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  <front>
    <journal-meta>
      <journal-id journal-id-type="issn">2411-3336</journal-id>
      <journal-id journal-id-type="eissn">2541-9404</journal-id>
      <journal-title-group>
        <journal-title xml:lang="ru">Записки Горного института</journal-title>
        <journal-title xml:lang="en">Journal of Mining Institute</journal-title>
      </journal-title-group>
      <publisher>
        <publisher-name xml:lang="ru">Санкт-Петербургский горный университет императрицы Екатерины ΙΙ</publisher-name>
        <publisher-name xml:lang="en">Empress Catherine II Saint Petersburg Mining University</publisher-name>
      </publisher>
    </journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.25515/pmi.2018.2.107</article-id>
      <article-id custom-type="pmi" pub-id-type="custom">pmi-11895</article-id>
      <article-id pub-id-type="uri">https://pmi.spmi.ru/pmi/article/view/11895</article-id>
      <article-categories>
        <subj-group subj-group-type="section-heading" xml:lang="ru">
          <subject>Геология</subject>
        </subj-group>
        <subj-group subj-group-type="section-heading" xml:lang="en">
          <subject>Geology</subject>
        </subj-group>
      </article-categories>
      <title-group>
        <article-title xml:lang="en">Volume and surface distribution of radiation defect in natural diamonds</article-title>
        <trans-title-group xml:lang="ru">
          <trans-title>Объемное и поверхностное распределение радиационных дефектов в природных алмазах</trans-title>
        </trans-title-group>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes">
          <name name-style="eastern">
            <surname>Vasilev</surname>
            <given-names>E. A.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Васильев</surname>
              <given-names>Е. А.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Vasilev</surname>
              <given-names>E. A.</given-names>
            </name>
          </name-alternatives>
          <email>simphy12@mail.ru</email>
          <contrib-id contrib-id-type="orcid">0000-0003-2216-0956</contrib-id>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <aff-alternatives id="aff1">
          <aff>
            <institution xml:lang="ru">Санкт-Петербургский горный университет (Санкт-Петербург, Россия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Saint-Petersburg Mining University (Saint-Petersburg, Russia)</institution>
          </aff>
        </aff-alternatives>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Kozlov</surname>
            <given-names>A. V.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Козлов</surname>
              <given-names>А. В.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Kozlov</surname>
              <given-names>A. V.</given-names>
            </name>
          </name-alternatives>
          <email>akozlov@spmi.ru</email>
          <xref ref-type="aff" rid="aff2"/>
        </contrib>
        <aff-alternatives id="aff2">
          <aff>
            <institution xml:lang="ru">Санкт-Петербургский горный университет (Санкт-Петербург, Россия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Saint-Petersburg Mining University (Saint-Petersburg, Russia)</institution>
          </aff>
        </aff-alternatives>
        <contrib contrib-type="author">
          <name name-style="eastern">
            <surname>Petrovskii</surname>
            <given-names>V. A.</given-names>
          </name>
          <name-alternatives>
            <name name-style="eastern" xml:lang="ru">
              <surname>Петровский</surname>
              <given-names>В. А.</given-names>
            </name>
            <name name-style="western" xml:lang="en">
              <surname>Petrovskii</surname>
              <given-names>V. A.</given-names>
            </name>
          </name-alternatives>
          <email>petrovsky@geo.komisc.ru</email>
          <xref ref-type="aff" rid="aff3"/>
        </contrib>
        <aff-alternatives id="aff3">
          <aff>
            <institution xml:lang="ru">Институт геологии Коми НЦ УрО РАН (Сыктывкар, Россия)</institution>
          </aff>
          <aff>
            <institution xml:lang="en">Institute of Geology of the Komi Science Center of the Ural Branch of the RAS (Syktyvkar, Russia)</institution>
          </aff>
        </aff-alternatives>
