<?xml version="1.0" encoding="UTF-8"?>
<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" dtd-version="1.4" article-type="research-article">
  <front>
    <journal-meta>
      <journal-id journal-id-type="issn">2411-3336</journal-id>
      <journal-id journal-id-type="eissn">2541-9404</journal-id>
      <journal-title-group>
        <journal-title xml:lang="ru">Записки Горного института</journal-title>
        <journal-title xml:lang="en">Journal of Mining Institute</journal-title>
      </journal-title-group>
      <publisher>
        <publisher-name xml:lang="ru">Санкт-Петербургский горный университет императрицы Екатерины ΙΙ</publisher-name>
        <publisher-name xml:lang="en">Empress Catherine II Saint Petersburg Mining University</publisher-name>
      </publisher>
    </journal-meta>
    <article-meta>
      <article-id custom-type="edn" pub-id-type="custom">RBJMNO</article-id>
      <article-id custom-type="pmi" pub-id-type="custom">pmi-16777</article-id>
      <article-id pub-id-type="uri">https://pmi.spmi.ru/pmi/article/view/16777</article-id>
      <article-categories>
        <subj-group subj-group-type="section-heading" xml:lang="ru">
          <subject>Геотехнология и инженерная геология</subject>
        </subj-group>
        <subj-group subj-group-type="section-heading" xml:lang="en">
          <subject>Geotechnical Engineering and Engineering Geology</subject>
        </subj-group>
      </article-categories>
      <title-group>
        <article-title xml:lang="en">A combined method for remediation of contaminated areas of the oil complex based on electrochemical treatment with the creation of a geochemical barrier</article-title>
        <trans-title-group xml:lang="ru">
          <trans-title>Комбинированный метод восстановления загрязненных территорий нефтяного комплекса на основе электрохимической обработки с созданием геохимического барьера</trans-title>
        </trans-title-group>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Shulaev</surname>
            <given-names>Nikolai S.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Шулаев</surname>
              <given-names>Н. С.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Shulaev</surname>
              <given-names>Nikolai S.</given-names>
            </name>
          </name-alternatives>
          <email>nshulayev@rambler.ru</email>
          <contrib-id contrib-id-type="orcid">0000-0002-3595-6948</contrib-id>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <aff-alternatives id="aff1">
          <aff>
            <institution xml:lang="ru">Уфимский государственный нефтяной технический университет (Уфа, Россия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Ufa State Petroleum Technological University (Ufa, Russia)</institution>
          </aff>
        </aff-alternatives>
        <contrib contrib-type="author" corresp="yes">
          <name name-style="eastern">
            <surname>Pryanichnikova</surname>
            <given-names>Valeria V.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Пряничникова</surname>
              <given-names>В. В.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Pryanichnikova</surname>
              <given-names>Valeria V.</given-names>
            </name>
          </name-alternatives>
          <email>prvaleria@mail.ru</email>
          <contrib-id contrib-id-type="orcid">0000-0001-8997-5186</contrib-id>
          <xref ref-type="aff" rid="aff2"/>
        </contrib>
        <aff-alternatives id="aff2">
          <aff>
            <institution xml:lang="ru">Уфимский государственный нефтяной технический университет (Уфа, Россия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Ufa State Petroleum Technological University (Ufa, Russia)</institution>
          </aff>
        </aff-alternatives>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Kadyrov</surname>
            <given-names>Ramil R.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Кадыров</surname>
              <given-names>Р. Р.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Kadyrov</surname>
              <given-names>Ramil R.</given-names>
            </name>
          </name-alternatives>
          <email>r_kadyrov@mail.ru</email>
          <contrib-id contrib-id-type="orcid">0000-0001-6665-9375</contrib-id>
          <xref ref-type="aff" rid="aff3"/>
        </contrib>
        <aff-alternatives id="aff3">
