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  <front>
    <journal-meta>
      <journal-id journal-id-type="issn">2411-3336</journal-id>
      <journal-id journal-id-type="eissn">2541-9404</journal-id>
      <journal-title-group>
        <journal-title xml:lang="ru">Записки Горного института</journal-title>
        <journal-title xml:lang="en">Journal of Mining Institute</journal-title>
      </journal-title-group>
      <publisher>
        <publisher-name xml:lang="ru">Санкт-Петербургский горный университет императрицы Екатерины ΙΙ</publisher-name>
        <publisher-name xml:lang="en">Empress Catherine II Saint Petersburg Mining University</publisher-name>
      </publisher>
    </journal-meta>
    <article-meta>
      <article-id custom-type="edn" pub-id-type="custom">TBOUJQ</article-id>
      <article-id custom-type="pmi" pub-id-type="custom">pmi-16619</article-id>
      <article-id pub-id-type="uri">https://pmi.spmi.ru/pmi/article/view/16619</article-id>
      <article-categories>
        <subj-group subj-group-type="section-heading" xml:lang="ru">
          <subject>Геология</subject>
        </subj-group>
        <subj-group subj-group-type="section-heading" xml:lang="en">
          <subject>Geology</subject>
        </subj-group>
      </article-categories>
      <title-group>
        <article-title xml:lang="en">Prospects for rare earth element mineralization in the weathering crusts developed on granite-gneisses of the Souktal Plutonic Complex  (Northern Kazakhstan)</article-title>
        <trans-title-group xml:lang="ru">
          <trans-title>Перспективы редкоземельной рудоносности кор выветривания  по гранито-гнейсам Соуктальского плутонического комплекса  (Северный Казахстан)</trans-title>
        </trans-title-group>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Junussov</surname>
            <given-names>Medet A.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Джунусов</surname>
              <given-names>М. А.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Junussov</surname>
              <given-names>Medet A.</given-names>
            </name>
          </name-alternatives>
          <email>medet.junussov@nu.edu.kz</email>
          <contrib-id contrib-id-type="orcid">0000-0002-1379-5952</contrib-id>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <aff-alternatives id="aff1">
          <aff>
            <institution xml:lang="ru">Назарбаевский университет (Астана, Казахстан)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Nazarbayev University (Astana, Kazakhstan)</institution>
          </aff>
        </aff-alternatives>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Regmi</surname>
            <given-names>Kamal R.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Регми</surname>
              <given-names>К. Р.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Regmi</surname>
              <given-names>Kamal R.</given-names>
            </name>
          </name-alternatives>
          <email>kamal.regmi@nu.edu.kz</email>
          <contrib-id contrib-id-type="orcid">0000-0003-1207-9118</contrib-id>
          <xref ref-type="aff" rid="aff2"/>
        </contrib>
        <aff-alternatives id="aff2">
          <aff>
            <institution xml:lang="ru">Назарбаевский университет (Астана, Казахстан)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Nazarbayev University (Astana, Kazakhstan)</institution>
          </aff>
        </aff-alternatives>
        <contrib contrib-type="author" corresp="yes">
          <name name-style="eastern">
            <surname>Klimova</surname>
            <given-names>Ekaterina V.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Климова</surname>
              <given-names>Е. В.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Klimova</surname>
              <given-names>Ekaterina V.</given-names>
            </name>
          </name-alternatives>
          <email>katya_kli@list.ru</email>
          <contrib-id contrib-id-type="orcid">0000-0002-9771-9518</contrib-id>
          <xref ref-type="aff" rid="aff3"/>
        </contrib>
        <aff-alternatives id="aff3">
          <aff>
            <institution xml:lang="ru">Институт геологии и геохронологии докембрия РАН (Санкт-Петербург, Россия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Institute of Precambrian Geology and Geochronology RAS (Saint  Petersburg, Russia)</institution>
          </aff>
        </aff-alternatives>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Reznik</surname>
            <given-names>Aleksandr V.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Резник</surname>
              <given-names>А. В.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Reznik</surname>
              <given-names>Aleksandr V.</given-names>
            </name>
          </name-alternatives>
          <email>a-reznik@mail.ru</email>
          <contrib-id contrib-id-type="orcid">0000-0002-0077-3404</contrib-id>
          <xref ref-type="aff" rid="aff4"/>
        </contrib>
        <aff-alternatives id="aff4">
          <aff>
            <institution xml:lang="ru">Институт горного дела им. Н.А.Чинакала СО РАН (Новосибирск, Россия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">N.A.Chinakal Institute of Mining Siberian Branch RAS (Novosibirsk, Russia)</institution>
          </aff>
        </aff-alternatives>
      </contrib-group>
      <pub-date pub-type="epub" iso-8601-date="2025-11-25">
        <day>25</day>
        <month>11</month>
        <year>2025</year>
      </pub-date>
      <pub-date date-type="collection">
        <year>2026</year>
      </pub-date>
      <volume>277</volume>
      <fpage>45</fpage>
      <lpage>54</lpage>
      <history>
        <date date-type="received" iso-8601-date="2024-12-09">
          <day>09</day>
          <month>12</month>
          <year>2024</year>
        </date>
        <date date-type="accepted" iso-8601-date="2025-07-02">
          <day>02</day>
          <month>07</month>
          <year>2025</year>
        </date>
