Ключевые слова

2411-3336

2541-9404

Записки Горного института

Journal of Mining Institute

Санкт-Петербургский горный университет императрицы Екатерины ΙΙ

Empress Catherine II Saint Petersburg Mining University

10.31897/PMI.2021.6.15

pmi-14913

https://pmi.spmi.ru/pmi/article/view/14913

Геоэкология и безопасность жизнедеятельности

Geoecology and occupational health and safety

Regularities of electrochemical cleaning of oil-contaminated soils

Закономерности электрохимической очистки нефтезагрязненных грунтов

Shulaev

Nikolay S.

Шулаев

Н. С.

Shulaev

Nikolay S.

nshulayev@rambler.ru

0000-0002-3595-6948

Уфимский государственный нефтяной технический университет, филиал в г. Стерлитамак (Россия) Ufa State Petroleum Technological University, Branch in the City of Sterlitamak (Russia)

Pryanichnikova

Valeriya V.

Пряничникова

В. В.

Pryanichnikova

Valeriya V.

prvaleria@mail.ru

0000-0001-8997-5186

Kadyrov

Ramil R.

Кадыров

Р. Р.

Kadyrov

Ramil R.

r_kadyrov@mail.ru

0000-0001-6665-9375

27 12 2021

2021

252 937 946 27 04 2021 30 11 2021 27 12 2021

2021

Н. С. Шулаев, В. В. Пряничникова, Р. Р. Кадыров

Nikolay S. Shulaev, Valeriya V. Pryanichnikova, Ramil R. Kadyrov

Эта статья доступна по лицензии Creative Commons Attribution 4.0 International (CC BY 4.0)

This article is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0)

https://pmi.spmi.ru/pmi/article/view/14913

Электрохимическая очистка нефтезагрязненных грунтов является перспективным направлением обеспечения экологической безопасности окружающей среды, так как может быть достаточно просто организована даже на участках, отдаленных от населенных пунктов. Для этого в качестве оборудования необходимы источник электроэнергии и система электродов. Возможно использование электрогенератора, если поблизости нет электроснабжающих линий. Материал электродов влияет на особенности окислительно-восстановительных процессов, что может сказываться на энергозатратах и степени очистки грунта от нефти или нефтепродуктов. Поэтому правильный выбор материалов электродов является одной из важных задач в области инжиниринга электрохимических методов очистки. Были исследованы изменения основных параметров (влажности, температуры, степени кислотности) в загрязненном нефтью модельном грунте, близком по составу к одному из нефтяных месторождений. Измерения параметров при использовании графитовых и металлических электродов осуществлялись на нескольких фиксированных участках межэлектродного пространства в зависимости от времени обработки. Установленные закономерности изменения параметров при очистке нефтезагрязненных грунтов позволяют сделать выводы об этапах электрохимического процесса, его скорости и энергоэффективности. Полученные результаты создают базу для проектирования промышленных установок по очистке грунтов.

Electrochemical cleaning of oil-contaminated soils is a promising area of environmental safety, as it can be easily organized even in locations remote from settlements. For this purpose, a power source and a system of electrodes are necessary as equipment. It is possible to use an electric generator if there are no power supply lines nearby. The material of electrodes affects the features of redox processes, which can affect the energy consumption and the degree of soil cleansing from oil or oil products. Therefore, the correct choice of electrode materials is one of the important tasks in the field of engineering electrochemical methods of purification. Changes in the main parameters (humidity, temperature, degree of acidity) in an oil-contaminated model soil, similar in composition to one of the oil fields, were investigated. Measurements of parameters when using graphite and metal electrodes were carried out at several fixed sections of the interelectrode space depending on the treatment time. The established patterns of parameter changes in the purification of oil-contaminated soils allow us to draw conclusions about the stages of the electrochemical process, its speed, and energy efficiency. The results obtained form a basis for designing industrial facilities for soil treatment.

Ключевые слова электрохимический метод нефтезагрязненный грунт электрод электрический ток параметры

Keywords electrochemical method oil-contaminated soil electrode electric current parameters

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