          <aff>
            <institution xml:lang="ru">Уфимский государственный нефтяной технический университет (Уфа, Россия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Ufa State Petroleum Technological University (Ufa, Russia)</institution>
          </aff>
        </aff-alternatives>
      </contrib-group>
      <pub-date pub-type="epub" iso-8601-date="2026-06-22">
        <day>22</day>
        <month>06</month>
        <year>2026</year>
      </pub-date>
      <pub-date date-type="collection">
        <year>2022</year>
      </pub-date>
      <fpage>1</fpage>
      <lpage>9</lpage>
      <history>
        <date date-type="received" iso-8601-date="2025-06-30">
          <day>30</day>
          <month>06</month>
          <year>2025</year>
        </date>
        <date date-type="accepted" iso-8601-date="2026-04-28">
          <day>28</day>
          <month>04</month>
          <year>2026</year>
        </date>
      </history>
      <permissions>
        <copyright-statement xml:lang="ru">© 2026 Н. С. Шулаев, В. В. Пряничникова, Р. Р. Кадыров</copyright-statement>
        <copyright-statement xml:lang="en">© 2026 Nikolai S. Shulaev, Valeria V. Pryanichnikova, Ramil R. Kadyrov</copyright-statement>
        <copyright-year>2026</copyright-year>
        <copyright-holder xml:lang="ru">Н. С. Шулаев, В. В. Пряничникова, Р. Р. Кадыров</copyright-holder>
        <copyright-holder xml:lang="en">Nikolai S. Shulaev, Valeria V. Pryanichnikova, Ramil R. Kadyrov</copyright-holder>
        <license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/4.0" xml:lang="ru">
          <license-p>Эта статья доступна по лицензии Creative Commons Attribution 4.0 International (CC BY 4.0)</license-p>
        </license>
        <license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/4.0" xml:lang="en">
          <license-p>This article is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0)</license-p>
        </license>
      </permissions>
      <self-uri xlink:type="simple" xlink:href="https://pmi.spmi.ru/pmi/article/view/16777">https://pmi.spmi.ru/pmi/article/view/16777</self-uri>
      <abstract xml:lang="ru">
        <p>Масштабы экологической проблемы, связанной с загрязнением обширных площадей промышленных зон нефтяного комплекса, значительны и требуют использования новых технологических подходов при ее решении. Развивающейся технологией в данной области является применение электрохимической очистки, т.е. очистки загрязненной среды от нефтепродуктов и сопутствующих водных растворов загрязнителей при помощи пропускания электрических токов малой величины. Преимуществом данного метода является очистка и поверхностного плодородного, и глубинных почвенных слоев. К актуальным направлениям развития электрохимических методов очистки относится их интеграция с прочими технологиями ремедиации, что позволяет увеличивать эффективность очистки за счет окисления либо извлечения полютантов, а также существенно сокращать время проведения восстановительных технических мероприятий. Данная работа посвящена комбинированию обработки нефтезагрязненных грунтов постоянным электрическим током с внесением дополнительного окисляющего компонента – пероксида кальция. Предлагается создание в межэлектродной зоне реактивного геохимического барьера из пероксида кальция, который будет служить индуктором окислительных реакций, способствующих постепенной минерализации нефтяных углеводородов. В лабораторных условиях моделируется формирование направленного загрязненного электрофоретического потока, движущегося от анода к катоду через слой пероксида кальция, исследуются особенности протекания процесса очистки. Изучается динамика таких важных параметров среды, как напряжение, кислотность обрабатываемой среды, объем формируемого электрофоретического потока, содержание нефтепродуктов в твердой (почва) и жидкой (вода) фазах после очистки.</p>
      </abstract>
      <abstract xml:lang="en">
