2411-3336 2541-9404 Записки Горного института Journal of Mining Institute Санкт-Петербургский горный университет императрицы Екатерины ΙΙ Empress Catherine II Saint Petersburg Mining University 10.31897/PMI.2021.1.15 pmi-14044 https://pmi.spmi.ru/pmi/article/view/14044 Геоэкология и безопасность жизнедеятельности Geoecology and occupational health and safety Trace element accumulation by soils and plants in the North Caucasian geochemical province Аккумуляция химических элементов почвенно-растительным покровом Северо-Кавказской геохимической провинции Alekseenko Vladimir A. Алексеенко В. А. Alekseenko Vladimir A. vl.al.alekseenko@gmail.com 0000-0002-7874-8110 Южный федеральный университет (Россия) Southern Federal University (Russia) Shvydkaya Natalya V. Швыдкая Н. В. Shvydkaya Natalya V. nepeta@mail.ru 0000-0003-0243-1480 Кубанский государственный аграрный университет имени И.Т.Трубилина (Россия) Kuban State Agrarian University (Russia) Bech Jaume Бек Дж. Bech Jaume jaumebechborras@gmail.com 0000-0001-9401-0266 Университет Барселоны (Испания) University of Barcelona (Spain) Puzanov Alexander V. Пузанов А. В. Puzanov Alexander V. puzanov@iwep.ru 0000-0002-1340-486X Институт водных и экологических проблем СО РАН (Россия) Institute for Water and Environmental Problems of Siberian Branch of the Russian Academy of Sciences (Russia) Nastavkin Aleksei V. Наставкин А. В. Nastavkin Aleksei V. geo_alex@mail.ru 0000-0003-1472-9399 Южный федеральный университет (Россия) Southern Federal University (Russia) 26 04 2021 2021 247 141 153 13 10 2020 02 03 2021 26 04 2021 © Vladimir A. Alekseenko, Natalya V. Shvydkaya, Jaume Bech, Alexander V. Puzanov, Aleksei V. Nastavkin 2021 В. А. Алексеенко, Н. В. Швыдкая, Дж. Бек, А. В. Пузанов, А. В. Наставкин Vladimir A. Alekseenko, Natalya V. Shvydkaya, Jaume Bech, Alexander V. Puzanov, Aleksei V. Nastavkin CC BY 4.0 https://pmi.spmi.ru/pmi/article/view/14044

Многолетние исследования Северо-Кавказской геохимической провинции позволили установить местные кларки и кларки концентрации (рассеяния) химических элементов в горных породах, почвах и растениях. Рассматриваемую провинцию характеризует ряд региональных особенностей. Ассоциации элементов, находящихся в повышенных и пониженных концентрациях, часто определяются преобладающим составом горных пород (карбонатно-терригенные, терригенные, магматические). Изучение средних содержаний ряда химических элементов в почвах провинции показало, что в ассоциацию аккумулированных элементов входят металлы с различными миграционными особенностями. Так, несмотря на довольно близкие размеры ионных радиусов, для Pb, Zn, Cu, Li (судя по ионному потенциалу) характерно образование катионов, а Mn, Mo, Zr образуют сложные комплексные ионы. На сероводородных барьерах, в основном, осаждаются Zn, Cu, Pb, а Mo, Co, Mn – на кислородных. Для Cu, Zn, Mo, Co биогенное накопление играет существенную роль, а для Pb, Ni оно практически отсутствует. Величины абсолютного разброса элементов не достигли экологически опасных значений, но свидетельствуют о довольно интенсивной миграции. В древесных растениях наиболее интенсивно накапливаются Ba, Nb, Sc, Sr, Zn. Специфические природные условия, характеризующие Северо-Кавказскую геохимическую провинцию, должны оказывать влияние на развитие техногенеза и его последствия.