      </contrib-group>
      <pub-date pub-type="epub" iso-8601-date="2018-04-24">
        <day>24</day>
        <month>04</month>
        <year>2018</year>
      </pub-date>
      <pub-date date-type="collection">
        <year>2018</year>
      </pub-date>
      <volume>230</volume>
      <fpage>107</fpage>
      <lpage>115</lpage>
      <history>
        <date date-type="received" iso-8601-date="2017-11-16">
          <day>16</day>
          <month>11</month>
          <year>2017</year>
        </date>
        <date date-type="accepted" iso-8601-date="2018-01-16">
          <day>16</day>
          <month>01</month>
          <year>2018</year>
        </date>
        <date date-type="rev-recd" iso-8601-date="2018-04-24">
          <day>24</day>
          <month>04</month>
          <year>2018</year>
        </date>
      </history>
      <permissions>
        <copyright-statement>© E. A. Vasilev, A. V. Kozlov, V. A. Petrovskii</copyright-statement>
        <copyright-year>2018</copyright-year>
        <copyright-holder xml:lang="ru">Е. А. Васильев, А. В. Козлов, В. А. Петровский</copyright-holder>
        <copyright-holder xml:lang="en">E. A. Vasilev, A. V. Kozlov, V. A. Petrovskii</copyright-holder>
        <license xlink:href="http://creativecommons.org/licenses/by/4.0">
          <license-p>CC BY 4.0</license-p>
        </license>
      </permissions>
      <self-uri xlink:type="simple" xlink:href="https://pmi.spmi.ru/pmi/article/view/11895">https://pmi.spmi.ru/pmi/article/view/11895</self-uri>
      <abstract xml:lang="ru">
        <p>Рассмотрены различные варианты природного радиоактивного облучения кристаллов алмаза. Показано, что в природных алмазах отмечены случаи радиационного воздействия на весь объем кристаллов, при котором наводится равномерная зеленая окраска. При малых дозах облучения радиоактивное воздействие диагностируется по люминесценции системы GR1, при больших дозах появляется голубоватый оттенок, переходящий в зеленый цвет, при максимальном объемном облучении кристаллы становятся черными. Приведено исследование кристаллов с равномерно распределенной по объему черной окраской. Предполагается, что основным источником радиации при облучении таких кристаллов может быть растворенный в воде 222Rn и продукты его распада. Рассмотрены геологические ситуации, в которых может происходить облучение алмазов за счет распада содержащегося в воде 222Rn.</p>
      </abstract>
      <abstract xml:lang="en">
        <p>In the following article, we have studied the variations of natural irradiation of diamond crystals. The natural diamonds in some cases show homogeneous green colour, caused by irradiation of the entire crystals volume. Radiation damage effects, produced by the low-radiation doses, are detected by the luminescence of the GR1 system. The high-radiation doses cause bluish hue, turning into a greenish colour, while the maximum level of volume irradiation produces the black crystals. The crystals with homogeneous volumetric black colour distribution were also studied. The major source of radiation in such cases may represent a local stream containing water rich in 222Rn and its decay products. There is a review of the geological environment in which diamonds could be irradiated due to the decay of the 222Rn containing in water.</p>
      </abstract>
      <kwd-group xml:lang="ru">
        <title>Ключевые слова</title>
        <kwd>алмаз</kwd>
        <kwd>облучение</kwd>
        <kwd>окраска</kwd>
        <kwd>вакансии</kwd>
        <kwd>ИК-спектроскопия</kwd>
      </kwd-group>
      <kwd-group xml:lang="en">
        <title>Keywords</title>
        <kwd>diamond</kwd>
        <kwd>irradiation</kwd>
        <kwd>vacancy</kwd>
        <kwd>FTIR</kwd>
      </kwd-group>
    </article-meta>
  </front>
  <body/>
  <back>
    <ref-list>
      <ref id="ref1">
        <label>1</label>
        <mixed-citation xml:lang="ru">Зинчук Н.Н. Типоморфизм алмаза Сибирской платформы / Н.Н.Зинчук, В.И.Коптиль. М.: Недра, 2003. 603 с.</mixed-citation>
      </ref>
      <ref id="ref2">
        <label>2</label>
        <mixed-citation xml:lang="ru">Инфракрасная спектроскопия и внутреннее строение алмазов россыпи Ичетью (Средний Тиман, Россия) / Е.А.Васильев, В.А.Петровский, А.В.Козлов, А.В.Антонов // Записки Российского минералогического общества. 2017. № 2. С. 58-72.</mixed-citation>
      </ref>
      <ref id="ref3">
        <label>3</label>