        <p>The scale of the environmental problem associated with the pollution of vast areas of industrial zones in the oil industry is significant and requires the use of new technological approaches in solving it. A developing technology in this field is the use of electrochemical remediation, i.e., the removal of petroleum products and associated aqueous contaminant solutions from environments using low-voltage electric currents. The advantage of this method is the purification of both the surface fertile soil and the deeper soil layers. A current trend in the deve-lopment of electrochemical remediation methods is their integration with other remediation technologies, which increases remediation efficiency through oxidation or pollutant extraction, as well as significantly reduces the time required for remediation. This work is devoted to combining the treatment of oil-contaminated soils with direct electric current with the adding of the oxidizing component, calcium peroxide. The creation of a reactive geochemical barrier made of calcium peroxide in the interelectrode zone is proposed. This barrier will act as an inductor of oxidative reactions that promote the gradual mineralization of petroleum hydrocarbons. The formation of a directed contaminated electrophoretic flow moving from the anode to the cathode through a layer of calcium peroxide is simulated under laboratory conditions, and the characteristics of the purification process are investigated. The dynamics of such important environmental parameters as voltage, acidity of the treated medium, volume of the generated electrophoretic flow and the content of petroleum products in the solid (soil) and liquid (water) phases after cleaning are studied.</p>
      </abstract>
      <kwd-group xml:lang="ru">
        <title>Ключевые слова</title>
        <kwd>геохимический барьер</kwd>
        <kwd>электрохимическая очистка</kwd>
        <kwd>пероксид кальция</kwd>
        <kwd>нефтезагрязненный грунт</kwd>
        <kwd>дизельное топливо</kwd>
        <kwd>подземные воды</kwd>
        <kwd>эффективность очистки</kwd>
      </kwd-group>
      <kwd-group xml:lang="en">
        <title>Keywords</title>
        <kwd>geochemical barrier</kwd>
        <kwd>electrochemical cleaning</kwd>
        <kwd>calcium peroxide</kwd>
        <kwd>oil-contaminated soil</kwd>
        <kwd>diesel fuel</kwd>
        <kwd>groundwater</kwd>
        <kwd>cleaning efficiency</kwd>
      </kwd-group>
    </article-meta>
  </front>
  <body/>
  <back>
    <ref-list>
      <ref id="ref1">
        <label>1</label>
        <mixed-citation xml:lang="ru">Talabi A. Groundwater Pollution and Remediation / A.Talabi, T.Kayode //Journal of Water Resource and Protection. 2019. Vol. 11. P. 1-19.DOI: 10.4236/jwarp.2019.111001.</mixed-citation>
        <mixed-citation xml:lang="en">Talabi A.O., Kayode T.J. Groundwater Pollution and Remediation // Journal of Water Resource and Protection. 2019. Vol. 11. № 1. P. 1-19. DOI: 10.4236/jwarp.2019.111001</mixed-citation>
      </ref>
      <ref id="ref2">
        <label>2</label>
        <mixed-citation xml:lang="ru">Sidiropoulos P. Groundwater Pollution: Sources, Mechanisms, and Prevention // Hydrology. 2024. Vol. 11. Iss. 7. P. 98-103. DOI: 10.3390/hydrology11070098.</mixed-citation>
        <mixed-citation xml:lang="en">Sidiropoulos P. Groundwater Pollution: Sources, Mechanisms, and Prevention // Hydrology. 2024. Vol. 11. Iss. 7. № 98. DOI: 10.3390/hydrology11070098</mixed-citation>
      </ref>
      <ref id="ref3">
        <label>3</label>
        <mixed-citation xml:lang="ru">Zohud A. Evaluation of Groundwater Quality Using the Water Quality Index (WQI) and Human Health Risk (HHR) As-sessment in West Bank, Palestine / A.Zohud, L.Alam, C.T.Goh // Hydrology. 2023. Vol. 10. Iss. 198. DOI:10.3390/hydrology10100198.</mixed-citation>
        <mixed-citation xml:lang="en">Zohud A., Alam L., Goh C.T. Evaluation of Groundwater Quality Using the Water Quality Index (WQI) and Human Health Risk (HHR) Assessment in West Bank, Palestine // Hydrology. 2023. Vol. 10. Iss. 10. № 198. DOI: 10.3390/hydrology10100198</mixed-citation>
      </ref>
      <ref id="ref4">
        <label>4</label>
        <mixed-citation xml:lang="ru">Ерзова В.А. Прогноз миграции радионуклидов в подземных водах в зоне влияния строительного дренажа Ленинград-ской АЭС-2 / В.А.Ерзова, В.Г.Румынин, А.М.Никуленков, К.В.Владимиров, С.М.Судариков, М.В.Вилькина // Записки Горного института. 2023. Т. 260. С. 194-211. DOI: 10.31897/PMI.2022.27.</mixed-citation>
        <mixed-citation xml:lang="en">Ерзова В.А., Румынин В.Г., Никуленков А.М. и др. Прогноз миграции радионуклидов в подземных водах в зоне влияния строительного дренажа Ленинградской АЭС-2 // Записки Горного института. 2023. Т. 260. С. 194-211. DOI: 10.31897/PMI.2022.27</mixed-citation>
      </ref>