Long-term studies of the North Caucasian geochemical province allowed to establish regional abundances and calculate accumulation (dispersion) factors for chemical elements in rocks, soils, and plants. Certain natural regional patterns characterize the province. Associations of elements in high and low concentrations are often determined by the predominant composition of rocks: carbonate-terrigenous, terrigenous, and igneous. The study of the average contents of several chemical elements in the soils of the province showed that the association of accumulated elements includes metals with different migration characteristics. Thus, despite the rather close values of the ionic radii, Pb, Zn, Cu, and Li (judging by the ionic potential) are characterized by the formation of cations, while Mn, Mo, and Zr form complex ions. Such elements as Zn, Cu, and Pb are mainly accumulated on hydrosulfuric barriers, while Mo, Co, and Mn are stopped by oxygenous barriers. For Cu, Zn, Mo, and Co, biogenic accumulation plays a significant role, while for Pb and Ni it is practically absent. The absolute dispersion of the elements did not reach environmentally hazardous values, although it indicates a fairly intensive migration. In woody plants, Ba, Nb, Sc, Sr, and Zn are accumulated most intensively.

 Ключевые слова геохимия почв фитоаккумуляция геохимические ассоциации фитомасса региональный геохимический фон Keywords soil geochemistry phytoaccumulation geochemical associations phytomass regional geochemical background Alekseenko V.A. Ecological geochemistry. Moscow: Logos, 2000, p. 627 (in Russian). Alekseenko V.A., Suvorinov A.V., Vlasova E.V. Metals in the environment. Forest landscapes of the Northwest Caucasus. Moscow: Universitetskaya kniga, 2008, p. 264 (in Russian). Alekseenko V.A. Geoecology. Ecological geochemistry. Rostov-na-Donu: Feniks, 2017, p. 688 (in Russian). Altukhov M.D., Gorcharuk L.G. Alpine meadows of the Northwestern Caucasus. Rastitelnye resursy. Part 2. Pishchevye, kormovye, lekarstvennye i drugie poleznye rasteniya. Rostov-na-Donu: Izd-vo Rostovskogo universiteta, 1984, p. 77-91. Bazilevich N.I., Grebenshchikov O.S., Tishkov A.A. Geographic patterns of the structure and functioning of ecosystems. Moscow: Nauka, 1986, p. 296 (in Russian). Bazilevich N.I., Rodin L.E. Dynamics of organic matter and biological cycle of nitrogen and ash elements in the main types of vegetation of the globe. Moscow, Leningrad: Nauka, 1965, p. 223 (in Russian). Vernadskii V.I. Living matter and biosphere. Moscow: Nauka, 1994, p. 672 (in Russian). Vinogradov A.P. Geochemistry of rare and trace elements in soils. Moscow: Izd-vo AN SSSR, 1957, p. 238 (in Russian). Ermolin M.S., Fedotov P.S., Ivaneev A.I. et al. Allocation and quantification of road dust nanoparticles. Zhurnal analiticheskoi khimii. 2017. Vol. 72. N 5, p. 448-461. DOI: 10.7868/S004445021705005X (in Russian). Ivanov V.V., Yushko-Zakharova O.E., Borisenko L.F., Ovchinnikov L.N. Geological reference book of siderophilic and chalcophilic rare metals. Moscow: Nedra, 1989, p. 462 (in Russian). Dzhabbarov N.S. Estimation of Soil Pollution with Heavy Metals Around Dashkesan Mining and Processing Factory. Bulletin of Science and Practice.2019. Vol. 5. N 9, p. 175-183. DOI: 10.33619/2414-2948/46/20 Kabata-Pendias A., Pendias Kh. Trace elements in soils and plants. Moscow: Mir, 1989, p. 439 (in Russian). Alekseenko V.A., Alekseenko Val.Ap., Sedletskii V.I. Map of geochemical landscapes of Krasnodar Krai. Moscow: Roskartografiya, 1988 (in Russian). Alekseenko V.A., Matasova I.Yu., Anikeenko R.V. et al. Map of geochemical landscapes of Krasnodar Krai and the Republic of Adygea. Scale 1:500,000. Moscow, Pyatigorsk: AO Severo-Kavkazskoe aerogeodezicheskoe predpriyatie, 2000, p. 2 (in Russian). Alekseenko V.A., Shvydkaya N.V., Puzanov A.V., Nastavkin A.V. Landscape monitoring studies of the North Caucasian geochemical province. Journal of Mining Institute. 