2411-3336 2541-9404 Записки Горного института Journal of Mining Institute Санкт-Петербургский горный университет императрицы Екатерины ΙΙ Empress Catherine II Saint Petersburg Mining University PUUADY pmi-16458 https://pmi.spmi.ru/pmi/article/view/16458 Геотехнология и инженерная геология Geotechnical Engineering and Engineering Geology Quantitative determination of sulfur forms in bottom sediments for rapid assessment of the industrial facilities impact on aquatic ecosystems Количественное определение форм серы в донных отложениях для экспресс-оценки влияния промышленных объектов на водные экосистемы Sverchkov Ivan P. Сверчков И. П. Sverchkov Ivan P. sverchkov_ip@pers.spmi.ru 0000-0003-4725-0050 Санкт-Петербургский горный университет императрицы Екатерины II (Россия) Empress Catherine ΙΙ Saint Petersburg Mining University (Russia) Povarov Vladimir G. Поваров В. Г. Povarov Vladimir G. povarov_vg@pers.spmi.ru 0000-0001-6710-0514 Санкт-Петербургский горный университет императрицы Екатерины II (Россия) Empress Catherine ΙΙ Saint Petersburg Mining University (Russia) 04 07 2024 2024 267 372 380 16 04 2024 03 06 2024 04 07 2024 © 2024 И. П. Сверчков, В. Г. Поваров © 2024 Ivan P. Sverchkov, Vladimir G. Povarov 2024 И. П. Сверчков, В. Г. Поваров Ivan P. Sverchkov, Vladimir G. Povarov Эта статья доступна по лицензии Creative Commons Attribution 4.0 International (CC BY 4.0) This article is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0) https://pmi.spmi.ru/pmi/article/view/16458

Описан рентгенофлуоресцентный метод количественного анализа сульфатной и общей серы в донных отложениях водотоков и водоемов, находящихся в зоне воздействия промышленных предприятий. Количественное определение форм серы производилось путем анализа формы характеристических линий SKα1,2 и SKβ1,3, а также линии-сателлита SKβ′ на рентгеновских эмиссионных спектрах, измеренных рентгенофлуоресцентным спектрометром с дисперсией по длине волны. Показано, что данные характеристические линии позволяют не только определить преобладающую форму серы, но и провести количественный анализ отдельно сульфатной, а также общей серы после подгонки пиков и отдельного анализа перекрывающихся друг с другом спектральных линий. Результаты количественного анализа химического состояния серы предложенным рентгенофлуоресцентным методом были сопоставлены с результатами атомно-эмиссионной спектроскопии с индуктивно связанной плазмой и элементного анализа, а также сертифицированными стандартными образцами донных отложений и почв и хорошо согласуются друг с другом.

The article describes an X-ray fluorescence method for quantitative analysis of sulfate and total sulfur in bottom sediments of watercourses and reservoirs located in the area of industrial enterprises impact. The quantitative determination of sulfur forms was carried out by analyzing the characteristic curves SKα1,2 and SKβ1,3, as well as the satellite line SKβ′ on X-ray emission spectra measured by an X-ray fluorescence spectrometer with wavelength dispersion. The study shows that these characteristic curves allow not only to determine the predominant form of sulfur, but also to separately conduct quantitative analyses of sulfates and total sulfur after fitting peaks and to separately analyze overlapping spectral lines. The results of quantitative analysis of the chemical state of sulfur by the proposed X-ray fluorescence method were compared with the results of inductively coupled plasma atomic emission spectroscopy and elemental analysis, as well as certified standard samples of soils and sediments. The results are in good agreement with each other.

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