      <ref id="ref5">
        <label>5</label>
        <mixed-citation xml:lang="ru">Li P Sources and Consequences of Groundwater Contamination / P.Li, D.Karunanidhi, T.Subramani, K.Srinivasamoorthy // Arch Environ Contam Toxicol. 2021. Vol. 80. Iss. 1. P. 1-10. DOI: 10.1007/s00244-020-00805-z.</mixed-citation>
        <mixed-citation xml:lang="en">Peiyue Li, Karunanidhi D., Subramani T., Srinivasamoorthy K. Sources and Consequences of Groundwater Contamination // Archives of Environmental Contamination and Toxicology. 2021. Vol. 80. Iss. 1. P. 1-10. DOI: 10.1007/s00244-020-00805-z</mixed-citation>
      </ref>
      <ref id="ref6">
        <label>6</label>
        <mixed-citation xml:lang="ru">Семячков А.И. Гидрогеоэкологические условия техногенных подземных вод в объектах размещения отходов / А.И.Семячков, В.А.Почечун, К.А.Семячков // Записки Горного института. 2023. Т. 260. С. 168-179. DOI: 10.31897/PMI.2023.24.</mixed-citation>
        <mixed-citation xml:lang="en">Семячков А.И., Почечун В.А., Семячков К.А. Гидрогеоэкологические условия техногенных подземных вод в объектах размещения отходов // Записки Горного института. 2023. Т. 260. С. 168-179. DOI: 10.31897/PMI.2023.24</mixed-citation>
      </ref>
      <ref id="ref7">
        <label>7</label>
        <mixed-citation xml:lang="ru">Gingine V. A review on study of Electrokinetic stabilization of Expansive soil / V.Gingine, R.P.Shah, R.Koteswar, P.Hari Krishna // Int. Journal on Earth Science and Engineering. 2013. Vol. 2. P. 176-181. DOI: 10.13140/2.1.2809.4086.</mixed-citation>
        <mixed-citation xml:lang="en">Gingine V., Shah R.P., Venkata Koteswara Rao P, Hari Krishna P. A review on study of Electrokinetic stabilization of Expansive soil // International Journal of Earth Science and Engineering. 2013. Vol. 6. № 2 (1). P. 176-181. DOI: 10.13140/2.1.2809.4086</mixed-citation>
      </ref>
      <ref id="ref8">
        <label>8</label>
        <mixed-citation xml:lang="ru">Vocciante M. Sustainability in ElectroKinetic Remediation Processes: A Critical Analysis / M.Vocciante, V.G.Dovì, S.Ferro // Sustainability. 2021. Vol. 13. P. 5-11. DOI: 10.3390/su13020770. URL: https://www.mdpi.com/2071-1050/13/2/770 (дата обращения: 15.10.2024)</mixed-citation>
        <mixed-citation xml:lang="en">Vocciante M., Dovì V.G., Ferro S. Sustainability in ElectroKinetic Remediation Processes: A Critical Analysis // Sustainability. 2021. Vol. 13. Iss. 2. № 770. DOI: 10.3390/su13020770</mixed-citation>
      </ref>
      <ref id="ref9">
        <label>9</label>
        <mixed-citation xml:lang="ru">Meshalkin V.P. Energy-efficient engineering of technologies in the field of electrochemical treatment of oil-containing soils / V.P.Meshalkin, N.S.Shulaev, V.V.Pryanichnikova, R.R.Kadyrov // Theoretical Foundations of Chemical Engineering. 2024. Vol. 58. Iss. 4. P. 1135-1142. DOI: 10.1134/S0040579525600251.</mixed-citation>
        <mixed-citation xml:lang="en">Мешалкин В.П., Шулаев Н.С., Пряничникова В.В., Кадыров Р.Р. Энергоэффективный инжиниринг технологий в области электрохимической обработки нефтесодержащих грунтов // Теоретические основы химической технологии. 2024. Т. 58. № 2. С. 195-201. DOI: 10.31857/S0040357124020076</mixed-citation>
      </ref>
      <ref id="ref10">
        <label>10</label>
        <mixed-citation xml:lang="ru">Ganiyu S.O., Gamal El-Din M. Insight into in-situ radical and non-radical oxidative degradation of organic compounds in complex real matrix during electrooxidation with boron doped diamond electrode: A case study of oil sands process water treatment / Gani-yu S.O., Gamal El-Din M. // Appl. Catal. B Environ. 2020. Vol. 270 №119366 DOI: 10.1016/j.apcatb.2020.119366</mixed-citation>
        <mixed-citation xml:lang="en">Ganiyu S.O., Gamal El-Din M. Insight into in-situ radical and non-radical oxidative degradation of organic compounds in complex real matrix during electrooxidation with boron doped diamond electrode: A case study of oil sands process water treatment // Applied Catalysis B: Environmental. 2020. Vol. 279. № 119366. DOI: 10.1016/j.apcatb.2020.119366</mixed-citation>
      </ref>
      <ref id="ref11">
        <label>11</label>
        <mixed-citation xml:lang="ru">Ferreira M.B. Coupling of Anodic Oxidation and Soil Remediation Processes: A Review / M.B.Ferreira, A.M.Sales Solano, E.V.Santos, C.A.Martinez-Huitle, S.O.Ganiyu // Materials. 2020. Vol. 13 Iss. 19 №4309. DOI: 10.3390/ma13194309. URL: https://www.mdpi.com/1996-1944/13/19/4309 (дата обращения: 15.02.2025).</mixed-citation>
