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  <front>
    <journal-meta>
      <journal-id journal-id-type="issn">2411-3336</journal-id>
      <journal-id journal-id-type="eissn">2541-9404</journal-id>
      <journal-title-group>
        <journal-title xml:lang="ru">Записки Горного института</journal-title>
        <journal-title xml:lang="en">Journal of Mining Institute</journal-title>
      </journal-title-group>
      <publisher>
        <publisher-name xml:lang="ru">Санкт-Петербургский горный университет императрицы Екатерины ΙΙ</publisher-name>
        <publisher-name xml:lang="en">Empress Catherine II Saint Petersburg Mining University</publisher-name>
      </publisher>
    </journal-meta>
    <article-meta>
      <article-id custom-type="edn" pub-id-type="custom">GISHQG</article-id>
      <article-id custom-type="pmi" pub-id-type="custom">pmi-16150</article-id>
      <article-id pub-id-type="uri">https://pmi.spmi.ru/pmi/article/view/16150</article-id>
      <article-categories>
        <subj-group subj-group-type="section-heading" xml:lang="ru">
          <subject>Геология</subject>
        </subj-group>
        <subj-group subj-group-type="section-heading" xml:lang="en">
          <subject>Geology</subject>
        </subj-group>
      </article-categories>
      <title-group>
        <article-title xml:lang="en">Origin of carbonate-silicate rocks of the Porya Guba  (the Lapland-Kolvitsa Granulite Belt) revealed  by stable isotope analysis (δ18O, δ13C)</article-title>
        <trans-title-group xml:lang="ru">
          <trans-title>Происхождение карбонатно-силикатных пород Порьей губы  (Лапландско-Колвицкий гранулитовый пояс) по результатам  анализа стабильных изотопов (δ18O, δ13C)</trans-title>
        </trans-title-group>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes">
          <name name-style="eastern">
            <surname>Krylov</surname>
            <given-names>Dmitrii P.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Крылов</surname>
              <given-names>Д. П.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Krylov</surname>
              <given-names>Dmitrii P.</given-names>
            </name>
          </name-alternatives>
          <email>d.p.krylov@ipgg.ru</email>
          <contrib-id contrib-id-type="orcid">0000-0001-6654-8659</contrib-id>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <aff-alternatives id="aff1">
          <aff>
            <institution xml:lang="ru">Институт геологии и геохронологии докембрия РАН (Санкт-Петербруг, Россия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Institute of Precambrian Geology and Geochronology RAS (Saint Petersburg, Russia)</institution>
          </aff>
        </aff-alternatives>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Klimova</surname>
            <given-names>Ekaterina V.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Климова</surname>
              <given-names>Е. В.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Klimova</surname>
              <given-names>Ekaterina V.</given-names>
            </name>
          </name-alternatives>
          <email>katya_kli@list.ru</email>
          <contrib-id contrib-id-type="orcid">0000-0002-9771-9518</contrib-id>
          <xref ref-type="aff" rid="aff2"/>
        </contrib>
        <aff-alternatives id="aff2">
          <aff>
            <institution xml:lang="ru">Институт геологии и геохронологии докембрия РАН (Санкт-Петербруг, Россия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Institute of Precambrian Geology and Geochronology RAS (Saint Petersburg, Russia)</institution>
          </aff>
        </aff-alternatives>
      </contrib-group>
      <pub-date pub-type="epub" iso-8601-date="2023-09-06">
        <day>06</day>
        <month>09</month>
        <year>2023</year>
      </pub-date>
      <pub-date date-type="collection">
        <year>2024</year>
      </pub-date>
      <volume>265</volume>
      <fpage>3</fpage>
      <lpage>15</lpage>
      <history>
        <date date-type="received" iso-8601-date="2023-02-07">
          <day>07</day>
          <month>02</month>
          <year>2023</year>
        </date>
        <date date-type="accepted" iso-8601-date="2023-06-20">
          <day>20</day>
          <month>06</month>
          <year>2023</year>
        </date>
        <date date-type="rev-recd" iso-8601-date="2024-02-29">
