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    <journal-meta>
      <journal-id journal-id-type="issn">2411-3336</journal-id>
      <journal-id journal-id-type="eissn">2541-9404</journal-id>
      <journal-title-group>
        <journal-title xml:lang="ru">Записки Горного института</journal-title>
        <journal-title xml:lang="en">Journal of Mining Institute</journal-title>
      </journal-title-group>
      <publisher>
        <publisher-name xml:lang="ru">Санкт-Петербургский горный университет императрицы Екатерины ΙΙ</publisher-name>
        <publisher-name xml:lang="en">Empress Catherine II Saint Petersburg Mining University</publisher-name>
      </publisher>
    </journal-meta>
    <article-meta>
      <article-id custom-type="edn" pub-id-type="custom">XGGRVF</article-id>
      <article-id custom-type="pmi" pub-id-type="custom">pmi-16157</article-id>
      <article-id pub-id-type="uri">https://pmi.spmi.ru/pmi/article/view/16157</article-id>
      <article-categories>
        <subj-group subj-group-type="section-heading" xml:lang="ru">
          <subject>Геология</subject>
        </subj-group>
        <subj-group subj-group-type="section-heading" xml:lang="en">
          <subject>Geology</subject>
        </subj-group>
      </article-categories>
      <title-group>
        <article-title xml:lang="en">Depth distribution of radiation defects in irradiated diamonds by confocal Raman spectroscopy</article-title>
        <trans-title-group xml:lang="ru">
          <trans-title>Распределение радиационных дефектов по глубине в облученных алмазах: данные конфокальной микроспектроскопии</trans-title>
        </trans-title-group>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Ardalkar</surname>
            <given-names>Rajendra M.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Ардалкар</surname>
              <given-names>Р. М.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Ardalkar</surname>
              <given-names>Rajendra M.</given-names>
            </name>
          </name-alternatives>
          <email>avramanareddy1@gmail.com</email>
          <contrib-id contrib-id-type="orcid">0000-0002-5981-9972</contrib-id>
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          <aff>
            <institution xml:lang="ru">Геммологический институт Индии (Мумбаи, Индия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Gemmological Institute of India (Mumbai, India)</institution>
          </aff>
        </aff-alternatives>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Salunkhe</surname>
            <given-names>Yogesh D.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Салунхе</surname>
              <given-names>Й. Д.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Salunkhe</surname>
              <given-names>Yogesh D.</given-names>
            </name>
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          <email>avramanareddy1@gmail.com</email>
          <contrib-id contrib-id-type="orcid">0000-0001-9256-6447</contrib-id>
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          <aff>
            <institution xml:lang="ru">Геммологический институт Индии (Мумбаи, Индия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Gemmological Institute of India (Mumbai, India)</institution>
          </aff>
        </aff-alternatives>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Gaonkar</surname>
            <given-names>Mahesh P.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Гаонкар</surname>
              <given-names>М. П.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Gaonkar</surname>
              <given-names>Mahesh P.</given-names>
            </name>
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          <email>avramanareddy1@gmail.com</email>
          <contrib-id contrib-id-type="orcid">0000-0002-3053-7867</contrib-id>
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            <institution xml:lang="ru">Геммологический институт Индии (Мумбаи, Индия)</institution>
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          <aff>
            <institution xml:lang="en">Gemmological Institute of India (Mumbai, India)</institution>
          </aff>
        </aff-alternatives>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Mane</surname>
            <given-names>Sandesh N.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Мане</surname>
              <given-names>С. Н.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Mane</surname>
              <given-names>Sandesh N.</given-names>
            </name>
          </name-alternatives>
          <email>avramanareddy1@gmail.com</email>
          <contrib-id contrib-id-type="orcid">0000-0002-0587-7923</contrib-id>
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          <aff>
            <institution xml:lang="ru">Геммологический институт Индии (Мумбаи, Индия)</institution>
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          <aff>
            <institution xml:lang="en">Gemmological Institute of India (Mumbai, India)</institution>
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        </aff-alternatives>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Ghaisas</surname>
            <given-names>Omkar A.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Гаисас</surname>
              <given-names>О. А.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Ghaisas</surname>
              <given-names>Omkar A.</given-names>
            </name>
          </name-alternatives>
          <email>avramanareddy1@gmail.com</email>
          <contrib-id contrib-id-type="orcid">0009-0002-5851-2909</contrib-id>
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          <aff>
            <institution xml:lang="ru">Геммологический институт Индии (Мумбаи, Индия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Gemmological Institute of India (Mumbai, India)</institution>
          </aff>
        </aff-alternatives>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Desai</surname>
            <given-names>Shripalkumar N.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Десаи</surname>
              <given-names>Ш. Н.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Desai</surname>
              <given-names>Shripalkumar N.</given-names>
            </name>
          </name-alternatives>
          <email>avramanareddy1@gmail.com</email>
          <contrib-id contrib-id-type="orcid">0009-0000-0101-0102</contrib-id>
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          <aff>