        <mixed-citation xml:lang="en">Ferreira M.B., Sales Solano A.M., dos Santos E.V. et al. Coupling of Anodic Oxidation and Soil Remediation Processes: A Review // Materials. 2020. Vol. 13. Iss. 19. № 4309. DOI: 10.3390/ma13194309</mixed-citation>
      </ref>
      <ref id="ref12">
        <label>12</label>
        <mixed-citation xml:lang="ru">Ganiyu S.O. Renewable energies driven electrochemical wastewater/soil decontamination technologies: A critical review of fundamental concepts and applications / S.O.Ganiyu, C.A.Martinez-Huitle, M.A.Rodrigo // Appl. Catal. B Environ. 2020. Vol. 270. P. 15-24. 118857 DOI: 10.1016/j.apcatb.2020.118857.</mixed-citation>
        <mixed-citation xml:lang="en">Ganiyu S.O., Martínez-Huitle C.A., Rodrigo M.A. Renewable energies driven electrochemical wastewater/soil decontamination technologies: A critical review of fundamental concepts and applications // Applied Catalysis B: Environmental. 2020. Vol. 270. № 118857. DOI: 10.1016/j.apcatb.2020.118857</mixed-citation>
      </ref>
      <ref id="ref13">
        <label>13</label>
        <mixed-citation xml:lang="ru">Streche C. Decontamination of Petroleum-Contaminated Soils Using The Electrochemical Technique: Remediation Degree and Energy Consumption / C.Streche, D.Cocarta, I.Istrate, A.Badea // Scientific Reports. 2018. Vol. 8. Iss. 10 DOI: 10.1038/s41598-018-21606-4. URL: https://www.researchgate.net/publication/323266184_Decontamination_of_Petroleum-Contaminated_Soils_Using_The_Electrochemical_Technique_Remediation_Degree_and_Energy_Consumption (дата обращения: 05.12.2024).</mixed-citation>
        <mixed-citation xml:lang="en">Streche C., Cocârţă D.M., Istrate I.-A., Badea A.A. Decontamination of Petroleum-Contaminated Soils Using The Electrochemical Technique: Remediation Degree and Energy Consumption // Scientific Reports. 2018. Vol. 8. № 3272. DOI: 10.1038/s41598-018-21606-4</mixed-citation>
      </ref>
      <ref id="ref14">
        <label>14</label>
        <mixed-citation xml:lang="ru">Dehghan Abkenar S., Khakipour N., Alahdadi I. Recent Advances in Electrochemical Treatment Technology for the Remedia-tion of Contaminated Soil // Analytical and Bioanalytical Electrochemistry. 2024. Vol. 16. Iss. 32024. P. 280-306. DOI: 10.22034/abec.2024.712243.</mixed-citation>
        <mixed-citation xml:lang="en">Dehghan Abkenar S., Khakipour N., Alahdadi I. Recent Advances in Electrochemical Treatment Technology for the Remediation of Contaminated Soil // Analytical and Bioanalytical Electrochemistry. 2024. Vol. 16. Iss. 3. P. 280-306. DOI: 10.22034/abec.2024.712243</mixed-citation>
      </ref>
      <ref id="ref15">
        <label>15</label>
        <mixed-citation xml:lang="ru">Шулаев Н.С. Электрохимическая очистка нефтезагрязненных грунтов с учетом рельефа местности / Н.С.Шулаев, В.П.Мешалкин, В.В. Пряничникова, Р.Р.Кадыров, Н.А.Быковский // Экология и промышленность России. 2022. Т. 26. № 2. С. 9–13. DOI: 10.18412/1816-0395-2022-2-9-13.</mixed-citation>
        <mixed-citation xml:lang="en">Шулаев Н.С., Мешалкин В.П., Пряничникова В.В. и др. Электрохимическая очистка нефтезагрязненных грунтов с учетом рельефа местности // Экология и промышленность России. 2022. Т. 26. № 2. С. 9-13. DOI: 10.18412/1816-0395-2022-2-9-13</mixed-citation>
      </ref>
      <ref id="ref16">
        <label>16</label>
        <mixed-citation xml:lang="ru">Han S., Wang B., Wang Y. Experimental study on soil improvement by electrochemical injection of calcium chloride solutions with time interval // Sci Rep. 2024. Vol. 14. Iss. 15748. DOI: 10.1038/s41598-024-66508-w.</mixed-citation>
        <mixed-citation xml:lang="en">Shaoyang Han, Baotian Wang, Yu Wang et al. Experimental study on soil improvement by electrochemical injection of calcium chloride solutions with time interval // Scientific Reports. 2024. Vol. 14. № 15748. DOI: 10.1038/s41598-024-66508-w</mixed-citation>
      </ref>
      <ref id="ref17">
        <label>17</label>
        <mixed-citation xml:lang="ru">Zheng W. Combined technologies for the remediation of soils contaminated by organic pollutants. A review / W.Zheng, T.Cui, H.Li // Environ Chem Lett. 2022. Vol. 20. P. 2047–2062. DOI: 10.1007/s10311-022-01407-y.</mixed-citation>