          <day>29</day>
          <month>02</month>
          <year>2024</year>
        </date>
      </history>
      <permissions>
        <copyright-statement>© Dmitrii P. Krylov, Ekaterina V. Klimova</copyright-statement>
        <copyright-year>2023</copyright-year>
        <copyright-holder xml:lang="ru">Д. П. Крылов, Е. В. Климова</copyright-holder>
        <copyright-holder xml:lang="en">Dmitrii P. Krylov, Ekaterina V. Klimova</copyright-holder>
        <license xlink:href="http://creativecommons.org/licenses/by/4.0">
          <license-p>CC BY 4.0</license-p>
        </license>
      </permissions>
      <self-uri xlink:type="simple" xlink:href="https://pmi.spmi.ru/pmi/article/view/16150">https://pmi.spmi.ru/pmi/article/view/16150</self-uri>
      <abstract xml:lang="ru">
        <p>В составе гранулитов Порьей губы Лапландско-Колвицкого пояса Фенноскандинавского щита наблюдаются карбонатно-силикатные породы неясного происхождения. Цель настоящей работы – реконструкция возможных источников вещества и условий метаморфических преобразований этих пород на основе изучения изотопного состава кислорода и углерода в сочетании с моделированием условий фазовых равновесий. Результаты изотопного анализа и литохимических реконструкций показывают, что карбонатно-силикатные породы Порьей губы сформировались в результате метаморфизма осадков (возможно, мергелей), изотопный состав которых соответствовал докембрийским диагенетически преобразованным карбонатам (δ18O ≈ 17,9 ‰, SMOW и δ13C ≈ –3,4 ‰, PDB). Химический состав варьировал в зависимости от соотношения карбонатного, глинистого и обломочного компонентов. Существенные изменения изотопного состава при метаморфизме обусловлены реакциями разложения первичных карбонатов (доломита, сидерита, анкерита) с образованием CO2 и последующей дегазацией. При этом δ18O и δ13C кальцита в изотопном равновесии с CO2 понижаются до 15 ‰ (SMOW) и –6 ‰ (PDB) соответственно. Контроль изотопного состава ограничивается локальными реакциями в пределах отдельных разновидностей пород, что исключает значимое влияние магматических и (или) метасоматических процессов.</p>
      </abstract>
      <abstract xml:lang="en">
        <p>Carbonate-silicate rocks of unclear origin have been observed in granulites of the Porya Guba of the Lapland-Kolvitsa Belt within the Fennoscandinavian Shield. The present work aims to reconstruct possible protoliths and conditions of metamorphic transformation of these rocks based on oxygen and carbon isotopic ratios combined with phase equilibria modeling. Isotope analysis and lithochemical reconstructions suggest that carbonate-silicate rocks of the Porya Guba represent metamorphosed sediments (possibly marls) with the isotopic composition corresponding to the Precambrian diagenetically transformed carbonates (δ18O ≈ 17.9 ‰, SMOW and δ13C ≈ –3.4 ‰, PDB). The chemical composition varies depending on the balance among the carbonate, clay, and clastic components. Significant changes of the isotopic composition during metamorphism are caused by decomposition reactions of primary carbonates (dolomite, siderite, and ankerite) producing CO2 followed by degassing. These reactions are accompanied by δ18O and δ13C decrease of calcite in isotopic equilibrium with CO2 down to 15 ‰ (SMOW) and –6 ‰ (PDB), respectively. The isotopic composition is buffered by local reactions within individual rock varieties, thus excluding any pronounced influence of magmatic and/or metasomatic processes.</p>
      </abstract>
      <kwd-group xml:lang="ru">
        <title>Ключевые слова</title>
        <kwd>карбонатно-силикатные породы</kwd>
        <kwd>стабильные изотопы</kwd>
        <kwd>метаморфизм</kwd>
        <kwd>неорганический углеродный цикл</kwd>
        <kwd>изотопное фракционирование</kwd>
        <kwd>дистилляция Рэлея</kwd>
      </kwd-group>
      <kwd-group xml:lang="en">
        <title>Keywords</title>
        <kwd>carbonate-silicate rocks</kwd>
        <kwd>stable isotopes</kwd>
        <kwd>metamorphism</kwd>
        <kwd>inorganic carbon cycle</kwd>
        <kwd>isotope fractionation</kwd>
        <kwd>Rayleigh distillation</kwd>
      </kwd-group>
      <funding-group>
        <funding-statement xml:lang="ru">Исследование выполнено за счет гранта Российского научного фонда № 22-27-00275, https://rscf.ru/project/22-27-00275</funding-statement>