2020. Vol. 243, p. 371-378. DOI: 10.31897/pmi.2020.3.371 Alekseenko V.A., Shvydkaya N.V., Rudakov E.P., Katyushenko M.A. Features of the formation of phytocenoses and changes in the morphobiological characteristics of plants at the spent mercury deposits of the Krasnodar Krai. Bio-geokhimiya khimicheskikh elementov i soedinenii v prirodnykh sredakh: Materialy II Mezhdunarodnoi shkoly-seminara dlya molodykh issledovatelei, posvyashchennoi pamyati professor V.B.Ilina. Tyumen: Tyumenskii gosudarstvennyi universitet, 2016, p. 178-183 (in Russian). Perelman A.I. Geochemistry. Moscow: Vysshaya shkola, 1979, p. 423 (in Russian). Seredin R.M. North Caucasus. Plantresources. Part 1. Forests. Rostov-na-Donu: Izd-vo Rostovskogo universiteta, 1980, p. 18-40 (in Russian). Seredin R.M. Flora and vegetation of the North Caucasus. Krasnodar: Izd-vo Kubanskogo gosudarstvennogo universiteta, 1979, p. 89 (in Russian). Fersman A.E. Selected Works. 5 Volumes. Moscow: Izd-vo AN SSSR, 1954-1959 (in Russian). Shvydkaya N.B. The study of adventive flora in anthropogenic landscapes of Krasnodar region. The North Caucasus Ecological Herald. Vol. 8. N 4, p. 87-89 (in Russian). Yashchinin S.B. Geology, metallogeny, and ore mineral resources of the North Caucasus at the beginning of the XXI century. Mineralnye Vody: Kavkazskaya zdravnitsa, 2008, p. 198 (in Russian). Bowen H.J.M. Environmental Chemistry of the Elements. N.Y.: Acad. Press, 1979, p. 333. Tume P., González E., King R.W.et al. Distinguishing between natural and anthropogenic sources for potentially toxic elements in urban soils of Talcahuano, Chile. Journal of Soils and Sediments. 2018. Vol. 18, p. 2335-2349. DOI: 10.1007/s11368-017-1750-0 Zhan F., Li B., Jiang M., Li Y., Wang Y. Effects of arbuscular mycorrhizal fungi on the growth and heavy metal accumulation of bermudagrass [Cynodondactylon (L.) Pers.] grown in a lead-zinc mine wasteland. International Journal of Phytoremediation. 2019. Vol. 21. Iss. 9, p. 849-856. DOI: 10.1080/15226514.2019.1577353 Nagornov D.O., Kremcheev E.A., Kremcheeva D.A. Research of the condition of regional parts of massif at longwall mining of prone to spontaneous ignition coal seams. International Journal of Civil Engineering and Technology. 2019. Vol. 10. Iss. 1, p. 876-883. Yalaltdinova A., Kim J., Baranovskaya N., Rikhvanov L. Populus nigra L. as a bioindicator of atmospheric trace element pollution and potential toxic impacts on human and ecosystem. Ecological Indicators. 2018. Vol. 95. Part 2, p. 974-983. DOI: 10.1016/j.ecolind.2017.06.021 Sliti N., Abdelkrim C., Ayed L. Assessment of tailings stability and soil contamination of Kef Ettout (NW Tunisia) abandoned mine. Arabian Journal of Geosciences. 2019. Vol. 12, p. 73. DOI: 10.1007/s12517-018-4204-0 Tepanosyan G., Sahakyan L., Zhang C., Saghatelyan A. The application of Local Moran's I to identify spatial clusters and hot spots of Pb, Mo and Ti in urban soils of Yerevan. Applied Geochemistry. 2019. Vol. 104, p. 116-123. DOI: 10.1016/j.apgeochem.2019.03.022