        <date date-type="rev-recd" iso-8601-date="2026-02-27">
          <day>27</day>
          <month>02</month>
          <year>2026</year>
        </date>
      </history>
      <permissions>
        <copyright-statement xml:lang="ru">© 2025 М. А. Джунусов, К. Р. Регми, Е. В. Климова, А. В. Резник</copyright-statement>
        <copyright-statement xml:lang="en">© 2025 Medet A. Junussov, Kamal R. Regmi, Ekaterina V. Klimova, Aleksandr V. Reznik</copyright-statement>
        <copyright-year>2025</copyright-year>
        <copyright-holder xml:lang="ru">М. А. Джунусов, К. Р. Регми, Е. В. Климова, А. В. Резник</copyright-holder>
        <copyright-holder xml:lang="en">Medet A. Junussov, Kamal R. Regmi, Ekaterina V. Klimova, Aleksandr V. Reznik</copyright-holder>
        <license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/4.0" xml:lang="ru">
          <license-p>Эта статья доступна по лицензии Creative Commons Attribution 4.0 International (CC BY 4.0)</license-p>
        </license>
        <license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/4.0" xml:lang="en">
          <license-p>This article is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0)</license-p>
        </license>
      </permissions>
      <self-uri xlink:type="simple" xlink:href="https://pmi.spmi.ru/pmi/article/view/16619">https://pmi.spmi.ru/pmi/article/view/16619</self-uri>
      <abstract xml:lang="ru">
        <p>Изучены уникальные образцы коры выветривания наиболее выветренных образцов профиля выветривания (30-43 м) из двух буровых скважин. Минеральный состав образцов представлен кварцем, каолинитом, микроклином, мусковитом и плагиоклазом, что определено с помощью поляризационного микроскопа и подтверждено рентгеноструктурным анализом. Образцы из коры выветривания по гранито-гнейсам Соуктальского плутонического комплекса Северного Казахстана подвергнуты последовательному извлечению редкоземельных элементов (РЗЭ). Содержание РЗЭ оценивалось методом масс-спектрометрии с индуктивно-связанной плазмой (ICP-MS) после двухступенчатой процедуры последовательного выщелачивания растворами хлорида гидроксиламиния и гидроксида натрия (0,2 моль NH2OH⋅HCI и 1 моль NaOH). Эксперименты по последовательному выщелачиванию образцов позволили эффективно извлечь РЗЭ из коры выветривания Соуктальского плутонического комплекса. Эффективность извлечения (РЗЭ + Sc + Y) составляет от 4,1 до 7,8 г/т. Суммарное содержание легких РЗЭ составляет от 3,5 до 5,9 г/т, тяжелых – от 0,2 до 0,7 г/т. Результаты изучения образцов из коры выветривания по гранито-гнейсам позволяют отнести объект к ионно-адсорбционному типу месторождения РЗЭ коры выветривания. Полученные результаты демонстрируют эффективность последовательного извлечения РЗЭ и свидетельствуют о перспективности изучаемой территории для месторождения РЗЭ. Ионно-адсорбционный тип месторождений РЗЭ является новым для Казахстана и может способствовать развитию промышленной отрасли.</p>
      </abstract>
      <abstract xml:lang="en">
        <p>This study investigates unique weathering crust samples from the most altered sections (30-43 m) of the weathering profile within the Souktal Plutonic Complex, Northern Kazakhstan. The samples, obtained from two drill cores, consist of quartz, kaolinite, microcline, muscovite, and plagioclase, as identified through polarized light microscopy and confirmed by X-ray diffraction analysis. Sequential extraction of rare earth elements (REE) was performed using inductively coupled plasma mass spectrometry (ICP-MS) following a two-step leaching procedure with hydroxylamine hydrochloride (0.2 mol NH2OH·HCl) and sodium hydroxide (1 mol NaOH) solutions. The extraction process effectively recovered REE, indicating their presence in an ion-exchangeable form, with total extraction rates (REE + Sc + Y) ranging from 4.1 to 7.8 ppm. The total light REE content varies from 3.5 to 5.9 ppm, while heavy REE content ranges from 0.2 to 0.7 ppm across all samples. Petrological and geochemical analyses suggest that the studied area represents an ion-adsorption-type REE weathered deposit. These findings enhance the understanding of ionic-adsorbed REE within weathering crusts and highlight the effectiveness of sequential extraction methods for REE determination. Moreover, the study suggests that this area holds promising potential as a future REE ion-adsorption site, contributing to the development of Kazakhstan’s national REE industry.</p>
      </abstract>
      <kwd-group xml:lang="ru">
        <title>Ключевые слова</title>
        <kwd>редкоземельные элементы</kwd>
        <kwd>кора выветривания</kwd>
        <kwd>месторождения РЗЭ</kwd>
        <kwd>Соуктал</kwd>
        <kwd>Казахстан</kwd>
      </kwd-group>
      <kwd-group xml:lang="en">
        <title>Keywords</title>
        <kwd>rare earth elements</kwd>
        <kwd>weathering crust</kwd>
        <kwd>REE deposits</kwd>
        <kwd>Souktal</kwd>
        <kwd>Kazakhstan</kwd>
      </kwd-group>
      <funding-group>
        <funding-statement xml:lang="ru">Работа выполнена в рамках темы 064.01.00 (SPG) Назарбаевского университета и темы НИР ИГГД РАН FMUW 2025-0003 (FMUW 2022-0004).</funding-statement>
        <funding-statement xml:lang="en">The work was performed within the framework of topic 064.01.00 (SPG) of Nazarbayev University and the research topic of the IPGG RAS FMUW 2025-0003 (FMUW 2022-0004).</funding-statement>
      </funding-group>
    </article-meta>
  </front>
  <body/>
  <back>
    <ref-list>
      <ref id="ref1">
        <label>1</label>
        <mixed-citation xml:lang="ru">Binnemans K., Jones P.T. Rare Earths and the Balance Problem // Journal of Sustainable Metallurgy. 2015. Vol. 1. Iss. 1. P. 29-38. DOI: 10.1007/s40831-014-0005-1</mixed-citation>
        <mixed-citation xml:lang="en">Binnemans K., Jones P.T. Rare Earths and the Balance Problem. Journal of Sustainable Metallurgy. 2015. Vol. 1. Iss. 1, p. 29-38. DOI: 10.1007/s40831-014-0005-1</mixed-citation>
      </ref>
      <ref id="ref2">