        <funding-statement xml:lang="en">The work was financed by Russian Science Foundation, grant N 22-27-00275, https://rscf.ru/en/project/22-27-00275</funding-statement>
      </funding-group>
    </article-meta>
  </front>
  <body/>
  <back>
    <ref-list>
      <ref id="ref1">
        <label>1</label>
        <mixed-citation xml:lang="ru">Berner R.A., Lasaga A.C., Garrels R.M. The carbonate-silicate geochemical cycle and its effect on atmospheric carbon dioxide over the past 100 million years // American Journal of Science. 1983. Vol. 283. Iss. 7. P. 641-683. DOI: 10.2475/ajs.283.7.641</mixed-citation>
        <mixed-citation xml:lang="en">Berner R.A., Lasaga A.C., Garrels R.M. The carbonate-silicate geochemical cycle and its effect on atmospheric carbon dioxide over the past 100 million years. American Journal of Science. 1983. Vol. 283. Iss. 7, p. 641-683. DOI: 10.2475/ajs.283.7.641</mixed-citation>
      </ref>
      <ref id="ref2">
        <label>2</label>
        <mixed-citation xml:lang="ru">Groppo C., Rolfo F., Castelli D., Connolly J.A.D. Metamorphic CO2 production from calc-silicate rocks via garnet-forming reactions in the CFAS-H2O-CO2 system // Contributions to Mineralogy and Petrology. 2013. Vol. 166. P. 1655-1675. DOI: 10.1007/s00410-013-0947-5</mixed-citation>
        <mixed-citation xml:lang="en">Groppo C., Rolfo F., Castelli D., Connolly J.A.D. Metamorphic CO2 production from calc-silicate rocks via garnet-forming reactions in the CFAS-H2O-CO2 system. Contributions to Mineralogy and Petrology. 2013. Vol. 166, p. 1655-1675. DOI: 10.1007/s00410-013-0947-5</mixed-citation>
      </ref>
      <ref id="ref3">
        <label>3</label>
        <mixed-citation xml:lang="ru">Catling D.C., Kasting J.F. Atmospheric Evolution on Inhabited and Lifeless Worlds. Cambridge: Cambridge University Press, 2017. 579 p. DOI: 10.1017/9781139020558</mixed-citation>
        <mixed-citation xml:lang="en">Catling D.C., Kasting J.F. Atmospheric Evolution on Inhabited and Lifeless Worlds. Cambridge: Cambridge University Press, 2017, p. 579. DOI: 10.1017/9781139020558</mixed-citation>
      </ref>
      <ref id="ref4">
        <label>4</label>
        <mixed-citation xml:lang="ru">Сорохтин Н.О., Никифоров С.Л., Козлов Н.Е. Коромантийная ветвь глобального цикла углерода и происхождение глубинных углеводородов // Вестник МГТУ. 2018. Т. 21. № 1. С. 61-79. DOI: 10.21443/1560-9278-2018-21-1-61-79</mixed-citation>
        <mixed-citation xml:lang="en">Sorokhtin N.O., Nikiforov S.L., Kozlov N.Ye. Crust-mantle branch of the global carbon cycle and origin of deep-seated hydrocarbons. Vestnik of MSTU. 2018. Vol. 21. N 1, p. 61-79 (in Russian). DOI: 10.21443/1560-9278-2018-21-1-61-79</mixed-citation>
      </ref>
      <ref id="ref5">
        <label>5</label>
        <mixed-citation xml:lang="ru">Brovarone A.V., Tumiati S., Piccoli F. et al. Fluid-mediated selective dissolution of subducting carbonaceous material: Implications for carbon recycling and fluid fluxes at forearc depths // Chemical Geology. 2020. Vol. 549. № 119682. DOI: 10.1016/j.chemgeo.2020.119682</mixed-citation>
        <mixed-citation xml:lang="en">Brovarone A.V., Tumiati S., Piccoli F. et al. Fluid-mediated selective dissolution of subducting carbonaceous material: Implications for carbon recycling and fluid fluxes at forearc depths. Chemical Geology. 2020. Vol. 549. N 119682. DOI: 10.1016/j.chemgeo.2020.119682</mixed-citation>
      </ref>
      <ref id="ref6">
        <label>6</label>
        <mixed-citation xml:lang="ru">Deep Carbon: Past to present / Ed. by Orcutt B.N., Daniel I., Dasgupta R. Cambridge: Cambridge University Press, 2020. 669 p. DOI: 10.1017/9781108677950</mixed-citation>
        <mixed-citation xml:lang="en">Deep Carbon: Past to present / Ed. by Orcutt B.N., Daniel I., Dasgupta R. Cambridge: Cambridge University Press, 2020, p. 669. DOI: 10.1017/9781108677950</mixed-citation>
      </ref>
      <ref id="ref7">
        <label>7</label>
        <mixed-citation xml:lang="ru">Stagno V. Carbon, carbides, carbonates and carbonatitic melts in the Earth’s interior // Journal of the Geological Society. 2019. Vol. 176. Iss. 2. P. 375-387. DOI: 10.1144/jgs2018-095</mixed-citation>
        <mixed-citation xml:lang="en">Stagno V. Carbon, carbides, carbonates and carbonatitic melts in the Earth’s interior. Journal of the Geological Society. 2019. Vol. 176. Iss. 2, p. 375-387. DOI: 10.1144/jgs2018-095</mixed-citation>