        <mixed-citation xml:lang="en">Wukui Zheng, Tian Cui, Hui Li. Combined technologies for the remediation of soils contaminated by organic pollutants. A review // Environmental Chemistry Letters. 2022. Vol. 20. P. 2043-2062. DOI: 10.1007/s10311-022-01407-y</mixed-citation>
      </ref>
      <ref id="ref18">
        <label>18</label>
        <mixed-citation xml:lang="ru">Шулаев Н.С. Комбинированный метод фиторемедиации и электрообработки для очистки загрязненных территорий нефтяного комплекса / Н.С.Шулаев, Р.Р.Кадыров, В.В.Пряничникова // Записки Горного института. 2024. Т. 265. С. 147-155.</mixed-citation>
        <mixed-citation xml:lang="en">Шулаев Н.С., Кадыров Р.Р., Пряничникова В.В. Комбинированный метод фиторемедиации и электрообработки для очистки загрязненных территорий нефтяного комплекса // Записки Горного института. 2024. Т. 265. С. 147-155.</mixed-citation>
      </ref>
      <ref id="ref19">
        <label>19</label>
        <mixed-citation xml:lang="ru">Wenwen Gu, Xixi Li, Qing Li, Yilin Hou, Maosheng Zheng, Yu Li Combined remediation of polychlorinated naphthalene-contaminated soil under multiple scenarios: An integrated method of genetic engineering and environmental remediation technology // Jour-nal of Hazardous Materials. 2021. Vol. 405. Iss. 124139. DOI:10.1016/j.jhazmat.2020.124139.</mixed-citation>
        <mixed-citation xml:lang="en">Wenwen Gu, Xixi Li, Qing Li et al. Combined remediation of polychlorinated naphthalene-contaminated soil under multiple scenarios: An integrated method of genetic engineering and environmental remediation technology // Journal of Hazardous Materials. 2021. Vol. 405. № 124139. DOI: 10.1016/j.jhazmat.2020.124139</mixed-citation>
      </ref>
      <ref id="ref20">
        <label>20</label>
        <mixed-citation xml:lang="ru">Crognale S. Development of laboratory-scale sequential electrokinetic and biological treatment of chronically hydrocarbon-impacted soils / S.Crognale, D.Cocarta, C.Streche, A.D'Annibale // New Biotechnology. 2020. Vol. 58. DOI: 10.1016/j.nbt.2020.04.002. URL: https://www.sciencedirect.com/science/article/abs/pii/S187167842030131X?via%3Dihub (дата обращения: 10.01.2025)</mixed-citation>
        <mixed-citation xml:lang="en">Crognale S., Cocarta D.M., Streche C., D’Annibale A. Development of laboratory-scale sequential electrokinetic and biological treatment of chronically hydrocarbon-impacted soils // New Biotechnology. 2020. Vol. 58. P. 38-44. DOI: 10.1016/j.nbt.2020.04.002</mixed-citation>
      </ref>
      <ref id="ref21">
        <label>21</label>
        <mixed-citation xml:lang="ru">Chen Y. Degradation of organochlorine pesticides by ultrasonic-thermally co-caticated persulfate in soil system / Y.Chen, LF.Dong, F.Zhang // J Changzhou Univ (Natural Science Edition). 2017. Vol. 29. P. 35–40.</mixed-citation>
        <mixed-citation xml:lang="en">Chen Yao, Dong Liangfei, Zhang Feng’e. Degradation of Organochlorine Pesticides by Ultrasonic-Thermally Co-activated Persulfate in Soil System // Journal of Changzhou University (Natural Science Edition). 2017. Vol. 29. № 1. P. 35-40.</mixed-citation>
      </ref>
      <ref id="ref22">
        <label>22</label>
        <mixed-citation xml:lang="ru">Dos santos E. Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches / E.Dos santos, C.Saez, P.Canizares, D.Silva, C.Martinez-Huitle, M.Rodrigo // Chemical Engineering Journal. Vol. 310. P. 581-588. DOI:10.1016/j.cej.2016.05.015.</mixed-citation>
        <mixed-citation xml:lang="en">dos Santos E.V., Sáez C., Cañizares P. et al. Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches // Chemical Engineering Journal. 2016. Vol. 310. Part 2. P. 581-588. DOI: 10.1016/j.cej.2016.05.015</mixed-citation>
      </ref>
      <ref id="ref23">
        <label>23</label>
        <mixed-citation xml:lang="ru">Andrade DC. Combination of electrokinetic remediation with permeable reactive barriers to remove organic compounds from soils / DC.Andrade, E.Vieira dos Santos// Current Opinion in Electrochemistry. 2020. Vol. 22. P. 136-144. DOI: 10.1016/j.coelec.2020.06.002.</mixed-citation>
        <mixed-citation xml:lang="en">Andrade D.C., dos Santos E.V. Combination of electrokinetic remediation with permeable reactive barriers to remove organic compounds from soils // Current Opinion in Electrochemistry. 2020. Vol. 22. P. 136-144. DOI: 10.1016/j.coelec.2020.06.002</mixed-citation>
