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Vol 50 Iss. 3
Pages:
64-69
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RUS
Article

About the pyrrhotite roasting process

Authors:
I. P. Mukhlenov
A. E. Gorshtein
A. A. Azatian
T. Hutter
F. Siklai
Date submitted:
1969-12-06
Date accepted:
1970-02-17
Date published:
1970-07-10

Abstract

Extensive experimental material on the kinetics of the pyrrhotite firing process has made it possible to establish the influence of temperature, oxygen concentration, and particle size on the rate of the oxidation process. Oxidative firing of pyrrhotides is a complex physicochemical heterogeneous process accompanied by the formation of gaseous and solid reaction products, which leads to additional resistance to mass transfer caused by the diffusion of oxygen through a porous layer of solid oxides...

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References

  1. Malin K. M. The possibility of processing sulfide raw materials from northern deposits for sulfuric acid. Journal of Chemistry. prom., No. 5, 1944.
  2. Malin K. M. combustion of sulfidov. Journal of Chemistry. prom., No. 3, 1945.
  3. Malin K. M., Kalma F. N. Kinetics of pyrite and pyrrhotite combustion. Journal of Chemistry. prom., No. 8, 1948.
  4. Malin K. M. Firing of various sulfur raw materials. Journal of Chemistry. prom., No. 3, 1949.
  5. Malii K. M. The use of oxygen in the nitrous production of sulfuric acid. Oxygen, No. 4, 1944.
  6. Melnik B. D. and others. Kinetics of pyrrhotite combustion. Journal of Chem. Ind., No. 2, 1938.
  7. Lesokhin I. G. Sulfatizing calcination of a cinder in a suspended layer. Journal of Appl. Chemistry, vol. 30, No. 3, 1962.
  8. Lesokhin I. G. On mass transfer during combustion of iron sulfides in a suspended layer. Pr. LTI. 1950, 1959, 1963.
  9. Zeldovich Ya. B. On the theory of reaction on porous or powdery material. Journal of Physic. Chemistry, 13, issue 11, 1939.
  10. Vulis L. A. On the combustion of ash coal. Journal of Technology. Physics. Vol. 10, issue 23-24, 1959.
  11. Okuiev A. I., Diev N. P., Popovkina L. A. On the kinetics of sulfide oxidation. RAS USSR, vol. 103, No. 5, 1955.
  12. Narsimhan G. Brit. Chemist Engng. v. 8, No. 8, 1963.
  13. Mckinstry H. Econ. Geol., v. 54, No. 6, 1959.

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