      </ref>
      <ref id="ref8">
        <label>8</label>
        <mixed-citation xml:lang="ru">Skublov S.G., Rumyantseva N.A., Qiuli Li et al. Zircon xenocrysts from the Shaka Ridge record ancient continental crust: New U-Pb geochronological and oxygen isotopic data // Journal of Earth Science. 2022. Vol. 33. № 1. P. 5-16. DOI: 10.1007/s12583-021-1422-2</mixed-citation>
        <mixed-citation xml:lang="en">Skublov S.G., Rumyantseva N.A., Qiuli Li et al. Zircon xenocrysts from the Shaka Ridge record ancient continental crust: New U-Pb geochronological and oxygen isotopic data. Journal of Earth Science. 2022. Vol. 33. N 1, p. 5-16. DOI: 10.1007/s12583-021-1422-2</mixed-citation>
      </ref>
      <ref id="ref9">
        <label>9</label>
        <mixed-citation xml:lang="ru">Левашова Е.В., Скублов С.Г., Ойцева Т.А. и др. Изотопно-геохимические особенности циркона из постколлизионных гранитов: на примере рибекитовых гранитов Верхнее Эспе, Восточный Казахстан // Геохимия. 2022. Т. 67. № 1. С. 3-18. DOI: 10.31857/S0016752522010083</mixed-citation>
        <mixed-citation xml:lang="en">Levashova E.V., Skublov S.G., Oitseva. T.A. et al. First Age and Geochemical Data on Zircon from Riebeckite Granites of the Verkhnee Espe Rare Earth-Rare Metal Deposit, East Kazakhstan. Geochemistry International. 2022. Vol. 60. N 1, p. 3-18. DOI: 10.31857/S0016752522010083</mixed-citation>
      </ref>
      <ref id="ref10">
        <label>10</label>
        <mixed-citation xml:lang="ru">Румянцева Н.А., Скублов С.Г., Ванштейн Б.Г. и др. Циркон из габброидов хребта Шака (Южная Атлантика):</mixed-citation>
        <mixed-citation xml:lang="en">Rumyantseva N.A., Skublov S.G., Vanshtein B.G. et al. Zircon from Gabbroids of the Shaka Ridge (South Atlantic): U-Pb Age, Oxygen Isotope Ratios and Trace Element Composition. Proceedings of the Russian Mineralogical Society. 2022. S. CLI. N 1, p. 44-73 (in Russian). DOI: 10.31857/S0869605522010099</mixed-citation>
      </ref>
      <ref id="ref11">
        <label>11</label>
        <mixed-citation xml:lang="ru">U-Pb возраст, соотношение изотопов кислорода и редкоэлементный состав // Записки Российского минерального общества. 2022. Ч. CLI. № 1. С. 44-73. DOI: 10.31857/S0869605522010099</mixed-citation>
        <mixed-citation xml:lang="en">Satish-Kumar M., Miyamoto T., Hermann J. et al. Pre-metamorphic carbon, oxygen and strontium isotope signature of high-grade marbles from the Lützow-Holm Complex, East Antarctica: apparent age constraints of carbonate deposition. Geological Society, London, Special Publications. 2008. Vol. 308. Iss. 1, p. 147-164. DOI: 10.1144/SP308.7</mixed-citation>
      </ref>
      <ref id="ref12">
        <label>12</label>
        <mixed-citation xml:lang="ru">Satish-Kumar M., Miyamoto T., Hermann J. et al. Pre-metamorphic carbon, oxygen and strontium isotope signature of high-grade marbles from the Lützow-Holm Complex, East Antarctica: apparent age constraints of carbonate deposition // Geological Society, London, Special Publications. 2008. Vol. 308. Iss. 1. P. 147-164. DOI: 10.1144/SP308.7</mixed-citation>
        <mixed-citation xml:lang="en">Thaworndumrongsakul P., Booth J., Nantasin P., Kim Y. Metamorphic Evolution of Calc-silicate Body Enclosed in Charnockitic Gneiss at West Ongul Island, Lützow-Holm Complex, East Antarctica. IOP Conference Series: Earth and Environmental Science. 2021. Vol. 837. N 012015. DOI: 10.1088/1755-1315/837/1/012015</mixed-citation>
      </ref>
      <ref id="ref13">
        <label>13</label>
        <mixed-citation xml:lang="ru">Thaworndumrongsakul P., Booth J., Nantasin P., Kim Y. Metamorphic Evolution of Calc-silicate Body Enclosed in Charnockitic Gneiss at West Ongul Island, Lützow-Holm Complex, East Antarctica // IOP Conference Series: Earth and Environmental Science. 2021. Vol. 837. № 012015. DOI: 10.1088/1755-1315/837/1/012015</mixed-citation>
        <mixed-citation xml:lang="en">Jacobs J., Mikhalsky E., Henjes-Kunst F. et al. Neoproterozoic geodynamic evolution of easternmost Kalahari: Constraints from U-Pb-Hf-O zircon, Sm-Nd isotope and geochemical data from the Schirmacher Oasis, East Antarctica. Precambrian Research. 2020. Vol. 342. N 105553. DOI: 10.1016/j.precamres.2019.105553</mixed-citation>
      </ref>
      <ref id="ref14">
        <label>14</label>