            <institution xml:lang="ru">Геммологический институт Индии (Мумбаи, Индия)</institution>
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          <aff>
            <institution xml:lang="en">Gemmological Institute of India (Mumbai, India)</institution>
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        </aff-alternatives>
        <contrib contrib-type="author" corresp="yes">
          <name name-style="eastern">
            <surname>Reddy</surname>
            <given-names>Annareddy V. R.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Редди</surname>
              <given-names>А. В. Р.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Reddy</surname>
              <given-names>Annareddy V. R.</given-names>
            </name>
          </name-alternatives>
          <email>avramanareddy1@gmail.com</email>
          <contrib-id contrib-id-type="orcid">0000-0002-3396-9606</contrib-id>
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          <aff>
            <institution xml:lang="ru">Геммологический институт Индии (Мумбаи, Индия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Gemmological Institute of India (Mumbai, India)</institution>
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      <pub-date pub-type="epub" iso-8601-date="2024-01-10">
        <day>10</day>
        <month>01</month>
        <year>2024</year>
      </pub-date>
      <pub-date date-type="collection">
        <year>2024</year>
      </pub-date>
      <volume>266</volume>
      <fpage>179</fpage>
      <lpage>187</lpage>
      <history>
        <date date-type="received" iso-8601-date="2023-02-10">
          <day>10</day>
          <month>02</month>
          <year>2023</year>
        </date>
        <date date-type="accepted" iso-8601-date="2023-09-20">
          <day>20</day>
          <month>09</month>
          <year>2023</year>
        </date>
        <date date-type="rev-recd" iso-8601-date="2024-04-25">
          <day>25</day>
          <month>04</month>
          <year>2024</year>
        </date>
      </history>
      <permissions>
        <copyright-statement xml:lang="ru">© 2024 Р. М. Ардалкар, Й. Д. Салунхе, М. П. Гаонкар, С. Н. Мане, О. А. Гаисас, Ш. Н. Десаи, А. В. Р. Редди</copyright-statement>
        <copyright-statement xml:lang="en">© 2024 Rajendra M. Ardalkar, Yogesh D. Salunkhe, Mahesh P. Gaonkar, Sandesh N. Mane, Omkar A. Ghaisas, Shripalkumar N. Desai, Annareddy V. R. Reddy</copyright-statement>
        <copyright-year>2024</copyright-year>
        <copyright-holder xml:lang="ru">Р. М. Ардалкар, Й. Д. Салунхе, М. П. Гаонкар, С. Н. Мане, О. А. Гаисас, Ш. Н. Десаи, А. В. Р. Редди</copyright-holder>
        <copyright-holder xml:lang="en">Rajendra M. Ardalkar, Yogesh D. Salunkhe, Mahesh P. Gaonkar, Sandesh N. Mane, Omkar A. Ghaisas, Shripalkumar N. Desai, Annareddy V. R. Reddy</copyright-holder>
        <license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/4.0" xml:lang="ru">
          <license-p>Эта статья доступна по лицензии Creative Commons Attribution 4.0 International (CC BY 4.0)</license-p>
        </license>
        <license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/4.0" xml:lang="en">
          <license-p>This article is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0)</license-p>
        </license>
      </permissions>
      <self-uri xlink:type="simple" xlink:href="https://pmi.spmi.ru/pmi/article/view/16157">https://pmi.spmi.ru/pmi/article/view/16157</self-uri>
      <abstract xml:lang="ru">
        <p>Исследована природа окраски пяти алмазов. Согласно результатам исследования с применением методов инфракрасной спектроскопии на основе преобразования Фурье, исследования поглощения в УФ, видимой и ближней ИК-областях (UV-Vis-NIR) и фотолюминесцентной спектроскопии, они являются природными алмазами типа Ia. Распределение интенсивности окраски по глубине определялось путем измерения интенсивности пика ФЛ при 741 нм (центр GR1) при возбуждении лазером с длиной волны 633 нм на рамановском конфокальном микроскопе. Для учета геометрических факторов профили распределения дефектов были нормализованы относительно интенсивности рамановского пика алмаза (691 нм). Для двух алмазов интенсивность пика GR1 (741 нм) резко снижалась до глубины 10 мкм, а затем сравнялась с фоновым уровнем, что характерно для облучения α-частицами из природных источников, таких как уран. В трех кристаллах профили незначительно меняются с глубиной, а интенсивность окраски близка к равномерной, что характерно для электронного или нейтронного облучений.</p>
      </abstract>
      <abstract xml:lang="en">
        <p>Five colored diamonds were investigated. According to the results of the study by FTIR, UV-Vis-NIR and Photoluminescence spectroscopy, they are natural type Ia diamonds. The depth distribution of the color intensity was carried out by measuring the intensity of the PL peak at 741 nm (GR1 center) upon excitation by a laser with a wavelength of 633 nm of Raman Confocal microscope. To minimise the perturbation due to geometrical effects, defect distribution profiles were normalised with respect to diamond Raman peak intensity (691 nm) point by point. For two diamonds, the intensity of the GR1 peak (741 nm) sharply decreased to a depth of 10 µm, and then became equal to the background level, which is typical for irradiation with alpha particles from natural sources like uranium. In other diamonds, the profiles vary slightly with depth, and the color intensity is close to uniform, which is for irradiation with accelerated electrons or neutrons. The source of radiation has not been determined. However, long duration radioactivity measurements of the diamonds suggested that neutrons were not used for colour centers production in the diamonds studied.</p>
      </abstract>
      <kwd-group xml:lang="ru">
        <title>Ключевые слова</title>
        <kwd>конфокальная рамановская микроскопия</kwd>
        <kwd>цветной алмаз</kwd>
        <kwd>профиль глубины</kwd>
        <kwd>ионизирующее  излучение</kwd>
        <kwd>облучение</kwd>
        <kwd>фотолюминесценция</kwd>
        <kwd>нормализация</kwd>
        <kwd>GR1</kwd>
      </kwd-group>
      <kwd-group xml:lang="en">
        <title>Keywords</title>
        <kwd>confocal Raman microscopy</kwd>
        <kwd>coloured diamond</kwd>
        <kwd>depth profile</kwd>
        <kwd>ionising radiation</kwd>
        <kwd>irradiation</kwd>
        <kwd>photoluminescence</kwd>
        <kwd>normalization</kwd>
        <kwd>GR1</kwd>
      </kwd-group>
    </article-meta>
  </front>
  <body/>
  <back>
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