        <mixed-citation xml:lang="ru">Николаенко В.А. Влияние интенсивности реакторного облучения на расширение кристаллической решетки алмаза / В.А.Николаенко, Е.А.Красиков // Атомная энергия. 2014. № 4. С. 223-230. DOI: 10.1007/s10512-014-9782-7</mixed-citation>
      </ref>
      <ref id="ref4">
        <label>4</label>
        <mixed-citation xml:lang="ru">О радиационном происхождении объемной зеленой окраски природных алмазов / С.В.Титков, А.И.Иванов, А.С.Марфунин, Л.В.Бершов, В.М.Кулаков, М.В.Чукичев // Доклады РАН. 1994. Т.335. № 4. С. 438-502.</mixed-citation>
      </ref>
      <ref id="ref5">
        <label>5</label>
        <mixed-citation xml:lang="ru">Смыслов А.А. Региональные прогнозно-металлогенические исследования на уран и их роль в формировании минерально-сырьевой базы атомной промышленности России / А.А.Смыслов, А.В.Козлов // Записки Горного института. 2011. Т. 194. С. 12-45.</mixed-citation>
      </ref>
      <ref id="ref6">
        <label>6</label>
        <mixed-citation xml:lang="ru">Akkerblom G. Mapping of groundwater radon potential / G.Akkerblom, J.Lindgren // Uranium exploration data and techniques applied to the preparation of radioelement maps: Proceedings of a Technical Committee meeting. Vienna, 1996. P. 237-255.</mixed-citation>
      </ref>
      <ref id="ref7">
        <label>7</label>
        <mixed-citation xml:lang="ru">Armitage M. Radioactive halos in a diamond // American Laboratory. 1993. N 18. P. 28-30.</mixed-citation>
      </ref>
      <ref id="ref8">
        <label>8</label>
        <mixed-citation xml:lang="ru">Balfour I. Famous Diamonds. Christie's Books, 1997. P. 320.</mixed-citation>
      </ref>
      <ref id="ref9">
        <label>9</label>
        <mixed-citation xml:lang="ru">Boyd S.R. Infrared absorption by the B nitrogen aggregate in diamond / S.R.Boyd, I.Kiflawi, G.S.Woods // Philosophical Magazine B. 1995. Vol. 72. P. 351-361. DOI: 10.1080/1364281950823908</mixed-citation>
      </ref>
      <ref id="ref10">
        <label>10</label>
        <mixed-citation xml:lang="ru">Boyd S.R. The relationship between infrared absorption and the A defect concentration in diamond / S.R.Boyd, I.Kiflawi, G.S.Woods // Philosophical Magazine B. 1994. Vol. 69. P. 1149-1153. DOI: 10.1080/01418639408240185</mixed-citation>
      </ref>
      <ref id="ref11">
        <label>11</label>
        <mixed-citation xml:lang="ru">Campbell B. Radiation Damage of Diamond by Electron and Gamma Irradiation / B.Campbell, A.Maiwood // Physica Status Solidi. 2000. N 1. P. 99-107. DOI: 10.1002/1521-396X(200009)</mixed-citation>
      </ref>
      <ref id="ref12">
        <label>12</label>
        <mixed-citation xml:lang="ru">Clark C.D. The absorption spectra of natural and irradiated diamonds / C.D.Clark, R.W.Ditchburn, H.B.Dyer // Proceedings Royal Society of London A. 1956. N 234. P. 363-381. DOI: 10.1098/rspa.1956.0040</mixed-citation>
      </ref>
      <ref id="ref13">
        <label>13</label>
        <mixed-citation xml:lang="ru">Davies G. Current problems in diamond: towards a quantitative understanding // Physica B. 1999. N 274. P. 15-23. DOI:10.1016/S0921-4526(99)00398-1</mixed-citation>
      </ref>
      <ref id="ref14">
        <label>14</label>
        <mixed-citation xml:lang="ru">Diamond from Arkhangelsk diamondiferous province / V.K.Garanin, S.M.Bezborodov, K.V.Garanin, N.N.Golovin, O.V.Palazhchenko // Extended Abstracts and articles of 30th Gemmological Conference. Moscow, 2007. P. 39-41.</mixed-citation>
      </ref>
      <ref id="ref15">
        <label>15</label>
        <mixed-citation xml:lang="ru">Dishler B. Handbook of spectral lines in diamond. Berlin Heidelberg: Springer-Verlag, 2012. 467 p.</mixed-citation>
      </ref>
      <ref id="ref16">
        <label>16</label>
        <mixed-citation xml:lang="ru">Eaton-Magana S.C. Temperature effects on radiation stains in natural diamonds / S.C.Eaton-Magana, K.S.Moe // Diamond and Related Materials. 2016. Vol. 64. P. 130-142. DOI: 10.1016/j.diamond.2016.02.009</mixed-citation>
      </ref>
      <ref id="ref17">
        <label>17</label>
        <mixed-citation xml:lang="ru">El-Khayatt A.M. Radiation shielding of concretes containing different lime/silica ratios // Annals of Nuclear Energy. 2010. N 37. P. 991-995.</mixed-citation>
      </ref>
      <ref id="ref18">
        <label>18</label>