        <mixed-citation xml:lang="ru">Jacobs J., Mikhalsky E., Henjes-Kunst F. et al. Neoproterozoic geodynamic evolution of easternmost Kalahari: Constraints from U-Pb-Hf-O zircon, Sm-Nd isotope and geochemical data from the Schirmacher Oasis, East Antarctica // Precambrian Research. 2020. Vol. 342. № 105553. DOI: 10.1016/j.precamres.2019.105553</mixed-citation>
        <mixed-citation xml:lang="en">Gusev N.I., Sergeeva L.Yu., Larionov A.N., Skublov S.G. Relics of the eoarchean continental crust of the Anabar shield, Siberian craton. Petrology. 2020. Vol. 28. N 2, p. 115-138. DOI: 10.31857/S086959032002003X</mixed-citation>
      </ref>
      <ref id="ref15">
        <label>15</label>
        <mixed-citation xml:lang="ru">Гусев Н.И., Сергеева Л.Ю., Ларионов А.Н., Скублов С.Г. Реликты эоархейской континентальной коры Анабарского щита, Сибирский кратон // Петрология. 2020. Т. 28. № 2. С. 115-138. DOI: 10.31857/S086959032002003X</mixed-citation>
        <mixed-citation xml:lang="en">Gusev N.I., Sergeeva L.Yu., Skublov S.G. Evidence of subduction of the paleoproterozoic oceanic crust in the Khapchan belt of the Anabar shield, Siberian craton. Petrology. 2021. Vol. 29. N 2, p. 115-135. DOI: 10.31857/S0869590321020047</mixed-citation>
      </ref>
      <ref id="ref16">
        <label>16</label>
        <mixed-citation xml:lang="ru">Гусев Н.И., Сергеева Л.Ю., Скублов С.Г. Свидетельства субдукции палеопротерозойской океанической коры в Хапчанском поясе Анабарского щита Cибирского кратона // Петрология. 2021. Т. 29. № 2. С. 115-135. DOI: 10.31857/S0869590321020047</mixed-citation>
        <mixed-citation xml:lang="en">Il’chenko V.L., Afanasieva E.N., Kaulina T.V. et al. Litsa Uranium ore occurrence (Arctic zone of the Fennoscandian Shield): new results of petrophysical and geochemical studies. Journal of Mining Institute. 2022. Vol. 255, p. 393-404. DOI: 10.31897/PMI.2022.44</mixed-citation>
      </ref>
      <ref id="ref17">
        <label>17</label>
        <mixed-citation xml:lang="ru">Ильченко В.Л., Афанасьева Е.Н., Каулина Т.В. и др. Лицевское рудопроявление урана (арктическая зона Фенноскандинавского щита): новые результаты петрофизических и геохимических исследований // Записки Горного института. 2022. Т. 255. С. 393-404. DOI: 10.31897/PMI.2022.44</mixed-citation>
        <mixed-citation xml:lang="en">Kudryashov N.M., Udoratina O.V., Kalinin A.A. et al. U-Pb (SHRIMP-RG) age of zircon from rare-metal (Li, Cs) pegmatites of the Okhmylk deposit of the Kolmozero-Voron’ya greenstone belt (northeast of the Fennoscandian shield). Journal of Mining Institute. 2022. Vol. 255, p. 448-454. DOI: 10.31897/PMI.2022.41</mixed-citation>
      </ref>
      <ref id="ref18">
        <label>18</label>
        <mixed-citation xml:lang="ru">Кудряшов Н.М., Удоратина О.В., Калинин А.А. и др. U-Pb (SHRIMP-RG) возраст циркона из редкометалльных (Li, Cs) пегматитов месторождения Охмыльк зеленокаменного пояса Колмозеро-Воронья (северо-восток Фенноскандинавского щита) // Записки Горного института. 2022. Т. 255. С. 448-454. DOI: 10.31897/PMI.2022.41</mixed-citation>
        <mixed-citation xml:lang="en">Smolkin V.F., Mokrushin A.V., Bayanova T.B. et al. Magma feeding paleochannel in the Monchegorsk ore region: geochemistry, isotope U-Pb and Sm-Ndanalysis (Kola region, Russia). Journal of Mining Institute. 2022. Vol. 255, p. 405-418. DOI: 10.31897/PMI.2022.48</mixed-citation>
      </ref>
      <ref id="ref19">
        <label>19</label>
        <mixed-citation xml:lang="ru">Смолькин В.Ф., Мокрушин А.В., Баянова Т.Б. и др. Магмаподводящий палеоканал в Мончегорском рудном районе: геохимия, изотопный U-Pb и Sm-Nd анализ (Кольский регион, Россия) // Записки Горного института. 2022. Т. 255. С. 405-418. DOI: 10.31897/PMI.2022.48</mixed-citation>
        <mixed-citation xml:lang="en">Salimgaraeva L.I., Skublov S.G., Berezin A.V., Galankina O.L. Fahlbands of the Keret archipelago, White Sea: the composition of rocks and minerals, ore mineralization. Journal of Mining Institute. 2020. Vol. 245, p. 513-521. DOI: 10.31897/ PMI.2020.5.2</mixed-citation>
      </ref>
      <ref id="ref20">
        <label>20</label>
        <mixed-citation xml:lang="ru">Салимгараева Л.И., Скублов С.Г., Березин А.В., Галанкина О.Л. Фальбанды Керетского архипелага Белого моря: характеристика состава пород и минералов, рудная минерализация // Записки Горного института. 2020. Т. 245. С. 513-521. DOI: 10.31897/ PMI.2020.5.2</mixed-citation>