        <label>2</label>
        <mixed-citation xml:lang="ru">Takeda O., Okabe T.H. Current Status on Resource and Recycling Technology for Rare Earths // Metallurgical and Materials Transactions E. 2014. Vol. 1. Iss. 2. P. 160-173. DOI: 10.1007/s40553-014-0016-7</mixed-citation>
        <mixed-citation xml:lang="en">Takeda O., Okabe T.H. Current Status on Resource and Recycling Technology for Rare Earths. Metallurgical and Materials Transactions E. 2014. Vol. 1. Iss. 2, p. 160-173. DOI: 10.1007/s40553-014-0016-7</mixed-citation>
      </ref>
      <ref id="ref3">
        <label>3</label>
        <mixed-citation xml:lang="ru">Рогова И.В., Стативко В.С., Петров Д.А., Скублов С.Г. Редкоэлементный состав циркона из гранитов рапакиви Губановской интрузии, Выборгский массив, как отражение флюидонасыщенности расплава // Геохимия. 2024. Т. 69. № 11. С. 975-991. DOI: 10.31857/S0016752524110024</mixed-citation>
        <mixed-citation xml:lang="en">Rogova I.V., Stativko V.S., Petrov D.A., Skublov S.G. Trace Element Composition of Zircons from Rapakivi Granites of the Gubanov Intrusion, the Wiborg Massif, as a Reflection of the Fluid Saturation of the Melt. Geochemistry International. 2024. Vol. 62. N 11, p. 1123-1136. DOI: 10.1134/S0016702924700630</mixed-citation>
      </ref>
      <ref id="ref4">
        <label>4</label>
        <mixed-citation xml:lang="ru">Skublov S.G., Petrov D.A., Galankina O.L. et al. Th-Rich Zircon from a Pegmatite Vein Hosted in the Wiborg Rapakivi Granite Massif // Geosciences. 2023. Vol. 13. Iss. 12. № 362. DOI: 10.3390/geosciences13120362</mixed-citation>
        <mixed-citation xml:lang="en">Skublov S.G., Petrov D.A., Galankina O.L. et al. Th-Rich Zircon from a Pegmatite Vein Hosted in the Wiborg Rapakivi Granite Massif. Geosciences. 2023. Vol. 13. Iss. 12. N 362. DOI: 10.3390/geosciences13120362</mixed-citation>
      </ref>
      <ref id="ref5">
        <label>5</label>
        <mixed-citation xml:lang="ru">Salimgaraeva L., Berezin A., Sergeev S. et al. Zircons from Eclogite-Associated Rocks of the Marun–Keu Complex, the Polar Urals: Trace Elements and U–Pb Dating // Geosciences. 2024. Vol. 14. Iss. 8. № 206. DOI: 10.3390/geosciences14080206</mixed-citation>
        <mixed-citation xml:lang="en">Salimgaraeva L., Berezin A., Sergeev S. et al. Zircons from Eclogite-Associated Rocks of the Marun–Keu Complex, the Polar Urals: Trace Elements and U–Pb Dating. Geosciences. 2024. Vol. 14. Iss. 8. N 206. DOI: 10.3390/geosciences14080206</mixed-citation>
      </ref>
      <ref id="ref6">
        <label>6</label>
        <mixed-citation xml:lang="ru">Skublov S.G., Hamdard N., Ivanov M.A., Stativko V.S. Trace element zoning of colorless beryl from spodumene pegmatites of Pashki deposit (Nuristan province, Afghanistan) // Frontiers in Earth Science. 2024. Vol. 12. № 1432222. DOI: 10.3389/feart.2024.1432222</mixed-citation>
        <mixed-citation xml:lang="en">Skublov S.G., Hamdard N., Ivanov M.A., Stativko V.S. Trace element zoning of colorless beryl from spodumene pegmatites of Pashki deposit (Nuristan province, Afghanistan). Frontiers in Earth Science. 2024. Vol. 12. N 1432222. DOI: 10.3389/feart.2024.1432222</mixed-citation>
      </ref>
      <ref id="ref7">
        <label>7</label>
        <mixed-citation xml:lang="ru">Левашова Е.В., Скублов С.Г., Хамдард Н. и др. Геохимия циркона из пегматитоносных лейкогранитов комплекса Лагман, провинция Нуристан, Афганистан // Russian Journal of Earth Sciences. 2024. Т. 24. № 2. № ES2011. DOI: 10.2205/2024ES000916</mixed-citation>
        <mixed-citation xml:lang="en">Levashova E.V., Skublov S.G., Hamdard N. et al. Geochemistry of Zircon from Pegmatite-bearing Leucogranites of the Laghman Complex, Nuristan Province, Afghanistan. Russian Journal of Earth Sciences. 2024. Vol. 2. Iss. 2. N ES2011 (in Russian). DOI: 10.2205/2024ES000916</mixed-citation>
      </ref>
      <ref id="ref8">
        <label>8</label>
        <mixed-citation xml:lang="ru">Евдокимов А.Н., Пхарое Б.Л. Индикаторная роль редких и редкоземельных элементов Северо-Западного рудопроявления марганца (ЮАР) в генетической модели гипергенных марганцевых месторождений // Записки Горного института. 2021. Том 252. С. 814-825. DOI: 10.31897/PMI.2021.6.4</mixed-citation>
        <mixed-citation xml:lang="en">Evdokimov A.N., Pharoe B.L. Indicator role of rare and rare-earth elements of the Northwest manganese ore occurrence (South Africa) in the genetic model of supergene manganese deposits. Journal of Mining Institute. 2021. Vol. 252, p. 814-825. DOI: 10.31897/PMI.2021.6.4</mixed-citation>
      </ref>
      <ref id="ref9">
        <label>9</label>
        <mixed-citation xml:lang="ru">Shijie Wang. Rare Earth Metals: Resourcefulness and Recovery // JOM. 2013. Vol. 65. Iss. 10. P. 1317-1320. DOI: 10.1007/s11837-013-0732-y</mixed-citation>
        <mixed-citation xml:lang="en">Shijie Wang. Rare Earth Metals: Resourcefulness and Recovery. JOM. 2013. Vol. 65. Iss. 10, p. 1317-1320. DOI: 10.1007/s11837-013-0732-y</mixed-citation>
      </ref>
      <ref id="ref10">
        <label>10</label>
        <mixed-citation xml:lang="ru">Yan Hei Martin Li, Wen Winston Zhao, Mei-Fu Zhou. Nature of parent rocks, mineralization styles and ore genesis of rego-lith-hosted REE deposits in South China: An integrated genetic model // Journal of Asian Earth Sciences. 2017. Vol. 148. P. 65-95. DOI: 10.1016/j.jseaes.2017.08.004</mixed-citation>
        <mixed-citation xml:lang="en">Yan Hei Martin Li, Wen Winston Zhao, Mei-Fu Zhou. Nature of parent rocks, mineralization styles and ore genesis of reg-olith-hosted REE deposits in South China: An integrated genetic model. Journal of Asian Earth Sciences. 2017. Vol. 148, p. 65-95. DOI: 10.1016/j.jseaes.2017.08.004</mixed-citation>
      </ref>
      <ref id="ref11">
        <label>11</label>
        <mixed-citation xml:lang="ru">Zhiwei Bao, Zhenhua Zhao. Geochemistry of mineralization with exchangeable REY in the weathering crusts of granitic rocks in South China // Ore Geology Reviews. 2008. Vol. 33. Iss. 3-4. P. 519-535. DOI: 10.1016/j.oregeorev.2007.03.005</mixed-citation>
