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Vol 54 Iss. 3
Pages:
125-129
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RUS
Article

On the kinetics of ion exchange adsorption in a gushing ionite layer

Authors:
A. E. Gorshtein
V. V. Zobnin
Date submitted:
1972-09-24
Date accepted:
1972-11-13
Date published:
1973-10-05

Abstract

Ion exchange is widely used in hydrometallurgy, especially in the extraction of rare earth or dispersed elements from solutions. The field of application of ionites in non-ferrous metallurgy can be significantly expanded, firstly, if sufficiently cheap and high-capacity domestic ionites are available, and secondly, if the mechanism of the ion exchange process is known, which makes it possible to obtain, analyze and use appropriate kinetic equations. For a number of cations (copper, zinc, etc.), the domestic KU-2 cationite can be confidently attributed to the number of ionites meeting the first requirement. Not having selectivity with respect to ions of a certain grade in the combined presence of several ions, KU-2 cationite turns out to be quite capacious with respect to each of the cations individually.

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References

  1. Saldadze K. M., Pashkov A. B., Titov V. S. Ion-Exchange Macromolecular Compounds. Goskhimizdat, 1960.
  2. Samson S., Nakhod F. Extraction of Metals by Ion Exchange. In: Ion Exchange. IL, 1951.
  3. Gorshteyn A. E., Posetsel'skii A. P., Zobnin V. V. On the Spouting Layer in a Liquid-Solid System. Zap. LGI, Vol. L, Issue 3, 1970.
  4. Mukhlenov I. P., Gorshteyn A. E. Study of the Spouting Layer. Khim. Prom., 1965, No. 6.
  5. Kokotov Yu. A., Pasechnik V. A. Equilibrium and Kinetics of Ion Exchange. Chemistry, 1970.
  6. Korolkov N. M. Theoretical Foundations of Ion-Exchange Technology. Liesma (Riga), 1968.
  7. Levenshpiel O. Engineering Design of Chemical Processes. Chemistry, 1969.
  8. Kafarov V. V. Methods of Cybernetics in Chemistry and Chemical Engineering. Chemistry, 1971.
  9. Barrer R. Diffusion in Solids. IL, 1948.
  10. Gorshkov V. I., Panchenkov G. V., Ivanova T. V. Diffusion in Ion Exchange. J. Phys. Chem., 1962, Vol. 36.
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