2411-3336 2541-9404 Записки Горного института Journal of Mining Institute Санкт-Петербургский горный университет императрицы Екатерины ΙΙ Empress Catherine II Saint Petersburg Mining University YORQKB pmi-16440 https://pmi.spmi.ru/pmi/article/view/16440 Геотехнология и инженерная геология Geotechnical Engineering and Engineering Geology The influence of ocean anoxia on conditions for the Domanik deposits formation Влияние аноксии океана на условия формирования доманиковых отложений Plotnikova Irina N. Плотникова И. Н. Plotnikova Irina N. irena-2005@rambler.ru 0000-0003-4807-1679 Институт прикладных исследований АН Республики Татарстан (Казань, Россия) Institute of Advanced Studies, Academy of Sciences of the Republic of Tatarstan (Kazan, Russia) Ostroukhov Sergei B. Остроухов С. Б. Ostroukhov Sergei B. ostso@mail.ru 0009-0003-4209-6290 Институт прикладных исследований АН Республики Татарстан (Казань, Россия) Institute of Advanced Studies, Academy of Sciences of the Republic of Tatarstan (Kazan, Russia) Pronin Nikita V. Пронин Н. В. Pronin Nikita V. nikita.oilgeol@mail.ru 0009-0006-8270-3659 ООО «РН-БашНИПИнефть» (Уфа, Россия) OOO RN-BashNIPIneft (Ufa, Russia) 12 11 2024 2024 269 803 814 10 04 2024 14 10 2024 12 11 2024 © Irina N. Plotnikova, Sergei B. Ostroukhov, Nikita V. Pronin 2024 И. Н. Плотникова, С. Б. Остроухов, Н. В. Пронин Irina N. Plotnikova, Sergei B. Ostroukhov, Nikita V. Pronin CC BY 4.0 https://pmi.spmi.ru/pmi/article/view/16440

В статье рассмотрено одно из условий формирования отложений доманиковых фаций на примере территорий Татарстана и Башкортостана. Основной акцент сделан на влияние аноксических условий палеобассейна на формирование высокоуглеродистых толщ. Детальное исследование углеводородного состава доманиковых отложений позволило установить в их составе характерные биомаркеры. Они основываются на составе и строении диагенетических продуктов биологических соединений, входящих в состав серных бактерий, обитающих в условиях аноксии/эвксинии палеобассейна. К таким соединениям относятся диарилизопреноиды составов С40 – изорениератан и палеорениератан. Особое место при изучении доманиковых отложений также занимают тетраметилбензолы состава С10. Их появление в составе органических веществ данных отложений – результат преобразования соединений серных бактерий. Диарилизопреноиды и тетраметилбензолы являются надежным индикатором аноксических условий формирования доманиковых отложений. При этом по соотношению изомеров тетраметибензолов можно установить термодинамическое состояние углеводородной среды.

The article considers one of conditions for the Domanik facies formation on the example of Tatarstan and Bashkortostan. The main emphasis is on the influence of anoxic paleobasin conditions on the high-carbon strata formation. A detailed study of the hydrocarbon composition of Domanik deposits made it possible to find characteristic biomarkers in their composition. They are based on the composition and structure of diagenetic products of biological compounds composing the sulphur bacteria living in anoxic/euxinic paleobasin conditions. Such compounds include C40 diaryl isoprenoids – isorenieratane and paleorenieratane. C10 tetramethylbenzenes also occupy a special place in the Domanik deposits study. Their appearance in the composition of organic matter of these deposits results from the transformation of sulphur bacteria compounds. Diaryl isoprenoids and tetramethylbenzenes are a reliable indicator of anoxic conditions of the Domanik deposits formation. The thermodynamic state of the hydrocarbon environment can be determined from the ratio of tetramethylbenzene isomers.

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