        <mixed-citation xml:lang="en">Zhiwei Bao, Zhenhua Zhao. Geochemistry of mineralization with exchangeable REY in the weathering crusts of granitic rocks in South China. Ore Geology Reviews. 2008. Vol. 33. Iss. 3-4, p. 519-535. DOI: 10.1016/j.oregeorev.2007.03.005</mixed-citation>
      </ref>
      <ref id="ref12">
        <label>12</label>
        <mixed-citation xml:lang="ru">Bosia C., Chabaux F., Pelt E. et al. U–Th–Ra variations in Himalayan river sediments (Gandak river, India): Weathering frac-tionation and/or grain-size sorting? // Geochimica et Cosmochimica Acta. 2016. Vol. 193. P. 176-196. DOI: 10.1016/j.gca.2016.08.026</mixed-citation>
        <mixed-citation xml:lang="en">Bosia C., Chabaux F., Pelt E. et al. U–Th–Ra variations in Himalayan river sediments (Gandak river, India): Weathering frac-tionation and/or grain-size sorting? Geochimica et Cosmochimica Acta. 2016. Vol. 193, p. 176-196. DOI: 10.1016/j.gca.2016.08.026</mixed-citation>
      </ref>
      <ref id="ref13">
        <label>13</label>
        <mixed-citation xml:lang="ru">Davranche M., Pourret O., Gruau G., Dia A. Impact of humate complexation on the adsorption of REE onto Fe oxyhydroxide // Journal of Colloid and Interface Science. 2004. Vol. 277. Iss. 2. P. 271-279. DOI: 10.1016/j.jcis.2004.04.007</mixed-citation>
        <mixed-citation xml:lang="en">Davranche M., Pourret O., Gruau G., Dia A. Impact of humate complexation on the adsorption of REE onto Fe oxyhydroxide. Journal of Colloid and Interface Science. 2004. Vol. 277. Iss. 2, p. 271-279. DOI: 10.1016/j.jcis.2004.04.007</mixed-citation>
      </ref>
      <ref id="ref14">
        <label>14</label>
        <mixed-citation xml:lang="ru">Piasecki W., Sverjensky D.A. Speciation of adsorbed yttrium and rare earth elements on oxide surfaces // Geochimica et Cosmochimica Acta. 2008. Vol. 72. Iss. 16. P. 3964-3979. DOI: 10.1016/j.gca.2008.05.049</mixed-citation>
        <mixed-citation xml:lang="en">Piasecki W., Sverjensky D.A. Speciation of adsorbed yttrium and rare earth elements on oxide surfaces. Geochimica et Cosmochimica Acta. 2008. Vol. 72. Iss. 16, p. 3964-3979. DOI: 10.1016/j.gca.2008.05.049</mixed-citation>
      </ref>
      <ref id="ref15">
        <label>15</label>
        <mixed-citation xml:lang="ru">Dardenne K., Schäfer T., Lindqvist-Reis P. et al. Low Temperature XAFS Investigation on the Lutetium Binding Changes during the 2-Line Ferrihydrite Alteration Process // Environmental Science &amp; Technology. 2002. Vol. 36. Iss. 23. P. 5092-5099. DOI: 10.1021/es025513f</mixed-citation>
        <mixed-citation xml:lang="en">Dardenne K., Schäfer T., Lindqvist-Reis P. et al. Low Temperature XAFS Investigation on the Lutetium Binding Changes during the 2-Line Ferrihydrite Alteration Process. Environmental Science &amp; Technology. 2002. Vol. 36. Iss. 23, p. 5092-5099. DOI: 10.1021/es025513f</mixed-citation>
      </ref>
      <ref id="ref16">
        <label>16</label>
        <mixed-citation xml:lang="ru">Bau M., Koschinsky A. Oxidative scavenging of cerium on hydrous Fe oxide: Evidence from the distribution of rare earth elements and yttrium between Fe oxides and Mn oxides in hydrogenetic ferromanganese crusts // Geochemical Journal. 2009. Vol. 43. Iss. 1. P. 37-47. DOI: 10.2343/geochemj.1.0005</mixed-citation>
        <mixed-citation xml:lang="en">Bau M., Koschinsky A. Oxidative scavenging of cerium on hydrous Fe oxide: Evidence from the distribution of rare earth elements and yttrium between Fe oxides and Mn oxides in hydrogenetic ferromanganese crusts. Geochemical Journal. 2009. Vol. 43. Iss. 1, p. 37-47. DOI: 10.2343/geochemj.1.0005</mixed-citation>
      </ref>
      <ref id="ref17">
        <label>17</label>
        <mixed-citation xml:lang="ru">Ткачев А.В., Рундквист Д.В., Вишневская Н.А. Основные черты исторической металлогении редкоземельных элементов // Геология рудных месторождений. 2022. Т. 64. № 3. С. 209-246. DOI: 10.31857/S0016777022030066</mixed-citation>
        <mixed-citation xml:lang="en">Tkachev A.V., Rundqvist D.V., Vishnevskaya N.A. Main Features of the REE Metallogeny through Geological Time. Geology of Ore Deposits. 2022. Vol. 64. N 3, p. 41-77. DOI: 10.1134/S1075701522030060</mixed-citation>
      </ref>
      <ref id="ref18">
        <label>18</label>
        <mixed-citation xml:lang="ru">Yufeng Huang, Hongping He, Xiaoliang Liang et al. Characteristics and genesis of ion adsorption type REE deposits in the weathering crusts of metamorphic rocks in Ningdu, Ganzhou, China // Ore Geology Reviews. 2021. Vol. 135. № 104173. DOI: 10.1016/j.oregeorev.2021.104173</mixed-citation>
        <mixed-citation xml:lang="en">Yufeng Huang, Hongping He, Xiaoliang Liang et al. Characteristics and genesis of ion adsorption type REE deposits in the weathering crusts of metamorphic rocks in Ningdu, Ganzhou, China. Ore Geology Reviews. 2021. Vol. 135. N 104173. DOI: 10.1016/j.oregeorev.2021.104173</mixed-citation>
      </ref>
      <ref id="ref19">
        <label>19</label>
        <mixed-citation xml:lang="ru">Spedding F.H., Voigt A.F., Gladrow E.M, Sleight N.R. The Separation of Rare Earths by Ion Exchange. I. Cerium and Yttrium // Journal of the American Chemical Society. 1947. Vol. 69. Iss. 11. P. 2777-2781. DOI: 10.1021/ja01203a058</mixed-citation>
        <mixed-citation xml:lang="en">Spedding F.H., Voigt A.F., Gladrow E.M, Sleight N.R. The Separation of Rare Earths by Ion Exchange. I. Cerium and Yttrium. Journal of the American Chemical Society. 1947. Vol. 69. Iss. 11, p. 2777-2781. DOI: 10.1021/ja01203a058</mixed-citation>
      </ref>
      <ref id="ref20">
        <label>20</label>
        <mixed-citation xml:lang="ru">Spedding F.H., Voigt A.F., Gladrow E.M. et al. The Separation of Rare Earths by Ion Exchange. II. Neodymium and Praseodymium // Journal of the American Chemical Society. 1947. Vol. 69. Iss. 11. P. 2786-2792. DOI: 10.1021/ja01203a060</mixed-citation>