        <mixed-citation xml:lang="en">Melnik A.E., Skublov S.G., Rubatto D. et al. Garnet and zircon geochronology of the Paleoproterozoic Kuru-Vaara eclogites, northern Belomorian Province, Fennoscandian Shield. Precambrian Research. 2021. Vol. 353. N 106014. DOI: 10.1016/j.precamres.2020.106014</mixed-citation>
      </ref>
      <ref id="ref21">
        <label>21</label>
        <mixed-citation xml:lang="ru">Melnik A.E., Skublov S.G., Rubatto D. et al. Garnet and zircon geochronology of the Paleoproterozoic Kuru-Vaara</mixed-citation>
        <mixed-citation xml:lang="en">Skublov S.G., Berezin A.V., Salimgaraeva L.I. Eclogites of the Belomorian mobile belt: geological-petrological and isotope-geochemical age criteria. Geochemistry International. 2022. Vol. 60. N 7, p. 626-640. DOI: 10.31857/S0016702922070047</mixed-citation>
      </ref>
      <ref id="ref22">
        <label>22</label>
        <mixed-citation xml:lang="ru">eclogites, northern Belomorian Province, Fennoscandian Shield // Precambrian Research. 2021. Vol. 353. № 106014. DOI: 10.1016/j.precamres.2020.106014</mixed-citation>
        <mixed-citation xml:lang="en">Kozlov N.E., Ivanov A.A., Nerovich L.I. The Lapland Granulite Belt: the primary nature and evolution. Apatity: KNTs AN SSSR, 1990, p. 168 (in Russian).</mixed-citation>
      </ref>
      <ref id="ref23">
        <label>23</label>
        <mixed-citation xml:lang="ru">Скублов С.Г., Березин А.В., Салимгараева Л.И. Эклогиты Беломорского подвижного пояса: геолого-петрологические и изотопно-геохимические критерии возраста // Геохимия. 2022. Т. 67. № 7. С. 621-638. DOI: 10.31857/S0016752522070044</mixed-citation>
        <mixed-citation xml:lang="en">Vinogradov L.A., Bogdanova M.N., Efimov M.M. The Granulite Belt of the Kola Peninsula. Leningrad: Nauka, 1980, p. 208 (in Russian).</mixed-citation>
      </ref>
      <ref id="ref24">
        <label>24</label>
        <mixed-citation xml:lang="ru">Козлов Н.Е., Иванов А.А., Нерович Л.И. Лапландский гранулитовый пояс – первичная природа и развитие. Апатиты: КНЦ АН СССР, 1990. 168 с.</mixed-citation>
        <mixed-citation xml:lang="en">Safronov V.T., Rosen O.M. Metacarbonate Rocks (Calciphyres) of the Lapland-Kolvitsa Granulite Belt, Baltic Shield. Lithology and Mineral Resources. 2004. Vol. 39. N 5, p. 425-436. </mixed-citation>
      </ref>
      <ref id="ref25">
        <label>25</label>
        <mixed-citation xml:lang="ru">Виноградов Л.А., Богданова М.Н., Ефимов М.М. Гранулитовый пояс Кольского полуострова. Ленинград: Наука, 1980. 208 с.</mixed-citation>
        <mixed-citation xml:lang="en">Ivliev A.I. Geology of the Lapland granulite belt metamorphic terraines (Sal’nye Tundras, the Kola Peninsula): Avtoref. dis. … kand. geol.-mineral. nauk. Moscow: IMGRE, 1977, p. 23 (in Russian).</mixed-citation>
      </ref>
      <ref id="ref26">
        <label>26</label>
        <mixed-citation xml:lang="ru">Сафронов В.Т., Розен О.М. Метакарбонатные породы (кальцифиры) Лапландско-Колвицкого гранулитового пояса Балтийского щита // Литология и полезные ископаемые. 2004. № 5. С. 491-503.</mixed-citation>
        <mixed-citation xml:lang="en">McCrea J.M. On the Isotopic Chemistry of Carbonates and a Paleotemperature Scale. The Journal of Chemical Physics. 1950. Vol. 18. N 6, p. 849-857. DOI: 10.1063/1.1747785</mixed-citation>
      </ref>
      <ref id="ref27">
        <label>27</label>
        <mixed-citation xml:lang="ru">Ивлиев А.И. Геология метаморфических комплексов Лапландского гранулитового пояса (Сальные тундры, Кольский полуостров): Автореф. дис. … канд. геол.-минерал. наук. М.: ИМГРЭ, 1977. 23 с.</mixed-citation>
        <mixed-citation xml:lang="en">Clayton R.N., Mayeda T.K. The use of bromine pentafluoride in the extraction of oxygen from oxides and silicates for isotopic analysis. Geochimica et Cosmochimica Acta. 1963. Vol. 27. Iss. 1, p. 43-52. DOI: 10.1016/0016-7037(63)90071-1</mixed-citation>
      </ref>
      <ref id="ref28">
        <label>28</label>
        <mixed-citation xml:lang="ru">McCrea J.M. On the Isotopic Chemistry of Carbonates and a Paleotemperature Scale // The Journal of Chemical Physics. 1950. Vol. 18. № 6. P. 849-857. DOI: 10.1063/1.1747785</mixed-citation>