        <mixed-citation xml:lang="ru">Gauthier-Lafaye F. Natural fission reactors in the Franceville Basin, Gabo: a review of the conditions and results of a «critical event» in a geologic system / F.Gauthier-Lafaye, P.Holliger, P.L.Blanc // Geochimica et Cosmochimica Acta. 1996. N 23. P. 4831-4852.DOI: 10.1016/S0016-7037(96)00245-1</mixed-citation>
      </ref>
      <ref id="ref19">
        <label>19</label>
        <mixed-citation xml:lang="ru">Harris J.W. Diamond geology // The properties of natural and synthetic diamond / J.E.Field (ed). London: Academic Press, 1992. P. 345-393.</mixed-citation>
      </ref>
      <ref id="ref20">
        <label>20</label>
        <mixed-citation xml:lang="ru">Infrared absorption studies of neutron-irradiated type Ib diamond / Y.Mita, Y.Yamada, Y.Nisida, M.Okada, T.Nakashima // Physica B. 2006. Vol. 376. P. 288-291. DOI: 10.1016/j.physb.2005.12.074</mixed-citation>
      </ref>
      <ref id="ref21">
        <label>21</label>
        <mixed-citation xml:lang="ru">Internal radioactive haloes in diamond / M.J.Mendelssohn, H.J.Milledge, E.R.Vance, E.Nave, P.A.Woods // Industrial Diamond Review. 1979. Vol. 39. P. 31-36.</mixed-citation>
      </ref>
      <ref id="ref22">
        <label>22</label>
        <mixed-citation xml:lang="ru">International Nuclear Structure and Decay Data Network of the IAEA. URL: www-nds.iaea.org (date of access 15.01.2018).</mixed-citation>
      </ref>
      <ref id="ref23">
        <label>23</label>
        <mixed-citation xml:lang="ru">Kanaya K. Penetration and energy loss theory of electrons in solid targets / K.Kanaya, S.Okayama // Journal Physics D: Applied Physics. 1972. N 5. P. 43-58. DOI: 10.1088/0022-3727/5/1/308</mixed-citation>
      </ref>
      <ref id="ref24">
        <label>24</label>
        <mixed-citation xml:lang="ru">Mironov V.P. FTIR spectroscopy of annealing processes in neutron irradiated diamonds // Wide Bandgap Layers: Abstract Book 3rd International Conference on Novel Applications of Wide Bandgap Layers. Warsaw, 2001. P. 130-131. DOI: 10.1109/WBL.2001.946572</mixed-citation>
      </ref>
      <ref id="ref25">
        <label>25</label>
        <mixed-citation xml:lang="ru">Nikolaenko V.A. Effect of γ-irradiation on defect annealing in diamond / V.A.Nikolaenko, V.G.Gordeyev, V.I.Karpukhin // Radiation Effects and Defects in Solids. 1996. N 3. P. 173-182. DOI: 10.1080/10420159608211544</mixed-citation>
      </ref>
      <ref id="ref26">
        <label>26</label>
        <mixed-citation xml:lang="ru">Palmer D.V. Rate of production of radiation damage in diamond // Properties and growth of diamond / G.Davies (ed). London: INSPEC IEE, 1994. P. 143-152.</mixed-citation>
      </ref>
      <ref id="ref27">
        <label>27</label>
        <mixed-citation xml:lang="ru">Radio-colouration of diamond: a spectroscopic study / L.Nasdala, D.Grambole, M.Wildner, A.M.Gigler, T.Hainschwang, A.M.Zaitsev, J.W.Harris, J.Milledge, D.J.Schulze, W.Hofmeister, W.A.Balmer // Contributions to Mineralogy and Petrology. 2013. N 5. P. 843-861. DOI: 10.1007/s00410-012-0838-1</mixed-citation>
      </ref>
      <ref id="ref28">
        <label>28</label>
        <mixed-citation xml:lang="ru">The Diamond Deposits of Kalimantan, Borneo / L.K.Spencer, S.D.Dikinis, P.C.Keller, R.E.Kane // Gems and Gemology. 1988. N 2. P. 67-80.</mixed-citation>
      </ref>
      <ref id="ref29">
        <label>29</label>
        <mixed-citation xml:lang="ru">Vanse E. X-ray study of neutron irradiated diamonds // Journal Physics C: Solid State Physics. 1971. N 4. P. 257-262. DOI: 10.1088/0022-3719/4/3/001</mixed-citation>
      </ref>
      <ref id="ref30">
        <label>30</label>
        <mixed-citation xml:lang="ru">Vanse E.J. Possible origins of a-damage in diamonds from kimberlite and alluvial sources / E.J.Vanse, J.W.Harris, H.J.Milledge // Mineralogical Magazine. 1973. Vol. 39. P. 349-360.</mixed-citation>
      </ref>
      <ref id="ref31">
        <label>31</label>
        <mixed-citation xml:lang="ru">Woods G.S. Infrared absorption studies of the annealing of irradiated diamonds // Philosophical Magazine B. 1984. N 6. P. 673-688. DOI: 10.1080/1364281</mixed-citation>
      </ref>
      <ref id="ref32">
        <label>32</label>
        <mixed-citation xml:lang="ru">Zaitsev A.M. Optical properties of diamond: a data handbook. New York: Springer, 2001. 502 p.</mixed-citation>
      </ref>
    </ref-list>
  </back>
</article>