        <mixed-citation xml:lang="en">Spedding F.H., Voigt A.F., Gladrow E.M. et al. The Separation of Rare Earths by Ion Exchange. II. Neodymium and Praseodymium. Journal of the American Chemical Society. 1947. Vol. 69. Iss. 11, p. 2786-2792. DOI: 10.1021/ja01203a060</mixed-citation>
      </ref>
      <ref id="ref21">
        <label>21</label>
        <mixed-citation xml:lang="ru">Зимина Г.В., Николаева И.И., Таук М.В., Цыганкова М.В. Экстракционные схемы разделения редкоземельных металлов // Цветные металлы. 2015. № 4. С. 23-27. DOI: 10.17580/tsm.2015.04.04</mixed-citation>
        <mixed-citation xml:lang="en">Zimina G.V., Nikolaeva I.I., Tauk M.V., Tsygankova M.V. Extraction schemes of rare-earth metals’ separation. Tsvetnye metally. 2015. N 4, p. 23-27 (in Russian). DOI: 10.17580/tsm.2015.04.04</mixed-citation>
      </ref>
      <ref id="ref22">
        <label>22</label>
        <mixed-citation xml:lang="ru">Land M., Öhlander B., Ingri J., Thunberg J. Solid speciation and fractionation of rare earth elements in a spodosol profile from northern Sweden as revealed by sequential extraction // Chemical Geology. 1999. Vol. 160. Iss. 1-2. P. 121-138. DOI: 10.1016/S0009-2541(99)00064-9</mixed-citation>
        <mixed-citation xml:lang="en">Land M., Öhlander B., Ingri J., Thunberg J. Solid speciation and fractionation of rare earth elements in a spodosol profile from northern Sweden as revealed by sequential extraction. Chemical Geology. 1999. Vol. 160. Iss. 1-2, p. 121-138. DOI: 10.1016/S0009-2541(99)00064-9</mixed-citation>
      </ref>
      <ref id="ref23">
        <label>23</label>
        <mixed-citation xml:lang="ru">Estrade G., Marquis E., Smith M. et al. REE concentration processes in ion adsorption deposits: Evidence from the Ambohimirahavavy alkaline complex in Madagascar // Ore Geology Reviews. 2019. Vol. 112. № 103027. DOI: 10.1016/j.oregeorev.2019.103027</mixed-citation>
        <mixed-citation xml:lang="en">Estrade G., Marquis E., Smith M. et al. REE concentration processes in ion adsorption deposits: Evidence from the Ambohimirahavavy alkaline complex in Madagascar. Ore Geology Reviews. 2019. Vol. 112. N 103027. DOI: 10.1016/j.oregeorev.2019.103027</mixed-citation>
      </ref>
      <ref id="ref24">
        <label>24</label>
        <mixed-citation xml:lang="ru">Denys A., Janots E., Auzende A.-L. et al. Evaluation of selectivity of sequential extraction procedure applied to REE speciation in laterite // Chemical Geology. 2021. Vol. 559. № 119954. DOI: 10.1016/j.chemgeo.2020.119954</mixed-citation>
        <mixed-citation xml:lang="en">Denys A., Janots E., Auzende A.-L. et al. Evaluation of selectivity of sequential extraction procedure applied to REE speciation in laterite. Chemical Geology. 2021. Vol. 559. N 119954. DOI: 10.1016/j.chemgeo.2020.119954</mixed-citation>
      </ref>
      <ref id="ref25">
        <label>25</label>
        <mixed-citation xml:lang="ru">Zhenxiao Wu, Yu Chen, Yang Wang et al. Review of rare earth element (REE) adsorption on and desorption from clay min-erals: Application to formation and mining of ion-adsorption REE deposits // Ore Geology Reviews. 2023. Vol. 157. № 105446. DOI: 10.1016/j.oregeorev.2023.105446</mixed-citation>
        <mixed-citation xml:lang="en">Zhenxiao Wu, Yu Chen, Yang Wang et al. Review of rare earth element (REE) adsorption on and desorption from clay minerals: Application to formation and mining of ion-adsorption REE deposits. Ore Geology Reviews. 2023. Vol. 157. N 105446. DOI: 10.1016/j.oregeorev.2023.105446</mixed-citation>
      </ref>
      <ref id="ref26">
        <label>26</label>
        <mixed-citation xml:lang="ru">Mihalasky M.J., Tucker R.D., Renaud K., Verstraeten I.M. Rare earth element and rare metal inventory of central Asia: Fact Sheet 2017–3089. U.S. Department of the Interior, U.S. Geological Survey, 2018. 4 p. DOI: 10.3133/fs20173089</mixed-citation>
        <mixed-citation xml:lang="en">Mihalasky M.J., Tucker R.D., Renaud K., Verstraeten I.M. Rare earth element and rare metal inventory of central Asia: Fact Sheet 2017–3089. U.S. Department of the Interior, U.S. Geological Survey, 2018, p. 4. DOI: 10.3133/fs20173089</mixed-citation>
      </ref>
      <ref id="ref27">
        <label>27</label>
        <mixed-citation xml:lang="ru">Исаева Л.Д., Дюсембаева К.Ш., Кембаев М.К., Юсупова У. Редкоземельные элементы и формы их нахождения в коре выветривания рудопроявления Талайрык (Северный Казахстан) // Известия Национальной академии наук Республики Казахстан. Серия геологии и технических наук. 2015. Т. 6. № 414. С. 57-65.</mixed-citation>
        <mixed-citation xml:lang="en">Isayeva L.D., Dyussembayeva K.Sh., Kembayev M.K., Yusupova U. Rare earth elements and their forms of occurrence in the weathering crust of ore talayryk (the North Kazakhstan). News of the National Academy of Sciences of the Republic of Kazakhstan. Series of geology and technical sciences. 2015. Vol. 6. N 414, p. 57-65 (in Russian).</mixed-citation>
      </ref>
      <ref id="ref28">
        <label>28</label>
        <mixed-citation xml:lang="ru">Setiawan I. The sequential REE (Rare Earth Elements) extraction of weathered crusts of granitoids from Sibolga, Indonesia // IOP Conference Series: Earth and Environmental Science. 2021. Vol. 882. № 012020. DOI: 10.1088/1755-1315/882/1/012020</mixed-citation>
        <mixed-citation xml:lang="en">Setiawan I. The sequential REE (Rare Earth Elements) extraction of weathered crusts of granitoids from Sibolga, Indonesia. IOP Conference Series: Earth and Environmental Science. 2021. Vol. 882. N 012020. DOI: 10.1088/1755-1315/882/1/012020</mixed-citation>
      </ref>
      <ref id="ref29">
        <label>29</label>
        <mixed-citation xml:lang="ru">Junussov M., Mádai F., Földessy J., Hámor-Vidó M. The Role of Organic Matter in Gold Occurrence: Insights from Western Mecsek Uranium Ore Deposit // Economic and Environmental Geology. 2024. Vol. 57. Iss. 4. P. 371-386. DOI: 10.9719/EEG.2024.57.4.371</mixed-citation>