        <mixed-citation xml:lang="en">Sang-Tae Kim, O’Neil J.R. Equilibrium and nonequilihrium oxygen isotope effects in synthetic carbonates. Geochimica et Cosmochimica Acta. 1997. Vol. 61. N 16, p. 3461-3475. DOI: 10.1016/s0016-7037(97)00169-5</mixed-citation>
      </ref>
      <ref id="ref29">
        <label>29</label>
        <mixed-citation xml:lang="ru">Clayton R.N., Mayeda T.K. The use of bromine pentafluoride in the extraction of oxygen from oxides and silicates for isotopic analysis // Geochimica et Cosmochimica Acta. 1963. Vol. 27. Iss. 1. P. 43-52. DOI: 10.1016/0016-7037(63)90071-1</mixed-citation>
        <mixed-citation xml:lang="en">Krylov D.P. Stable isotope fractionations involving Ca-Mg carbonates: evaluation of the β-factors by the “frozen phonon” method. Geokhimiya. 2022. Vol. 67. N 10, p. 942-960 (in Russian). DOI: 10.31857/S0016752522100065 </mixed-citation>
      </ref>
      <ref id="ref30">
        <label>30</label>
        <mixed-citation xml:lang="ru">Sang-Tae Kim, O’Neil J.R. Equilibrium and nonequilihrium oxygen isotope effects in synthetic carbonates // Geochimica et Cosmochimica Acta. 1997. Vol. 61. № 16. P. 3461-3475. DOI: 10.1016/s0016-7037(97)00169-5</mixed-citation>
        <mixed-citation xml:lang="en">Connoly J.A.D. Multivariable phase-diagrams – an algorithm based on generalized thermodynamics. American Journal of Science. 1990. Vol. 290. Iss. 6, p. 666-718. DOI: 10.2475/ajs.290.6.666</mixed-citation>
      </ref>
      <ref id="ref31">
        <label>31</label>
        <mixed-citation xml:lang="ru">Крылов Д.П. Фракционирование стабильных изотопов в Сa-Mg карбонатах: расчет β-факторов методом «замороженных фононов» // Геохимия. 2022. Т. 67. № 10. С. 942-960. DOI: 10.31857/S0016752522100065</mixed-citation>
        <mixed-citation xml:lang="en">Connolly J.A.D. A Primer in Gibbs Energy Minimization for Geophysicists. Petrology. 2017. Vol. 25. N 5, p. 526-534. DOI: 10.1134/S0869591117050034</mixed-citation>
      </ref>
      <ref id="ref32">
        <label>32</label>
        <mixed-citation xml:lang="ru">Connoly J.A.D. Multivariable phase-diagrams – an algorithm based on generalized thermodynamics // American Journal of Science. 1990. Vol. 290. Iss. 6. P. 666-718. DOI: 10.2475/ajs.290.6.666</mixed-citation>
        <mixed-citation xml:lang="en">Hua Xiang, Connolly J.A.D. GeoPS: An interactive visual computing tool for thermodynamic modelling of phase equilibria. Journal of Metamorphic Geology. 2022. Vol. 40. Iss. 2, p. 243-255. DOI: 10.1111/jmg.12626</mixed-citation>
      </ref>
      <ref id="ref33">
        <label>33</label>
        <mixed-citation xml:lang="ru">Connolly J.A.D. A Primer in Gibbs Energy Minimization for Geophysicists // Petrology. 2017. Vol. 25. № 5. P. 526-534. DOI: 10.1134/S0869591117050034</mixed-citation>
        <mixed-citation xml:lang="en">Holland T.J.B., Powell R. An internally consistent thermodynamic data set for phases of petrological interest. Journal of Metamorphic Geology. 1998. Vol. 16. N 3, p. 309-343. DOI: 10.1111/j.1525-1314.1998.00140.x</mixed-citation>
      </ref>
      <ref id="ref34">
        <label>34</label>
        <mixed-citation xml:lang="ru">Hua Xiang, Connolly J.A.D. GeoPS: An interactive visual computing tool for thermodynamic modelling of phase equilibria // Journal of Metamorphic Geology. 2022. Vol. 40. Iss. 2. P. 243-255. DOI: 10.1111/jmg.12626</mixed-citation>
        <mixed-citation xml:lang="en">Bibikova E.V., Melnikov V.F., Avakyan K.Kh. The Lapland granulites: petrology, geochemistry, isotopic age. Petrologiya. 1993. Vol. 1. N 2, p. 215-234 (in Russian).</mixed-citation>
      </ref>
      <ref id="ref35">
        <label>35</label>
        <mixed-citation xml:lang="ru">Holland T.J.B., Powell R. An internally consistent thermodynamic data set for phases of petrological interest // Journal of Metamorphic Geology. 1998. Vol. 16. № 3. P. 309-343. DOI: 10.1111/j.1525-1314.1998.00140.x</mixed-citation>
        <mixed-citation xml:lang="en">Mints M.V., Glaznev V.N., Konilov A.N. et al. The Lapland-Kolvitsa Granulite-Gneiss Belt. The Early Precambrian of the northeastern Baltic Shield: paleogeodynamics, crustal structure and evolution. Moscow: Nauchnyi Mir, 1996, p. 112-138 (in Russian).</mixed-citation>
      </ref>
      <ref id="ref36">
        <label>36</label>
        <mixed-citation xml:lang="ru">Бибикова Е.В., Мельников В.Ф., Авакян К.Х. Лапландские гранулиты: петрология, геохимия и изотопный возраст // Петрология. 1993. Т. 1. № 2. С. 215-234.</mixed-citation>