      </ref>
      <ref id="ref24">
        <label>24</label>
        <mixed-citation xml:lang="ru">Barati Fardin A. A critical review on soil remediation using electrokinetic-enhanced permeable reactive barriers: Challenges and enhancements / A.Barati Fardin, A.Jamshidi-Zanjani // Chemical Engineering Journal Advances. 2025. Vol. 23. 100774. DOI: 10.1016/j.ceja.2025.100774. URL: https://www.sciencedirect.com/science/article/pii/S2666821125000717 (дата обращения: 10.06.2025).</mixed-citation>
        <mixed-citation xml:lang="en">Fardin A.B., Jamshidi-Zanjani A. A critical review on soil remediation using electrokinetic-enhanced permeable reactive barriers: Challenges and enhancements // Chemical Engineering Journal Advances. 2025. Vol. 23. № 100774. DOI: 10.1016/j.ceja.2025.100774</mixed-citation>
      </ref>
      <ref id="ref25">
        <label>25</label>
        <mixed-citation xml:lang="ru">Mengwei Li. Remediation of Cd-contaminated soil by electrokinetics coupled with the permeable reactive barrier from immo-bilized yeast / L.Mengwei, Zh.Haidong, W.Yadan, Y.Mixuan, X.Xinxuan, L.Xin // Science of The Total Environment. 2023. Vol. 882. 163451. DOI:10.1016/j.scitotenv.2023.163451.</mixed-citation>
        <mixed-citation xml:lang="en">Mengwei Li, Haidong Zhou, Yadan Wangjin et al. Remediation of Cd-contaminated soil by electrokinetics coupled with the permeable reactive barrier from immobilized yeast // Science of the Total Environment. 2023. Vol. 882. № 163451. DOI: 10.1016/j.scitotenv.2023.163451</mixed-citation>
      </ref>
      <ref id="ref26">
        <label>26</label>
        <mixed-citation xml:lang="ru">Xiao J. The mechanism of acid-washed zero-valent iron/activated carbon as permeable reactive barrier enhanced electrokinetic remediation of uranium-contaminated soil / J.Xiao, Z.Pang, S.Zhou, L.Chu, L.Rong, Y.Liu, J.Li, L. Tian // Sep. Purif. Technol. 2020. Vol. 244. Iss. 116667. DOI: 10.1016/j.seppur.2020.116667.</mixed-citation>
        <mixed-citation xml:lang="en">Jiang Xiao, Zhaohui Pang, Shukui Zhou et al. The mechanism of acid-washed zero-valent iron/activated carbon as permeable reactive barrier enhanced electrokinetic remediation of uranium-contaminated soil // Separation and Purification Technology. 2020. Vol. 244. № 116667. DOI: 10.1016/j.seppur.2020.116667</mixed-citation>
      </ref>
      <ref id="ref27">
        <label>27</label>
        <mixed-citation xml:lang="ru">Budania R. Comprehensive review on permeable reactive barrier for the remediation of groundwater contamination / R.Budania, S.Dangayach // J. Environ. Manag. 2023. Vol. 332. Iss.117343. DOI: 10.1016/j.jenvman.2023.117343.</mixed-citation>
        <mixed-citation xml:lang="en">Budania R., Dangayach S. A comprehensive review on permeable reactive barrier for the remediation of groundwater contamination // Journal of Environmental Management. 2023. Vol. 332. № 117343. DOI: 10.1016/j.jenvman.2023.117343</mixed-citation>
      </ref>
      <ref id="ref28">
        <label>28</label>
        <mixed-citation xml:lang="ru">Sakr M. A review on the use of permeable reactive barriers as an effective technique for groundwater remediation / M.Sakr, H.El Agamawi, H. Klammler, M.M. Mohamed // Groundw. Sustain. Dev. 2023. Vol. 21. Iss. 100914. DOI: 10.1016/j.gsd.2023.100914.</mixed-citation>
        <mixed-citation xml:lang="en">Sakr M., El Agamawi H., Klammler H. et al. A review on the use of permeable reactive barriers as an effective technique for groundwater remediation // Groundwater for Sustainable Development. 2023. Vol. 21. № 100914. DOI: 10.1016/j.gsd.2023.100914</mixed-citation>
      </ref>
      <ref id="ref29">
        <label>29</label>
        <mixed-citation xml:lang="ru">Опекунов А.Ю. Анализ эффективности геохимических барьеров как основа применения природоподобных техноло-гий очистки воды / А.Ю.Опекунов, Д.В.Коршунова, М.Г.Опекунова, В.В.Сомов, Д.А.Акулов // Записки Горного института. 2024. Т. 267. С. 343-355.</mixed-citation>
        <mixed-citation xml:lang="en">Опекунов А.Ю., Коршунова Д.В., Опекунова М.Г. и др. Анализ эффективности геохимических барьеров как основа применения природоподобных технологий очистки воды // Записки Горного института. 2024. Т. 267. С. 343-355.</mixed-citation>
      </ref>
      <ref id="ref30">
        <label>30</label>