        <mixed-citation xml:lang="en">Junussov M., Mádai F., Földessy J., Hámor-Vidó M. The Role of Organic Matter in Gold Occurrence: Insights from Western Mecsek Uranium Ore Deposit. Economic and Environmental Geology. 2024. Vol. 57. Iss. 4, p. 371-386. DOI: 10.9719/EEG.2024.57.4.371</mixed-citation>
      </ref>
      <ref id="ref30">
        <label>30</label>
        <mixed-citation xml:lang="ru">Junussov M., Mustapayeva S. Preliminary XRF Analysis of Coal Ash from Jurassic and Carboniferous Coals at Five Kazakh Mines: Industrial and Environmental Comparisons // Applied Sciences. 2024. Vol. 14. Iss. 22. № 10586. DOI: 10.3390/app142210586</mixed-citation>
        <mixed-citation xml:lang="en">Junussov M., Mustapayeva S. Preliminary XRF Analysis of Coal Ash from Jurassic and Carboniferous Coals at Five Kazakh Mines: Industrial and Environmental Comparisons. Applied Sciences. 2024. Vol. 14. Iss. 22. N 10586. DOI: 10.3390/app142210586</mixed-citation>
      </ref>
      <ref id="ref31">
        <label>31</label>
        <mixed-citation xml:lang="ru">Junussov M., Madai F., Kristály F. et al. Preliminary analysis on roles of metal–organic compounds in the formation of in-visible gold // Acta Geochimica. 2021. Vol. 40. Iss. 6. P. 1050-1072. DOI: 10.1007/s11631-021-00494-y</mixed-citation>
        <mixed-citation xml:lang="en">Junussov M., Madai F., Kristály F. et al. Preliminary analysis on roles of metal–organic compounds in the formation of in-visible gold. Acta Geochimica. 2021. Vol. 40. Iss. 6, p. 1050-1072. DOI: 10.1007/s11631-021-00494-y</mixed-citation>
      </ref>
      <ref id="ref32">
        <label>32</label>
        <mixed-citation xml:lang="ru">Kretz R. Symbols for rock-forming minerals // American Mineralogist. 1983. Vol. 68. № 1-2. P. 277-279.</mixed-citation>
        <mixed-citation xml:lang="en">Kretz R. Symbols for rock-forming minerals. American Mineralogist. 1983. Vol. 68. N 1-2, p. 277-279.</mixed-citation>
      </ref>
      <ref id="ref33">
        <label>33</label>
        <mixed-citation xml:lang="ru">Shi-Yong Wei, Fan Liu, Xiong-Han Feng et al. Formation and Transformation of Iron Oxide–Kaolinite Associations in the Presence of Iron(II) // Soil Science Society of America Journal. 2011. Vol. 75. Iss. 1. P. 45-55. DOI: 10.2136/sssaj2010.0175</mixed-citation>
        <mixed-citation xml:lang="en">Shi-Yong Wei, Fan Liu, Xiong-Han Feng et al. Formation and Transformation of Iron Oxide–Kaolinite Associations in the Presence of Iron(II). Soil Science Society of America Journal. 2011. Vol. 75. Iss. 1, p. 45-55. DOI: 10.2136/sssaj2010.0175</mixed-citation>
      </ref>
      <ref id="ref34">
        <label>34</label>
        <mixed-citation xml:lang="ru">Sababa E., Essomba Owona L.G., Temga J.P., Ndjigui P.-D. Petrology of weathering materials developed on granites in Biou area, North-Cameroon: implication for rare-earth elements (REE) exploration in semi-arid regions // Heliyon. 2021. Vol. 7. Iss. 12. № e08581. DOI: 10.1016/j.heliyon.2021.e08581</mixed-citation>
        <mixed-citation xml:lang="en">Sababa E., Essomba Owona L.G., Temga J.P., Ndjigui P.-D. Petrology of weathering materials developed on granites in Biou area, North-Cameroon: implication for rare-earth elements (REE) exploration in semi-arid regions. Heliyon. 2021. Vol. 7. Iss. 12. N e08581. DOI: 10.1016/j.heliyon.2021.e08581</mixed-citation>
      </ref>
      <ref id="ref35">
        <label>35</label>
        <mixed-citation xml:lang="ru">Deng-hong Wang, Zhi Zhao, Yang Yu et al. Exploration and research progress on ion-adsorption type REE deposit in South China // China Geology. 2018. Vol. 1. Iss. 3. P. 415-424. DOI: 10.31035/cg2018022</mixed-citation>
        <mixed-citation xml:lang="en">Deng-hong Wang, Zhi Zhao, Yang Yu et al. Exploration and research progress on ion-adsorption type REE deposit in South China. China Geology. 2018. Vol. 1. Iss. 3, p. 415-424. DOI: 10.31035/cg2018022</mixed-citation>
      </ref>
      <ref id="ref36">
        <label>36</label>
        <mixed-citation xml:lang="ru">Wang Zhen, Chen Zhen Yu, Zhao Zhi et al. REE mineral and geochemical characteristics of Neoproterozoic metamorphic rocks in South Jiangxi Province // Mineral Deposits. 2019. Vol. 38. № 4. P. 837-850 (in Chinese). DOI: 10.16111/j.0258-7106.2019.04.010</mixed-citation>
        <mixed-citation xml:lang="en">Wang Zhen, Chen Zhen Yu, Zhao Zhi et al. REE mineral and geochemical characteristics of Neoproterozoic metamorphic rocks in South Jiangxi Province. Mineral Deposits. 2019. Vol. 38. N 4, p. 837-850 (in Chinese). DOI: 10.16111/j.0258-7106.2019.04.010</mixed-citation>
      </ref>
      <ref id="ref37">
        <label>37</label>
        <mixed-citation xml:lang="ru">Sanematsu K., Kon Y. Geochemical characteristics determined by multiple extraction from ion-adsorption type REE ores in Dingnan County of Jiangxi Province, South China // Bulletin of the Geological Survey of Japan. 2013. Vol. 64. № 11/12. P. 313-330.</mixed-citation>
        <mixed-citation xml:lang="en">Sanematsu K., Kon Y. Geochemical characteristics determined by multiple extraction from ion-adsorption type REE ores in Dingnan County of Jiangxi Province, South China. Bulletin of the Geological Survey of Japan. 2013. Vol. 64. N 11/12, p. 313-330.</mixed-citation>
      </ref>
      <ref id="ref38">
        <label>38</label>
        <mixed-citation xml:lang="ru">Li M.Y.H., Mei-Fu Zhou, Williams-Jones A.E. The Genesis of Regolith-Hosted Heavy Rare Earth Element Deposits: Insights from the World-Class Zudong Deposit in Jiangxi Province, South China // Economic Geology. 2019. Vol. 114. № 3. P. 541-568. DOI: 10.5382/econgeo.4642</mixed-citation>
        <mixed-citation xml:lang="en">Li M.Y.H., Mei-Fu Zhou, Williams-Jones A.E. The Genesis of Regolith-Hosted Heavy Rare Earth Element Deposits: Insights from the World-Class Zudong Deposit in Jiangxi Province, South China. Economic Geology. 2019. Vol. 114. N 3, p. 541-568. DOI: 10.5382/econgeo.4642</mixed-citation>
      </ref>
      <ref id="ref39">
        <label>39</label>
