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Elizaveta M. Kravchenko
Elizaveta M. Kravchenko
Engineer of the 1st Category
Scientific and Analytical Centre of Aprelevka Branch, All-Russian Research Geological Oil Institute
Engineer of the 1st Category
Scientific and Analytical Centre of Aprelevka Branch, All-Russian Research Geological Oil Institute
Москва
Russia

Articles

Geotechnical Engineering and Engineering Geology
  • Date submitted
    2024-04-25
  • Date accepted
    2024-09-24
  • Date published
    2024-11-12

Specific features of kinetics of thermal transformation of organic matter in Bazhenov and Domanik source rocks based on results of pyrolysis gas chromatography

Article preview

Pyrolysis of organic matter with subsequent analysis of hydrocarbon composition of the resulting products allows obtaining multicomponent distribution spectra of the generation potential by the activation energies of reactions of kerogen transformation into hydrocarbons. Configuration of the spectra depends on the structure of kerogen and is individual for each type of organic matter. Studies of kerogen kinetics showed that the distribution of activation energies is unique for each oil source rocks. The kinetic model of thermal decomposition of kerogen of the same type, for example, marine planktonic (type II), can differ significantly in different sedimentary basins due to the multivariate relationship of chemical bonds and their reaction energy threshold. The developed method for calculating multicomponent kinetic spectra (four-component models are used) based on results of pyrolysis gas chromatography allows obtaining one of the most important elements of modelling the history of oil and gas generation in geological basins. Kinetic parameters of organic matter of oil and gas source rocks influence the onset time of generation and directly reflect differences in the composition and structure of different types of kerogens. The results of determining the kinetic parameters of two high-carbon source rocks occurring across the territory of three oil and gas basins are shown. Generation and updating of the data of kinetic models of certain oil and gas source rocks will increase the reliability of forecasting oil and gas potential using the basin modelling method.

How to cite: Mozhegova S.V., Gerasimov R.S., Paizanskaya I.L., Alferova A.A., Kravchenko E.M. Specific features of kinetics of thermal transformation of organic matter in Bazhenov and Domanik source rocks based on results of pyrolysis gas chromatography // Journal of Mining Institute. 2024. Vol. 269. p. 765-776. EDN FIMBWV