date submitted:
1955-09-05
Date accepted:
1955-11-09
Date published:
1956-05-17

Abstract

The results of flotation of oxidized copper ores at a given mineralogical composition are mainly determined by the selected conditions of preliminary sulfidization of the ore. Conscious management of this operation at the factory requires clear ideas about the kinetics of the process of interaction between soluble sulfides and copper carbonates, about the influence of the sulfide layer on minerals on the subsequent process of their interaction with xanthates, etc. Detailed studies of the sulfidization process, carried out in the laboratory of general and physical chemistry of the Leningrad Mining Institute, on the example of malachite were characterized: 1) kinetics of interaction between soluble sulfides and malachite; 2) influence of electrolytes on the sulfidization process; 3) kinetics of interaction between xanthates and malachite - natural and sulfidized; 4) flotation of malachite using different sulfidizers, etc. The results of the study are of interest for industrial flotation of ores containing oxidized minerals, since the processes of interaction between such minerals and flotation reagents have not yet received sufficient coverage in the literature.

Funding:

None

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References

  1. Aseev N.P., Beloglazov K.F., Graver N.S. To the problem of acid hydrometallurgical processing of lime ores.Metals Tsvetnye metally, 1931, No. 5, p. 570. (in Russian)
  2. Beloglazov K.F., Osolodkov G.A. Influence of pulp alkalinity on apatite flotation. Zapiski Gornogo Instituta, 1935, vol. IX, iss. 1. (in Russian)
  3. Godin A. Fundamentals of Flotation. GONTI, 1933. (in Russian)
  4. Davidovich B.A., Lubman N.M. Flotation of oxidized copper ores. Metals Tsvetnye metally, 1930, No. 7, p. 977. (in Russian)
  5. Iou D.G. Colorimetry. ONTI, 1935. (in Russian)
  6. Creighton G. Fundamentals of Electrochemistry. Goskhimtekhizdat, 1934. (in Russian)
  7. Osolodkov G.A. Potentiometric titration of sodium sulfide and xanthate in dilute solutions in their combined presence. Zapiski Gornogo Instituta, 1941, vol. XIII, iss. 3. (in Russian)
  8. Treadwell. Course of Analytical Chemistry, vol. II, Goskhimizdat, 1933. (in Russian)
  9. Iellineck K., Czerwinski J.Z. phys. Chefn., 1922, № 102.
  10. Landolt, Bernstein. Phys. Chem. Tabl., 1923, B. II.

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