        <mixed-citation xml:lang="ru">Li M.Y.H., Mei-Fu Zhou. The role of clay minerals in formation of the regolith-hosted heavy rare earth element deposits // American Mineralogist. 2020. Vol. 105. № 1. P. 92-108. DOI: 10.2138/am-2020-7061</mixed-citation>
        <mixed-citation xml:lang="en">Li M.Y.H., Mei-Fu Zhou. The role of clay minerals in formation of the regolith-hosted heavy rare earth element deposits. American Mineralogist. 2020. Vol. 105. N 1, p. 92-108. DOI: 10.2138/am-2020-7061</mixed-citation>
      </ref>
      <ref id="ref40">
        <label>40</label>
        <mixed-citation xml:lang="ru">Yuejun Wang, Weiming Fan, Guowei Zhang, Yanhua Zhang. Phanerozoic tectonics of the South China Block: Key obser-vations and controversies // Gondwana Research. 2013. Vol. 23. Iss. 4. P. 1273-1305. DOI: 10.1016/j.gr.2012.02.019</mixed-citation>
        <mixed-citation xml:lang="en">Yuejun Wang, Weiming Fan, Guowei Zhang, Yanhua Zhang. Phanerozoic tectonics of the South China Block: Key obser-vations and controversies. Gondwana Research. 2013. Vol. 23. Iss. 4, p. 1273-1305. DOI: 10.1016/j.gr.2012.02.019</mixed-citation>
      </ref>
      <ref id="ref41">
        <label>41</label>
        <mixed-citation xml:lang="ru">Bern C.R., Shah A.K., Benzel W.M., Lowers H.A. The distribution and composition of REE-bearing minerals in placers of the Atlantic and Gulf coastal plains, USA // Journal Geochemical Exploration. 2016. Vol. 162. P. 50-61. DOI: 10.1016/j.gexplo.2015.12.011</mixed-citation>
        <mixed-citation xml:lang="en">Bern C.R., Shah A.K., Benzel W.M., Lowers H.A. The distribution and composition of REE-bearing minerals in placers of the Atlantic and Gulf coastal plains, USA. Journal Geochemical Exploration. 2016. Vol. 162, p. 50-61. DOI: 10.1016/j.gexplo.2015.12.011</mixed-citation>
      </ref>
      <ref id="ref42">
        <label>42</label>
        <mixed-citation xml:lang="ru">Xiangping Zhu, Bin Zhang, Guotao Ma et al. Mineralization of ion-adsorption type rare earth deposits in Western Yunnan, China // Ore Geology Reviews. 2022. Vol. 148. № 104984. DOI: 10.1016/j.oregeorev.2022.104984</mixed-citation>
        <mixed-citation xml:lang="en">Xiangping Zhu, Bin Zhang, Guotao Ma et al. Mineralization of ion-adsorption type rare earth deposits in Western Yunnan, China. Ore Geology Reviews. 2022. Vol. 148. N 104984. DOI: 10.1016/j.oregeorev.2022.104984</mixed-citation>
      </ref>
      <ref id="ref43">
        <label>43</label>
        <mixed-citation xml:lang="ru">Исаева Л.Д., Дюсембаева К.Ш., Кембаев М.К. и др. Формы нахождения редкоземельных элементов в коре вывет-ривания месторождения Кундыбай (Северный Казахстан) // Известия Национальной академии наук Республики Казахстан. Серия геологии и технических наук. 2015. Т. 2. № 410. С. 23-30.</mixed-citation>
        <mixed-citation xml:lang="en">Isayeva L.D., Dyussembayeva K.Sh., Kembayev M.K. et al. Forms of occurrence of rare earth elements in the weathering crust of the Kundybay deposit (North Kazakhstan). News of the National Academy of Sciences of the Republic of Kazakhstan. Series of geology and technical sciences. 2015. Vol. 2. N 410, p. 23-30 (in Russian).</mixed-citation>
      </ref>
      <ref id="ref44">
        <label>44</label>
        <mixed-citation xml:lang="ru">Alshameri A., Hongping He, Chen Xin et al. Understanding the role of natural clay minerals as effective adsorbents and al-ternative source of rare earth elements: Adsorption operative parameters // Hydrometallurgy. 2019. Vol. 185. P. 149-161. DOI: 10.1016/j.hydromet.2019.02.016</mixed-citation>
        <mixed-citation xml:lang="en">Alshameri A., Hongping He, Chen Xin et al. Understanding the role of natural clay minerals as effective adsorbents and al-ternative source of rare earth elements: Adsorption operative parameters. Hydrometallurgy. 2019. Vol. 185, p. 149-161. DOI: 10.1016/j.hydromet.2019.02.016</mixed-citation>
      </ref>
      <ref id="ref45">
        <label>45</label>
        <mixed-citation xml:lang="ru">Meijun Yang, Xiaoliang Liang, Lingya Ma et al. Adsorption of REEs on kaolinite and halloysite: A link to the REE distri-bution on clays in the weathering crust of granite // Chemical Geology. 2019. Vol. 525. P. 210-217. DOI: 10.1016/j.chemgeo.2019.07.024</mixed-citation>
        <mixed-citation xml:lang="en">Meijun Yang, Xiaoliang Liang, Lingya Ma et al. Adsorption of REEs on kaolinite and halloysite: A link to the REE distribution on clays in the weathering crust of granite. Chemical Geology. 2019. Vol. 525, p. 210-217. DOI: 10.1016/j.chemgeo.2019.07.024</mixed-citation>
      </ref>
      <ref id="ref46">
        <label>46</label>
        <mixed-citation xml:lang="ru">Zhenyue Zhang, Changyu Zhou, Wendou Chen et al. Effects of Ammonium Salts on Rare Earth Leaching Process of Weath-ered Crust Elution-Deposited Rare Earth Ores // Metals. 2023. Vol. 13. Iss. 6. № 1112. DOI: 10.3390/met13061112</mixed-citation>
        <mixed-citation xml:lang="en">Zhenyue Zhang, Changyu Zhou, Wendou Chen et al. Effects of Ammonium Salts on Rare Earth Leaching Process of Weath-ered Crust Elution-Deposited Rare Earth Ores. Metals. 2023. Vol. 13. Iss. 6. N 1112. DOI: 10.3390/met13061112</mixed-citation>
      </ref>
      <ref id="ref47">
        <label>47</label>
        <mixed-citation xml:lang="ru">Lifen Yang, Cuicui Li, Dashan Wang et al. Leaching ion adsorption rare earth by aluminum sulfate for increasing efficiency and lowering the environmental impact // Journal of Rare Earths. 2019. Vol. 37. Iss. 4. P. 429-436. DOI: 10.1016/j.jre.2018.08.012</mixed-citation>
        <mixed-citation xml:lang="en">Lifen Yang, Cuicui Li, Dashan Wang et al. Leaching ion adsorption rare earth by aluminum sulfate for increasing efficiency and lowering the environmental impact. Journal of Rare Earths. 2019. Vol. 37. Iss. 4, p. 429-436. DOI: 10.1016/j.jre.2018.08.012</mixed-citation>
      </ref>
      <ref id="ref48">
        <label>48</label>