        <mixed-citation xml:lang="ru">Fan G. Mechanochemical treatment with CaO-activated PDS of HCB contaminated soils / G.Fan, X.Liu, X.Li, C.Lin, W.Ouyang // Chemosphere. 2020. Vol. 257 P. 264-269. DOI:10.1016/j.chemosphere.2020.127207.</mixed-citation>
        <mixed-citation xml:lang="en">Guoxuan Fan, Xitao Liu, Xiaowan Li et al. Mechanochemical treatment with CaO-activated PDS of HCB contaminated soils // Chemosphere. 2020. Vol. 257. № 127207. DOI: 10.1016/j.chemosphere.2020.127207</mixed-citation>
      </ref>
      <ref id="ref31">
        <label>31</label>
        <mixed-citation xml:lang="ru">Wieckol-Ryk A. Solid Peroxy Compounds as Additives to Organic Waste for Reclamation of Post-Industrial Contaminated Soils / A.Wieckol-Ryk, M.Thomas, B.Bialecka // Materials (Basel). 2021. Vol. 14. Iss. 22. 6979. DOI: 10.3390/ma14226979.</mixed-citation>
        <mixed-citation xml:lang="en">Więckol-Ryk A., Thomas M., Białecka B. Solid Peroxy Compounds as Additives to Organic Waste for Reclamation of Post-Industrial Contaminated Soils // Materials. 2021. Vol. 14. Iss. 22. № 6979. DOI: 10.3390/ma14226979</mixed-citation>
      </ref>
      <ref id="ref32">
        <label>32</label>
        <mixed-citation xml:lang="ru">Zhou W. Activated carbon as effective cathode material in iron-free Electro-Fenton process: Integrated H2O2 electrogenera-tion, activation, and pollutants adsorption / W.Zhou, L.Rajic, L.Chen // Electrochimical Acta. 2018. Vol. 296. P. 317-326. DOI:10.1016/j.electacta.2018.11.052.</mixed-citation>
        <mixed-citation xml:lang="en">Wei Zhou, Ljiljana Rajic, Long Chen et al. Activated carbon as effective cathode material in iron-free Electro-Fenton process: Integrated H2O2 electrogeneration, activation, and pollutants adsorption // Electrochimica Acta. 2019. Vol. 296. P. 317-326. DOI: 10.1016/j.electacta.2018.11.052</mixed-citation>
      </ref>
      <ref id="ref33">
        <label>33</label>
        <mixed-citation xml:lang="ru">Lawrence M.Z. Electrochemical Geo-Oxidation (ECGO) treatment of Massachusetts New Bedford Harbor sediment PCBs / M.Z.Lawrence, J.W.Kenneth, S.Pamukcu // Electrochimica Acta. 2020. Vol. 354. 136690. DOI: 10.1016/j.electacta.2020.136690.</mixed-citation>
        <mixed-citation xml:lang="en">Zanko L.M., Wittle J.K., Pamukcu S. Case study: Electrochemical Geo-Oxidation (ECGO) treatment of Massachusetts New Bedford Harbor sediment PCBs // Electrochimica Acta. 2020. Vol. 354. № 136690. DOI: 10.1016/j.electacta.2020.136690</mixed-citation>
      </ref>
      <ref id="ref34">
        <label>34</label>
        <mixed-citation xml:lang="ru">Adhami S. Remediation of oil-based drilling waste using the electrokinetic-fenton method / S.Adhami, A.Jamshidi-Zanjani, A.K.Darban // Process Saf. Environ. Prot. 2021. Vol. 149. P. 432-441.</mixed-citation>
        <mixed-citation xml:lang="en">Adhami S., Jamshidi-Zanjani A., Darban A.K. Remediation of oil-based drilling waste using the electrokinetic-Fenton method // Process Safety and Environmental Protection. 2021. Vol. 149. P. 432-441. DOI: 10.1016/j.psep.2020.11.018</mixed-citation>
      </ref>
      <ref id="ref35">
        <label>35</label>
        <mixed-citation xml:lang="ru">Targhan H. A review of the role of hydrogen peroxide in organic transformations / H.Targhan, P.Evans, K.Bahrami // Jour-nal of Industrial and Engineering Chemistry. 2021. Vol. 104. P. 295-332, DOI: 10.1016/j.jiec.2021.08.024.</mixed-citation>
        <mixed-citation xml:lang="en">Targhan H., Evans P., Bahrami K. A review of the role of hydrogen peroxide in organic transformations // Journal of Industrial and Engineering Chemistry. 2021. Vol. 104. P. 295-332. DOI: 10.1016/j.jiec.2021.08.024</mixed-citation>
      </ref>
      <ref id="ref36">
        <label>36</label>
        <mixed-citation xml:lang="ru">Pai Z.P. Catalysts for Liquid-Phase Oxidation of Organic Compounds by Hydrogen Peroxide: Homogeneous and Phase-Transfer Systems / Z.P.Pai, V.N.Parmon, V.I.Bukhtiyarov // Kinetika i kataliz. 2023. Vol. 64. N. 4. P. 347-383. DOI: 10.31857/S0453881123040123.</mixed-citation>
        <mixed-citation xml:lang="en">Пай З.П., Пармон В.Н., Бухтияров В.И. Катализаторы жидкофазного окисления пероксидом водорода органических соединений: гомогенные и межфазные системы // Кинетика и катализ. 2023. Т. 64. № 4. С. 347-383. DOI: 10.31857/S0453881123040123</mixed-citation>
      </ref>
    </ref-list>
  </back>
</article>