        <mixed-citation xml:lang="en">Schidlowski M., Eichmann R., Junge C.E. Precambrian sedimentary carbonates: carbon and oxygen isotope geochemistry and implications for the terrestrial oxygen budget. Precambrian Research. 1975. Vol. 2. Iss. 1, p. 1-69. DOI: 10.1016/0301-9268(75)90018-2</mixed-citation>
      </ref>
      <ref id="ref37">
        <label>37</label>
        <mixed-citation xml:lang="ru">Минц М.В., Глазнев В.Н., Конилов А.Н. и др. Лапландско-Колвицкий гранулито-гнейсовый пояс // Ранний докембрий северо-востока Балтийского щита: палеогеодинамика, строение и эволюция континентальной коры. М.: Научный мир, 1996. С. 112-138.</mixed-citation>
        <mixed-citation xml:lang="en">Shields G., Veizer J. Precambrian marine carbonate isotope database: Version 1.1. Geochemistry, Geophysics, Geosystems. 2002. Vol. 3. N 6, p. 1-12. DOI: 10.1029/2001GC000266</mixed-citation>
      </ref>
      <ref id="ref38">
        <label>38</label>
        <mixed-citation xml:lang="ru">Schidlowski M., Eichmann R., Junge C.E. Precambrian sedimentary carbonates: carbon and oxygen isotope geochemistry and implications for the terrestrial oxygen budget // Precambrian Research. 1975. Vol. 2. Iss. 1. P. 1-69. DOI: 10.1016/0301-9268(75)90018-2</mixed-citation>
        <mixed-citation xml:lang="en">Baumgartner L.P., Valley J.W. Stable Isotope Transport and Contact Metamorphic Fluid Flow. Reviews in Mineralogy and Geochemistry. 2001. Vol. 43. N 1, p. 415-467. DOI: 10.2138/gsrmg.43.1.415</mixed-citation>
      </ref>
      <ref id="ref39">
        <label>39</label>
        <mixed-citation xml:lang="ru">Shields G., Veizer J. Precambrian marine carbonate isotope database: Version 1.1 // Geochemistry, Geophysics, Geosystems. 2002. Vol. 3. № 6. P. 1-12. DOI: 10.1029/2001GC000266</mixed-citation>
        <mixed-citation xml:lang="en">Valley J.W. Stable isotope geochemistry of metamorphic rocks. Stable Isotopes in High Temperature Geological Processes. 1986, p. 445-490. DOI: 10.1515/9781501508936-018</mixed-citation>
      </ref>
      <ref id="ref40">
        <label>40</label>
        <mixed-citation xml:lang="ru">Baumgartner L.P., Valley J.W. Stable Isotope Transport and Contact Metamorphic Fluid Flow // Reviews in Mineralogy and Geochemistry. 2001. Vol. 43. № 1. P. 415-467. DOI: 10.2138/gsrmg.43.1.415</mixed-citation>
        <mixed-citation xml:lang="en">Lattanzi P., Rye D.M., Rice J.M. Behavior of 13C and 18O in carbonates during contact metamorphism at Marysville, Montana: implications for isotope systematics in impure dolomitic limestones. American Journal of Science. 1980. Vol. 280, p. 890-906. DOI: 10.2475/ajs.280.9.890</mixed-citation>
      </ref>
      <ref id="ref41">
        <label>41</label>
        <mixed-citation xml:lang="ru">Valley J.W. Stable isotope geochemistry of metamorphic rocks // Stable Isotopes in High Temperature Geological Processes. 1986. P. 445-490. DOI: 10.1515/9781501508936-018</mixed-citation>
        <mixed-citation xml:lang="en">Graf D.L. Geochemistry of Carbonate Sediments and Sedimentary Carbonate Rocks: Part IA-A. Isotopic Composition Chemical Analysis. Urbana: Illinois State Geological Survey, 1960, p. 42. </mixed-citation>
      </ref>
      <ref id="ref42">
        <label>42</label>
        <mixed-citation xml:lang="ru">Lattanzi P., Rye D.M., Rice J.M. Behavior of 13C and 18O in carbonates during contact metamorphism at Marysville, Montana: implications for isotope systematics in impure dolomitic limestones // American Journal of Science. 1980. Vol. 280. P. 890-906. DOI: 10.2475/ajs.280.9.890</mixed-citation>
        <mixed-citation xml:lang="en">Hoefs J. Stable Isotope Geochemistry. Springer, 2015, p. 389. DOI: 10.1007/978-3-319-19716-6</mixed-citation>
      </ref>
      <ref id="ref43">
        <label>43</label>
        <mixed-citation xml:lang="ru">Graf D.L. Geochemistry of Carbonate Sediments and Sedimentary Carbonate Rocks: Part IA-A. Isotopic Composition Chemical Analysis. Urbana: Illinois State Geological Survey, 1960. 42 p.</mixed-citation>
      </ref>
      <ref id="ref44">
        <label>44</label>
        <mixed-citation xml:lang="ru">Hoefs J. Stable Isotope Geochemistry. Springer, 2015. 389 p. DOI: 10.1007/978-3-319-19716-6</mixed-citation>
      </ref>
    </ref-list>
  </back>
</article>