        <mixed-citation xml:lang="ru">Zhi Zhao, Denghong Wang, Leon Bagas, Zhenyu Chen. Geochemical and REE mineralogical characteristics of the Zhaibei Granite in Jiangxi Province, southern China, and a model for the genesis of ion-adsorption REE deposits // Ore Geology Reviews. 2022. Vol. 140. № 104579. DOI: 10.1016/j.oregeorev.2021.104579</mixed-citation>
        <mixed-citation xml:lang="en">Zhi Zhao, Denghong Wang, Leon Bagas, Zhenyu Chen. Geochemical and REE mineralogical characteristics of the Zhaibei Granite in Jiangxi Province, southern China, and a model for the genesis of ion-adsorption REE deposits. Ore Geology Reviews. 2022. Vol. 140. N 104579. DOI: 10.1016/j.oregeorev.2021.104579</mixed-citation>
      </ref>
      <ref id="ref49">
        <label>49</label>
        <mixed-citation xml:lang="ru">Nesbitt H.W. Chapter 6 – Diagenesis and metasomatism of weathering profiles, with emphasis on Precambrian paleosols // Developments in Earth Surface Processes. Elsevier, 1992. Vol. 2: Weathering, Soils &amp; Paleosols. P. 127-152. DOI: 10.1016/B978-0-444-89198-3.50011-8</mixed-citation>
        <mixed-citation xml:lang="en">Nesbitt H.W. Chapter 6 – Diagenesis and metasomatism of weathering profiles, with emphasis on Precambrian paleosols. Developments in Earth Surface Processes. Elsevier, 1992. Vol. 2: Weathering, Soils &amp; Paleosols, p. 127-152. DOI: 10.1016/B978-0-444-89198-3.50011-8</mixed-citation>
      </ref>
      <ref id="ref50">
        <label>50</label>
        <mixed-citation xml:lang="ru">Chaoxi Fan, Cheng Xu, Aiguo Shi et al. Origin of heavy rare earth elements in highly fractionated peraluminous granites // Geochimica et Cosmochimica Acta. 2023. Vol. 343. P. 371-383. DOI: 10.1016/j.gca.2022.12.019</mixed-citation>
        <mixed-citation xml:lang="en">Chaoxi Fan, Cheng Xu, Aiguo Shi et al. Origin of heavy rare earth elements in highly fractionated peraluminous granites. Geochimica et Cosmochimica Acta. 2023. Vol. 343, p. 371-383. DOI: 10.1016/j.gca.2022.12.019</mixed-citation>
      </ref>
      <ref id="ref51">
        <label>51</label>
        <mixed-citation xml:lang="ru">Фелицын С.Б., Алфимова Н.А., Климова Е.В. Фракционирование РЗЭ при кислотном выщелачивании гранитоидов // Литология и полезные ископаемые. 2011. № 4. С. 439-442.</mixed-citation>
        <mixed-citation xml:lang="en">Felitsyn S.B., Alfimova N.A., Klimova E.V. Fractionation of Rare Earth Elements in the Acid Treatment of Granitoids. Lithology and Mineral Resources. 2011. Vol. 46. N 4, p. 391-394. DOI: 10.1134/S0024490211040031</mixed-citation>
      </ref>
      <ref id="ref52">
        <label>52</label>
        <mixed-citation xml:lang="ru">Дубинин А.В. Геохимия редкоземельных элементов в океане. М.: Наука, 2006. 360 с.</mixed-citation>
        <mixed-citation xml:lang="en">Dubinin A.V. Geochemistry of rare earth elements in the ocean. Мoscow: Nauka, 2006, p. 360.</mixed-citation>
      </ref>
      <ref id="ref53">
        <label>53</label>
        <mixed-citation xml:lang="ru">Developments in Geochemistry / P.Henderson. Elsevier, 1984. Vol. 2: Rare Earth Element Geochemistry. 522 p.</mixed-citation>
        <mixed-citation xml:lang="en">Developments in Geochemistry. Ed. by P.Henderson. Elsevier, 1984. Vol. 2: Rare Earth Element Geochemistry, p. 522.</mixed-citation>
      </ref>
      <ref id="ref54">
        <label>54</label>
        <mixed-citation xml:lang="ru">Матреничев В.А., Климова Е.В. Экспериментальное моделирование условий формирования докембрийских кор выветривания. Особенности дренажных растворов и перераспределение лантаноидов в гипергенном профиле // Вестник Санкт-Петербургского университета. Науки о Земле. 2017. Т. 62. № 4. С. 389-408. DOI: 10.21638/11701/spbu07.2017.405</mixed-citation>
        <mixed-citation xml:lang="en">Matrenichev V.A., Klimova E.V. Experimental modeling of the conditions for the formation of Precambrian weathering profiles. Composition of solutions and redistribution of lanthanides. Vestnik of Saint-Petersburg University. Earth Sciences. 2017. Vol. 62. N 4, p. 389-408 (in Russian). DOI: 10.21638/11701/spbu07.2017.405</mixed-citation>
      </ref>
      <ref id="ref55">
        <label>55</label>
        <mixed-citation xml:lang="ru">De Baar H.J.W., Bacon M.P., Brewer P.G., Bruland K.W. Rare earth elements in the Pacific and Atlantic Oceans // Geochimica et Cosmochimica Acta. 1985. Vol. 49. Iss. 9. P. 1943-1959. DOI: 10.1016/0016-7037(85)90089-4</mixed-citation>
        <mixed-citation xml:lang="en">De Baar H.J.W., Bacon M.P., Brewer P.G., Bruland K.W. Rare earth elements in the Pacific and Atlantic Oceans. Geochimica et Cosmochimica Acta. 1985. Vol. 49. Iss. 9, p. 1943-1959. DOI: 10.1016/0016-7037(85)90089-4</mixed-citation>
      </ref>
      <ref id="ref56">
        <label>56</label>
        <mixed-citation xml:lang="ru">Li M.Y.H., Mei-Fu Zhou, Williams-Jones A.E. Controls on the Dynamics of Rare Earth Elements During Subtropical Hillslope Processes and Formation of Regolith-Hosted Deposits // Economic Geology. 2020. Vol. 115. № 5. P. 1097-1118. DOI: 10.5382/econgeo.4727</mixed-citation>
        <mixed-citation xml:lang="en">Li M.Y.H., Mei-Fu Zhou, Williams-Jones A.E. Controls on the Dynamics of Rare Earth Elements During Subtropical Hillslope Processes and Formation of Regolith-Hosted Deposits. Economic Geology. 2020. Vol. 115. N 5, p. 1097-1118. DOI: 10.5382/econgeo.4727</mixed-citation>
      </ref>
      <ref id="ref57">
        <label>57</label>
        <mixed-citation xml:lang="ru">Ni Su, Shouye Yang, Yulong Guo et al. Revisit of rare earth element fractionation during chemical weathering and river sediment transport // Geochemistry, Geophysics, Geosystems. 2017. Vol. 18. Iss. 3. P. 935-955. DOI: 10.1002/2016GC006659</mixed-citation>
        <mixed-citation xml:lang="en">Ni Su, Shouye Yang, Yulong Guo et al. Revisit of rare earth element fractionation during chemical weathering and river sediment transport. Geochemistry, Geophysics, Geosystems. 2017. Vol. 18. Iss. 3, p. 935-955. DOI: 10.1002/2016GC006659</mixed-citation>
      </ref>
    </ref-list>
  </back>
</article>
